UV-, VIS- and IR-light-induced isomerization of HSNO in a low-temperature matrix
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All energy barriers to isomerization of HSNO isomers are small because of the mobile hydrogen, and all isomers appear to degrade thermally or rapidly polymerize.
“Whatever the truth of the matter, all the energy barriers to isomerization are small because of the mobile hydrogen, and all isomers appear to degrade thermally to unknown products or rapidly polymerize [53,55].”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [55]
In HSNO, the strength of the S-N bond is not substantially different from that in other nitrosothiols.
“Further calculations suggest that in HSNO the strength of the S-N bond is not substantially different from that in other nitrosothiols [55,56].”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [55]
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Cortese-Krott, M. M., Fernandez, B. O., Santos, J. L. T., Mergia, E., Grman, M., Nagy, P., Kelm, M., Butler, A., & Feelisch, M. (2014) · Redox Biology · doi:10.1016/j.redox.2013.12.031 · Cited by 153 · see citing works
On the chemical biology of the nitrite/sulfide interaction
Cortese-Krott, M. M., Fernandez, B. O., Kelm, M., Butler, A. R., & Feelisch, M. (2015) · Nitric Oxide · doi:10.1016/j.niox.2014.12.009 · Cited by 115 · see citing works
- Authors
- Müller, R. P., Nonella, M., Russegger, P., & Huber, J. R.
- Affiliations
- University of Zurich (CH)
- Corresponding author
- Huber, J.Robert
- ORCID
- Huber, J.Robert
- Venue
- Chemical Physics
- Publisher
- Elsevier BV
- Published
- 1984-07
- Volume
- 87
- Issue
- 3
- Pages
- 351-361
- ISSN
- 0301-0104 (ISSN-L)
- OpenAlex
- W2027641410
- Cited by
- 40
- References
- 39
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 2 · 2022: 1 · 2020: 2 · 2019: 2 · 2017: 4 · 2016: 6 · 2015: 2 · 2014: 4 · 2013: 1
- FWCI
- 1.60
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Physics (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Chemical Reactions and Mechanisms
- Physical Sciences › Chemistry › Spectroscopy › Molecular Spectroscopy and Structure
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
- Keywords
- cis-trans isomerization, internal rotation, matrix isolation, argon matrix, isotopic labeling, photolysis, fundamental frequency, normal coordinate analysis, internal rotation barrier, low-temperature spectroscopy
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