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IR-Driven strong plasmonic-coupling on Ag nanorices/W18O49 nanowires heterostructures for photo/thermal synergistic enhancement of H2 evolution from ammonia borane

Liu, Yang, Zhang, Zhenyi, Fang, Yurui, Liu, Benkang, Huang, Jindou, Miao, Fujun, Bao, Yanan, Dong, Bin·2019·Applied Catalysis B: Environmental

Abstract

Abstract Plasmonic coupling between two or more metal nanostructures has attracted significant interest, since this fascinating near-field interaction is more effective for the aggregation/magnification of the incident light intensity compared to normal surface-plasmon-resonance (SPR) of single nanostructures. Herein, we report, for the first time, an IR-driven strong plasmonic coupling in an unusual metal/non-metal heterostructure system. This system is fabricated through random assemblage of Ag nanorices (NRs) onto W18O49 nanowires (NWs) film with F-doped SnO2 glass as substrate. Through the 3D-finite element simulation, we demonstrate that the plasmonic coupling between Ag NRs and W18O49 NWs significantly enhances the localized electric fields at the “hot spots”. This achieved magnitudes of 101-104 times of that of incident light, thus leading to the promoted generation of plasmonic “hot-electrons”. Moreover, the resonance excitation of plasmonic coupling on the heterostructures not only induces ultrafast electron transfer from W18O49 to Ag hetero-components, but also the photothermal effect to increase the localized temperature. Upon SPR-coupling excitation, the Ag/W18O49 heterostructures film exhibits a remarkable enhancement of the photo/thermal catalytic activity for H2 evolution from ammonia borane compared to that of either the Ag NRs (˜8.2 × ) or W18O49 NWs (˜9.0 × ) films. Notably, we observed an obvious H2 evolution over the Ag/W18O49 heterostructures film under natural sunlight irradiation.

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Metadata

Authors
Liu, Y., Zhang, Z., Fang, Y., Liu, B., Huang, J., Miao, F., Bao, Y., & Dong, B.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2019-09
Volume
252
Pages
164-173
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2940171821
Cited by
214
References
1
FWCI
12.52
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: IR-Driven strong plasmonic-coupling on Ag nanorices/W18O49 nanowires heterostructures for photo/thermal synergistic enhancement of H2 evolution from ammonia borane. https://app.cochat.ai/papers/10.1016/j.apcatb.2019.04.035
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Liu, Y., Zhang, Z., Fang, Y., Liu, B., Huang, J., Miao, F., Bao, Y., & Dong, B. (2019). IR-Driven strong plasmonic-coupling on Ag nanorices/W18O49 nanowires heterostructures for photo/thermal synergistic enhancement of H2 evolution from ammonia borane. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.04.035

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