The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters

MORSE, J; MILLERO, F; CORNWELL, J; RICKARD, D

doi:10.1016/0012-8252(87)90046-8

Cited by 660Geochemistry and Elemental AnalysisPaleontology and Stratigraphy of FossilsMarine and coastal ecosystems

The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters

MORSE, J, MILLERO, F, CORNWELL, J, RICKARD, D·1987·Earth-Science Reviews

DOI 10.1016/0012-8252(87)90046-8

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At physiological pH, H2S exists largely (75-80%) as the hydrosulfide anion HS-, with negligible S2- and very little dissolved uncharged gas.
“Therefore, at physiological pH H2S exists largely (75-80%) in the form of the hydrosulfide anion (HS -), with negligible amounts of S 2- [8,9], and very little of it is in the form of the dissolved uncharged gas [9].”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [8]

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Authors: MORSE, J., MILLERO, F., CORNWELL, J., & RICKARD, D.
ORCID: MILLERO, F
CORNWELL, J
RICKARD, D
Venue: Earth-Science Reviews
Publisher: Elsevier BV
Published: 1987-03
Volume: 24
Issue: 1
Pages: 1-42
ISSN: 0012-8252 (ISSN-L)
DOI: 10.1016/0012-8252(87)90046-8
OpenAlex: W2058811848
Cited by: 660
References: 193
Citations by year: 2026: 4 · 2025: 9 · 2024: 16 · 2023: 15 · 2022: 19 · 2021: 30 · 2020: 17 · 2019: 23 · 2018: 23 · 2017: 31 · 2016: 21 · 2015: 24 · 2014: 21 · 2013: 25 · 2012: 18
FWCI: 12.07
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Earth-Science Reviews (publishedVersion)
ORCA Online Research @Cardiff (Cardiff University) (submittedVersion)
Topics: Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
Physical Sciences › Earth and Planetary Sciences › Oceanography › Marine and coastal ecosystems
Keywords: hydrogen sulfide, iron sulfide, reduced sulfur compounds, natural waters, inorganic chemistry, anaerobic sediments, sediment diagenesis, biogeochemical interactions, sulfur speciation

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