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Synthesis, characterization and rheological behavior of pH sensitive poly(acrylamide-co-acrylic acid) hydrogels

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Nesrinne, Seddiki, Djamel, Aliouche·2017·Arabian Journal of Chemistry

Abstract

Poly(acrylamide-co-acrylic acid) poly(AAm-co-AAc) hydrogels were prepared by free radical polymerization initiated by redox initiators of ammonium peroxodisulphate (APS) and N , N , N ′, N ′-tetramethyl ethylene diamine (TEMED); N , N ′-methylene bisacrylamide (BIS) was employed as a crosslinking agent. The copolymers were characterized by infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), dynamic rheology and swelling measurements. Results indicated that the strong interaction in the hydrogels resulted in the formation of a more stable copolymer. The single glass transition temperature ( T g ) in sample suggested that the two polymers into the hydrogel have a good miscibility. The elastic modulus (G′) and linear viscoelastic region increased with increase in PAAc concentration. The oscillation time sweep study of the hydrogels exhibited a flat G′ indicating a stable structure and good mechanical strength. In the swelling measurements, the gels exhibited appreciable water uptake and were highly sensitive to pH environment. So the poly(AAm-co-AAc) hydrogel will have promising application in pharmaceutical use and in biomaterials.

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Metadata

Authors
Nesrinne, S., & Djamel, A.
Venue
Arabian Journal of Chemistry
Published
2017-05
Volume
10
Issue
4
Pages
539-547
ISSN
1878-5352 (ISSN-L)
OpenAlex
W2013941566
Cited by
253
References
37
FWCI
2.49
Type
journal article
Language
en
Open access
hybrid

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Nesrinne, S., & Djamel, A. (2017). Synthesis, characterization and rheological behavior of pH sensitive poly(acrylamide-co-acrylic acid) hydrogels. Arabian Journal of Chemistry. https://doi.org/10.1016/j.arabjc.2013.11.027

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