The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
The thermodynamics and kinetics of the hydrogen sulfide system in natural waters
Open accessAbstract
The thermodynamics and kinetics of the H2S system in natural waters have been critically reviewed. Equations have been derived for the solubility and ionization of H2S in water and seawater as a function of salinity, temperature and pressure. Pitzer parameters for the interaction of the major cations (Na+, Mg2+ and Ca2+) with HS− have been determined to allow one to calculate values of pK1∗ in various ionic media. The limited data available for the interaction of trace metals for HS− are summarized and future work is suggested. The kinetics of oxidation of H2S have also been examined as a function of pH, temperature, and salinity. The discrepancies in the available data are largely due to the different [O2]/[HS−] ratios used in various studies. Over a limited pH range (6–8) the pseudo first order rate constant for the oxidation is shown to be directly proportional to the activity of HS−. Further studies are suggested to examine the effect of ionic media and temperature on the rate of oxidation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Hydrogen sulphide ionization and sulphur hydrolysis in high temperature solution
Ellis, A. J., & Giggenbach, W. (1971) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(71)90036-6 · Cited by 161
Cited by
The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters
MORSE, J., MILLERO, F., CORNWELL, J., & RICKARD, D. (1987) · Earth-Science Reviews · doi:10.1016/0012-8252(87)90046-8 · Cited by 660
Self-citationChemical foundations of hydrogen sulfide biology
Li, Q., & Lancaster, J. R. (2013) · Nitric Oxide · doi:10.1016/j.niox.2013.07.001 · Cited by 334
Ridgwell, A., Hargreaves, J. C., Edwards, N. R., Annan, J. D., Lenton, T. M., Marsh, R., Yool, A., & Watson, A. (2007) · Biogeosciences · doi:10.5194/bg-4-87-2007 · Cited by 295
Manganese cycling in a eutrophic lake ? Rates and pathways
Sternbeck, J. (1996) · Aquatic Geochemistry · doi:10.1007/bf00702741 · Cited by 16
Metadata
- Authors
- Millero, F. J.
- Venue
- Marine Chemistry
- Publisher
- Elsevier BV
- Published
- 1986-03
- Volume
- 18
- Issue
- 2-4
- Pages
- 121-147
- ISSN
- 0304-4203 (ISSN-L)
- OpenAlex
- W1968972277
- Cited by
- 265
- References
- 1
- FWCI
- 4.77
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The thermodynamics and kinetics of the hydrogen sulfide system in natural waters. https://app.cochat.ai/papers/10.1016/0304-4203(86)90003-4
- The paper
- Millero, F. J. (1986). The thermodynamics and kinetics of the hydrogen sulfide system in natural waters. Marine Chemistry. https://doi.org/10.1016/0304-4203(86)90003-4
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
