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One-step synthesis of novel K+ and cyano groups decorated triazine-/heptazine-based g-C3N4 tubular homojunctions for boosting photocatalytic H2 evolution

Yang, Jian, Liang, Yujun, Li, Kai, Yang, Gui, Wang, Kun, Xu, Rui, Xie, Xianjun·2020·Applied Catalysis B: Environmental

Abstract

Abstract Constructing homojunctions with different morphologies, exposing facets, crystal phases or semiconductor types in a photocatalyst is an essential approach to boost the photoactivity. Herein, the g-C3N4 phase homojunctions decorated with cyano groups and K+ were designed and successfully synthesized via only adjusting the reaction temperatures within a facile one-step molten salt route. Such unique junctions were constructed through the overgrowth of triazine-based g-C3N4 nanoparticles embedded in the surface and inner wall of heptazine-based g-C3N4 hollow tubes. Benefited from the multiple advantages of high specific surface area, unique tubular structure, enhanced visible light absorption, and fast charge transfer and separation, the triazine-/heptazine-based g-C3N4 homojunctions drastically enhanced the photocatalytic hydrogen production performance, achieving a 2 and 12-fold improvement than the pristine g-C3N4 microtube and bulk g-C3N4, respectively. This study provides an in-depth insight into the design and fabrication of other g-C3N4-based photocatalysts for more efficient solar energy conversion applications.

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Metadata

Authors
Yang, J., Liang, Y., Li, K., Yang, G., Wang, K., Xu, R., & Xie, X.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2020-03
Volume
262
Pages
118252
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2978696075
Cited by
257
References
57
FWCI
5.88
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: One-step synthesis of novel K+ and cyano groups decorated triazine-/heptazine-based g-C3N4 tubular homojunctions for boosting photocatalytic H2 evolution. https://app.cochat.ai/papers/10.1016/j.apcatb.2019.118252
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Yang, J., Liang, Y., Li, K., Yang, G., Wang, K., Xu, R., & Xie, X. (2020). One-step synthesis of novel K+ and cyano groups decorated triazine-/heptazine-based g-C3N4 tubular homojunctions for boosting photocatalytic H2 evolution. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.118252

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