Cited by 31Plant biochemistry and biosynthesisPlant tissue culture and regenerationBiochemical and biochemical processes

Biosynthesis of irregular monoterpenes in extracts from higher plants

Banthorpe, Derek V., Doonan, Shawn, Gutowski, Jan A.·1977·Phytochemistry

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Crossref · 10.1016/0031-9422(77)83019-7

Cites

47 of 47 references verified0 citation errors · 0 not checkable

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  • Artemisia ketone is formed by a non-standard head-to-middle condensation of DMAPP, which is thought to proceed via chrysanthemyl pyrophosphate, an intermediate containing a three-membered ring.

    “Artemisia ketone (276) is formed by a non-standard “head-to-middle” condensation of DMAPP [104,122,123,124,125,126], which is thought to proceed as shown in Scheme 2 via chrysanthemyl pyrophosphate, an intermediate containing a three-membered ring.”
  • The formation of the artemisyl, lavandulyl and santolinyl skeletons has been explained in terms of different cleavage reactions occurring at each of the three carbon-carbon bonds in the cyclopropyl ring of chrysanthemyl pyrophosphate.

    “The formation of all three skeletons has been explained in terms of different cleavage reactions occurring at each of the three carbon-carbon bonds in the cyclopropyl ring of the common precursor, chysanthemyl pyrophosphate (Scheme 2) [126].”

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Authors
Banthorpe, D. V., Doonan, S., & Gutowski, J. A.
Affiliations
University College London (GB)
Venue
Phytochemistry
Publisher
Elsevier BV
Published
1977
Volume
16
Issue
1
Pages
85-92
ISSN
0031-9422 (ISSN-L)
OpenAlex
W2078024616
Cited by
31
References
47
FWCI
1.77
Type
journal article
Language
en
Open access
closed
Locations
Phytochemistry (publishedVersion)
Topics
  • Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Plant biochemistry and biosynthesis
  • Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Plant tissue culture and regeneration
  • Life Sciences › Biochemistry, Genetics and Molecular Biology › Biotechnology › Biochemical and biochemical processes
Keywords
monoterpene biosynthesis, Artemisia annua, Santolina chamaecyparissus, artemisia ketone, lavandulol, isopentenyl pyrophosphate, NAD+, NADPH, biogenetic pathway

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