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The geochemistry of rhenium and osmium in recent sediments from the Black Sea
Open accessAbstract
The Os isotopic composition of recent sediments from the Black Sea are reported with the concentrations of Re, Os, and major and minor elements. Osmium concentrations range from 0.23 to 0.69 ppb and Re concentrations range from 21 to 85 ppb. Concentrations of both elements are large relative to average crustal material and are positively correlated with organic carbon. 187Os186Os ratios range from 5.7 to 7.1; all of these values are less radiogenic than the estimated 187Os186Os ratio of seawater and average continental crust material. Variations in the Os isotopic composition of these sediments are attributed to mixing of a hydrogenous component (187Os186Os ratio between 7 and 9) and a less radiogenic detrital component (187Os186Os ratio between 1 and 4). A mixing model is used to determine the fraction of Os in the sediment associated with each component, and the burial fluxes of Re and Os in the Black Sea are calculated. In addition the data are used to estimate the magnitude of systematic error which such initial Os isotopic heterogeneity may introduce into Re-Os age determinations of ancient organic-rich sediments.
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Citations
Cited by
Geochemistry of Recent oxic and anoxic marine sediments: Implications for the geological record
Calvert, S. E., & Pedersen, T. F. (1993) · Marine Geology · doi:10.1016/0025-3227(93)90150-t · Cited by 1,679
The geochemistry of redox sensitive trace metals in sediments
Morford, J. L., & Emerson, S. (1999) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00126-x · Cited by 1,215
Algeo, T. J., & Lyons, T. W. (2006) · Paleoceanography · doi:10.1029/2004pa001112 · Cited by 1,194
The marine osmium isotope record
Peucker‐Ehrenbrink, B., & Ravizza, G. (2000) · Terra Nova · doi:10.1046/j.1365-3121.2000.00295.x · Cited by 371
Self-citationHannah, J. L., Bekker, A., Stein, H. J., Markey, R. J., & Holland, H. D. (2004) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2004.06.013 · Cited by 263
Metadata
- Authors
- Ravizza, G., Turekian, K. K., & Hay, B. J.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 1991-12
- Volume
- 55
- Issue
- 12
- Pages
- 3741-3752
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1963487805
- Cited by
- 166
- References
- 0
- FWCI
- 4.64
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- CoChat. (2026). Citation check: The geochemistry of rhenium and osmium in recent sediments from the Black Sea. https://app.cochat.ai/papers/10.1016/0016-7037(91)90072-d
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- Ravizza, G., Turekian, K. K., & Hay, B. J. (1991). The geochemistry of rhenium and osmium in recent sediments from the Black Sea. Geochimica et Cosmochimica Acta. https://doi.org/10.1016/0016-7037(91)90072-d
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