The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
Plasmonic Hot Electrons from Oxygen Vacancies for Infrared Light‐Driven Catalytic CO2 Reduction on Bi2O3−x
Abstract
Current plasmonic photocatalysts are mainly based on noble metal nanoparticles and rarely work in the infrared (IR) light range. Herein, cost‐effective Bi 2 O 3−x with oxygen vacancies was formed in situ on commercial bismuth powder by calcination at 453.15 K in atmosphere. Interestingly, defects introduced into Bi 2 O 3−x simultaneously induced a localized surface plasmon resonance (LSPR) in the wavelength range of 600–1400 nm and enhanced the adsorption for CO 2 molecules, which enabled efficient photocatalysis of CO 2‐to‐CO (ca. 100 % selectivity) even under low‐intensity near‐IR light irradiation. Significantly, the apparent quantum yield for CO evolution at 940 nm reached 0.113 %, which is approximately 4 times that found at 450 nm. We also showed that the unique LSPR allows for the realization of a nearly linear dependence of photocatalytic CO production rate on light intensity and operating temperature. Finally, based on an IR spectroscopy study, an oxygen‐vacancy induced Mars‐van Krevlen mechanism was proposed to understand the CO 2 reduction reactions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Localized surface plasmon resonances arising from free carriers in doped quantum dots
Luther, J. M., Jain, P. K., Ewers, T., & Alivisatos, A. P. (2011) · Nature Materials · doi:10.1038/nmat3004 · Cited by 1,851
Photochemical transformations on plasmonic metal nanoparticles
Linic, S., Aslam, U., Boerigter, C., & Morabito, M. (2015) · Nature Materials · doi:10.1038/nmat4281 · Cited by 1,701
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
White, J. L., Baruch, M. F., Pander, J. E., Hu, Y., Fortmeyer, I. C., Park, J. E., Zhang, T., Liao, K., Gu, J., Yan, Y., et al. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00370 · Cited by 1,673
Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H2 on Au
Mukherjee, S., Libisch, F., Large, N., Neumann, O., Brown, L. V., Cheng, J., Lassiter, J. B., Carter, E. A., Nordlander, P., & Halas, N. J. (2013) · Nano Letters · doi:10.1021/nl303940z · Cited by 1,583
Lei, F., Sun, Y., Liu, K., Gao, S., Liang, L., Pan, B., & Xie, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501866r · Cited by 1,390
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
An autonomous photosynthetic device in which all charge carriers derive from surface plasmons
Mubeen, S., Lee, J., Singh, N., Krämer, S., Stucky, G. D., & Moskovits, M. (2013) · Nature Nanotechnology · doi:10.1038/nnano.2013.18 · Cited by 1,187
Huang, H., Tu, S., Zeng, C., Zhang, T., Reshak, A. H., & Zhang, Y. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706549 · Cited by 1,041
Atomically-thin two-dimensional sheets for understanding active sites in catalysis
Sun, Y., Gao, S., Lei, F., & Xie, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00236a · Cited by 1,034
Christopher, P., Xin, H., Marimuthu, A., & Linic, S. (2012) · Nature Materials · doi:10.1038/nmat3454 · Cited by 885
Cited by
Oxygen Vacant Semiconductor Photocatalysts
Hao, L., Huang, H., Zhang, Y., & Ma, T. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202100919 · Cited by 579
Role of oxygen vacancy in metal oxides for photocatalytic CO2 reduction
Jiang, W., Loh, H., Low, B. Q. L., Zhu, H., Low, J., Heng, J. Z. X., Tang, K. Y., Li, Z., Loh, X. J., Ye, E., et al. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122079 · Cited by 401
Shangguan, W., Liu, Q., Wang, Y., Sun, N., Liu, Y., Zhao, R., Li, Y., Wang, C., & Zhao, J. (2022) · Nature Communications · doi:10.1038/s41467-022-31474-2 · Cited by 332
Self-citationThermo-photo catalysis: a whole greater than the sum of its parts
Fang, S., & Hu, Y. H. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00782c · Cited by 283
Metadata
- Authors
- Li, Y., Wen, M., Wang, Y., Tian, G., Wang, C., & Zhao, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-11-09
- Volume
- 60
- Issue
- 2
- Pages
- 910-916
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3086218747
- Cited by
- 284
- References
- 49
- FWCI
- 7.56
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Plasmonic Hot Electrons from Oxygen Vacancies for Infrared Light‐Driven Catalytic CO2 Reduction on Bi2O3−x. https://app.cochat.ai/papers/10.1002/anie.202010156
- The paper
- Li, Y., Wen, M., Wang, Y., Tian, G., Wang, C., & Zhao, J. (2021). Plasmonic Hot Electrons from Oxygen Vacancies for Infrared Light‐Driven Catalytic CO2 Reduction on Bi2O3−x. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202010156
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
