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Cited by 169

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Trifle Pt coupled with NiFe hydroxide synthesized via corrosion engineering to boost the cleavage of water molecule for alkaline water-splitting

Zhao, Ying, Gao, Yuxiao, Chen, Zhi, Li, Zhenjiang, Ma, Tianyi, Wu, Zexing, Wang, Lei·2021·Applied Catalysis B: Environmental

Abstract

Abstract Developing cost-effective and highly efficient hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) electrocatalysts with small overpotentials and superior long-term stabilities is imperative for catalyzing water electrolysis. Herein, corrosion engineering is applied to synthesize NiFe-LDH incorporating noble metals on a 3D porous Ni foam at room temperature to afford the NF-Na-Fe-Pt electrocatalyst. The optimized balance adsorption of hydroxyl ions and atomic hydrogen that are manifested by the synergism between NiFe-LDH and trifle noble metals endow the nanomaterial with an excellent electrocatalytic performance and long-term durability for mediating the water-splitting process in 1 M KOH. Only 31 and 261 mV are required to drive 10 mA cm−2 of the prepared NF-Na-Fe-Pt electrocatalyst for HER and OER, respectively. DFT calculations demonstrate that Pt and NiFe-LDH synergistically accelerate the Volmer reaction and adsorption/desorption of atomic H to enhance alkaline HER. Moreover, the NF-Na-Fe-Pt electrocatalyst also exhibit remarkable catalytic activity for water splitting.

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Metadata

Authors
Zhao, Y., Gao, Y., Chen, Z., Li, Z., Ma, T., Wu, Z., & Wang, L.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2021-11
Volume
297
Pages
120395
ISSN
0926-3373 (ISSN-L)
OpenAlex
W3164774549
Cited by
169
References
3
FWCI
6.22
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Trifle Pt coupled with NiFe hydroxide synthesized via corrosion engineering to boost the cleavage of water molecule for alkaline water-splitting. https://app.cochat.ai/papers/10.1016/j.apcatb.2021.120395
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Zhao, Y., Gao, Y., Chen, Z., Li, Z., Ma, T., Wu, Z., & Wang, L. (2021). Trifle Pt coupled with NiFe hydroxide synthesized via corrosion engineering to boost the cleavage of water molecule for alkaline water-splitting. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2021.120395

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