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IR-Driven strong plasmonic-coupling on Ag nanorices/W18O49 nanowires heterostructures for photo/thermal synergistic enhancement of H2 evolution from ammonia borane
Abstract
Abstract Plasmonic coupling between two or more metal nanostructures has attracted significant interest, since this fascinating near-field interaction is more effective for the aggregation/magnification of the incident light intensity compared to normal surface-plasmon-resonance (SPR) of single nanostructures. Herein, we report, for the first time, an IR-driven strong plasmonic coupling in an unusual metal/non-metal heterostructure system. This system is fabricated through random assemblage of Ag nanorices (NRs) onto W18O49 nanowires (NWs) film with F-doped SnO2 glass as substrate. Through the 3D-finite element simulation, we demonstrate that the plasmonic coupling between Ag NRs and W18O49 NWs significantly enhances the localized electric fields at the “hot spots”. This achieved magnitudes of 101-104 times of that of incident light, thus leading to the promoted generation of plasmonic “hot-electrons”. Moreover, the resonance excitation of plasmonic coupling on the heterostructures not only induces ultrafast electron transfer from W18O49 to Ag hetero-components, but also the photothermal effect to increase the localized temperature. Upon SPR-coupling excitation, the Ag/W18O49 heterostructures film exhibits a remarkable enhancement of the photo/thermal catalytic activity for H2 evolution from ammonia borane compared to that of either the Ag NRs (˜8.2 × ) or W18O49 NWs (˜9.0 × ) films. Notably, we observed an obvious H2 evolution over the Ag/W18O49 heterostructures film under natural sunlight irradiation.
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Hou, C.-C., Li, Q., Wang, C.-J., Peng, C.-Y., Chen, Q.-Q., Ye, H.-F., Fu, W.-F., Che, C.-M., López, N., & Chen, Y. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01553d · Cited by 267
Cited by
Shandilya, P., Sambyal, S., Sharma, R., Mandyal, P., & Fang, B. (2022) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2022.128218 · Cited by 384
Li, X., Wang, W., Dong, F., Zhang, Z., Han, L., Luo, X., Huang, J., Feng, Z., Chen, Z., Jia, G., et al. (2021) · ACS Catalysis · doi:10.1021/acscatal.0c05354 · Cited by 357
Self-citationLi, Y., Wen, M., Wang, Y., Tian, G., Wang, C., & Zhao, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202010156 · Cited by 284
Metadata
- Authors
- Liu, Y., Zhang, Z., Fang, Y., Liu, B., Huang, J., Miao, F., Bao, Y., & Dong, B.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2019-09
- Volume
- 252
- Pages
- 164-173
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W2940171821
- Cited by
- 214
- References
- 1
- FWCI
- 12.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: IR-Driven strong plasmonic-coupling on Ag nanorices/W18O49 nanowires heterostructures for photo/thermal synergistic enhancement of H2 evolution from ammonia borane. https://app.cochat.ai/papers/10.1016/j.apcatb.2019.04.035
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- Liu, Y., Zhang, Z., Fang, Y., Liu, B., Huang, J., Miao, F., Bao, Y., & Dong, B. (2019). IR-Driven strong plasmonic-coupling on Ag nanorices/W18O49 nanowires heterostructures for photo/thermal synergistic enhancement of H2 evolution from ammonia borane. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.04.035
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