The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
NiSe@NiOx core-shell nanowires as a non-precious electrocatalyst for upgrading 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid
Abstract
Abstract A key challenge for the conversion of 5-hydroxymethylfurfural (HMF) into value-added 2,5-furandicarboxylic acid (FDCA) is improving the sluggish kinetics of selective oxidation alcohol groups. Electrocatalysis has been proved to be a green and efficient strategy for heterogeneous synthetic chemistry. Herein, we report an electrocatalyst of NiSe@NiOx core-shell nanowires for efficiently upgrading HMF into FDCA. The NiSe@NiOx features conductive NiSe nanowires as a core and active NiOx as a shell, showing a smaller Tafel slope of 23 mV dec−1 accompanying with a near-quantitative yield of FDCA and 99% Faradaic efficiency (FE). X-ray photoelectron spectroscopy unveils the high valence of Ni species in the NiOx shell may be the active sites. Further integrated electrolyzer can produce FDCA and hydrogen simultaneously, showing a 100% FE even after six successive cycles, disclosing robust stability. All these results demonstrate NiSe@NiOx core-shell nanowires as a promising robust non-precious electrocatalyst for highly efficient biomass transformation.
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Bozell, J. J., & Petersen, G. R. (2010) · Green Chemistry · doi:10.1039/b922014c · Cited by 4,566
Metallic Nickel Nitride Nanosheets Realizing Enhanced Electrochemical Water Oxidation
Xu, K., Chen, P., Li, X., Tong, Y., Ding, H., Wu, X., Chu, W., Peng, Z., Wu, C., & Xie, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5119495 · Cited by 1,115
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Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
Eerhart, A. J. J. E., Faaij, A. P. C., & Patel, M. K. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02480b · Cited by 666
Li, X., Han, G.-Q., Liu, Y.-R., Dong, B., Hu, W.-H., Shang, X., Chai, Y.-M., & Liu, C.-G. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b05597 · Cited by 270
Cited by
Xu, C., Paone, E., Rodríguez-Padrón, D., Luque, R., & Mauriello, F. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00041h · Cited by 1,042
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Yang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
Luo, H., Barrio, J., Sunny, N., Li, A., Steier, L., Shah, N., Stephens, I. E. L., & Titirici, M. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202101180 · Cited by 447
Xu, H., Shang, H., Wang, C., & Du, Y. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213374 · Cited by 322
Metadata
- Authors
- Gao, L., Liu, Z., Ma, J., Zhong, L., Song, Z., Xu, J., Gan, S., Han, D., & Niu, L.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2020-02
- Volume
- 261
- Pages
- 118235
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W2975772735
- Cited by
- 212
- References
- 5
- FWCI
- 7.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, L., Liu, Z., Ma, J., Zhong, L., Song, Z., Xu, J., Gan, S., Han, D., & Niu, L. (2020). NiSe@NiOx core-shell nanowires as a non-precious electrocatalyst for upgrading 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.118235
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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