Thermal degradation of urethanes based on 4,4′-diphenylmethane diisocyanate and 1,4-butanediol (MDI/BDO)
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Thermoplastic SMPUs undergo thermal degradation first via decomposition of urethane bonds before soft segments start to decompose.
“Thermoplastic SMPUs undergo thermal degradation first via decomposition of urethane bonds before soft segments start to decompose [235,236].”
From Review on the Functional Determinants and Durability of Shape Memory Polymers (2010) · cites this paper as [235]
Cites
Mechanism of thermal degradation of polyurethanes. Effect of ammonium polyphosphate
Montaudo, G., Puglisi, C., Scamporrino, E., et al. (1984) · Macromolecules · doi:10.1021/ma00138a032 · Cited by 82 · see citing works
Synthesis and DSC study of model hard segments from diphenyl methane diisocyanate and butane diol
Camberlin, Y., Pascault, J., Létoffé, J. M., et al. (1982) · Journal of Polymer Science Polymer Chemistry Edition · doi:10.1002/pol.1982.170200212 · Cited by 63 · see citing works
Synthesis and characterization of MDI‐butanediol urethane model compounds
Hwang, K. K. S., Wu, G., Lin, S. B., et al. (1984) · Journal of Polymer Science Polymer Chemistry Edition · doi:10.1002/pol.1984.170220714 · Cited by 54 · see citing works
Mukaiyama, T., & Iwanami, M. (1957) · Journal of the American Chemical Society · doi:10.1021/ja01558a019 · Cited by 49 · see citing works
Mukaiyama, T., & Hoshino, Y. (1956) · Journal of the American Chemical Society · doi:10.1021/ja01590a050 · Cited by 49 · see citing works
The Thermal Dissociation of Blocked Toluene Diisocyanates
Griffin, G. R., & Willwerth, L. J. (1962) · I&EC Product Research and Development · doi:10.1021/i360004a010 · Cited by 47 · see citing works
Impingement mixing and its effect on the microstructure of RIM polyurethanes
Kolodziej, P., Yang, W. P., Macosko, C. W., et al. (1986) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.1986.090241017 · Cited by 39 · see citing works
Self-citationSynthesis and characterization of model urethane compounds
Qin, Z. Y., Macosko, C. W., & Wellinghoff, S. T. (1985) · Macromolecules · doi:10.1021/ma00145a040 · Cited by 28 · see citing works
Self-citationThermoplastic Polyurethane Elastomer Melt Polymerization Study
Schollenberger, C. S., Dinbergs, K., & Stewart, F. D. (1982) · Rubber Chemistry and Technology · doi:10.5254/1.3535862 · Cited by 14 · see citing works
The Reactions of Carbamates with Alcohols
Gaylord, N. G., & Sroog, C. E. (1953) · The Journal of Organic Chemistry · doi:10.1021/jo50018a002 · Cited by 12 · see citing works
The Effect of the Substituents (Alkyl-groups) on the Thermal Dissociation of Carbaminic Acid Esters
Mukaiyama, T., Motoki, S., & Hamada, Y. (1953) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.26.49 · Cited by 8 · see citing works
Mukaiyama, T., Akiba, T., & Asahi, T. (1960) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.33.1137 · Cited by 6 · see citing works
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Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811 · see citing works
Chemically Recyclable Biobased Polyurethanes
Schneiderman, D. K., Vanderlaan, M. E., Mannion, A. M., Panthani, T. R., Batiste, D. C., Wang, J. Z., Bates, F. S., Macosko, C. W., & Hillmyer, M. A. (2016) · ACS Macro Letters · doi:10.1021/acsmacrolett.6b00193 · Cited by 213 · see citing works
Self-citationReview on the Functional Determinants and Durability of Shape Memory Polymers
Pretsch, T. (2010) · Polymers · doi:10.3390/polym2030120 · Cited by 138 · see citing works
Guignot, C., Betz, N., Legendre, B., Le Moel, A., & Yagoubi, N. (2001) · Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms · doi:10.1016/s0168-583x(01)00850-3 · Cited by 81 · see citing works
Structure and mechanical properties of shape memory polyurethane based on hyperbranched polyesters
Cao, Q., & Liu, P. (2006) · Polymer Bulletin · doi:10.1007/s00289-006-0650-z · Cited by 56 · see citing works
- Authors
- Yang, W. P., Macosko, C. W., & Wellinghoff, S. T.
- Affiliations
- University of Minnesota (US)
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 1986-08
- Volume
- 27
- Issue
- 8
- Pages
- 1235-1240
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2002312364
- Cited by
- 190
- References
- 12
- Citations by year
- 2026: 5 · 2025: 5 · 2024: 7 · 2023: 5 · 2022: 6 · 2021: 3 · 2020: 1 · 2019: 8 · 2018: 3 · 2017: 2 · 2016: 4 · 2015: 6 · 2014: 6 · 2013: 5 · 2012: 8
- FWCI
- 4.97
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- Funders
- National Science Foundation
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
- Keywords
- thermal degradation, urethane, 4,4'-diphenylmethane diisocyanate, 1,4-butanediol, annealing temperature, molecular weight distribution, depolymerization, polymerization, thermal dissociation, first-order kinetics, triblock copolymers, thermal stability
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