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Cited by 518

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Synergy between van der waals heterojunction and vacancy in ZnIn2S4/g-C3N4 2D/2D photocatalysts for enhanced photocatalytic hydrogen evolution

Qin, Yingying, Li, Hong, Lu, Jian, Feng, Yonghai, Meng, Fanying, Ma, Changchang, Yan, Yongsheng, Meng, Minjia·2020·Applied Catalysis B: Environmental

Abstract

Abstract Fabricating 2D/2D heterojunction with vacancy is more favorable to the spatial separation and transfer of charge owing to the matching of unique 2D structure and vacancy engineering, but the regulation and observation of interlayer forces and electronic structure is a challenging task for synthesizing heterojunction photocatalyst and studying the photocatalytic hydrogen evolution mechanism. Herein, an original 2D/2D ZnIn2S4/g-C3N4 Van der Waals heterojunction with S vacancies (ZIS-S/CN VDW) photocatalyst are firstly engineered. The optimized 30ZIS-S/g-C3N4 has the highest H2 evolution rate of 6095.1 μmol h−1 g−1, which is primarily attributed to the fact that 2D/2D VDW heterojunction possesses larger contact area and strong electronic interaction to stimulate charge kinetics, and the vacancy engineering can enhance light absorption by regulating the electronic band structure and act as effective active sites for capturing electrons. This work not only enriches 2D/2D heterojunction photocatalytic system based on g-C3N4, but also provides alternative proposal for engineering 2D/2D heterojunction photocatalyst with satisfactory performance.

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Metadata

Authors
Qin, Y., Li, H., Lu, J., Feng, Y., Meng, F., Ma, C., Yan, Y., & Meng, M.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2020-11
Volume
277
Pages
119254
ISSN
0926-3373 (ISSN-L)
OpenAlex
W3036413810
Cited by
518
References
47
FWCI
14.94
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synergy between van der waals heterojunction and vacancy in ZnIn2S4/g-C3N4 2D/2D photocatalysts for enhanced photocatalytic hydrogen evolution. https://app.cochat.ai/papers/10.1016/j.apcatb.2020.119254
The paper
Qin, Y., Li, H., Lu, J., Feng, Y., Meng, F., Ma, C., Yan, Y., & Meng, M. (2020). Synergy between van der waals heterojunction and vacancy in ZnIn2S4/g-C3N4 2D/2D photocatalysts for enhanced photocatalytic hydrogen evolution. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2020.119254

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