Catalytic removal of oxygen from biomass-derived syngas
Abstract
Selective oxygen (O2) removal from wood-derived syngas was investigated over three types of ceria-modified alumina supported metal catalysts (i.e., Pt, Pd, and Cu). Complete O2 removal was observed with the Pt and Pd catalysts at a lower temperature than with the Cu catalyst. Gas hourly space velocity (GHSV) was another critical parameter affecting O2 removal, substantially reducing O2 conversion by all three catalysts at 4000 h(-1) or above. The Cu catalyst appeared to be most sensitive to GHSV. Among three catalysts, the Pd catalyst had the best performance on O2 removal. In addition to reaction conditions, CO2 and water vapor in the syngas also influenced O2 removal, both of which had adverse effects on O2 conversion. Stability tests indicated that both Pt and Pd catalysts were quite stable over a 300 h testing period while the Cu catalyst was deactivated after 50h and regenerated by elevating reaction temperature.
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O2 can be removed by passing the gas over various metal catalysts such as Pt, Pd, and Cu.
“O2 can be removed by passing the gas over various metal catalysts such as Pt, Pd, and Cu (Yan et al., 2013).”
From Gas Fermentation—A Flexible Platform for Commercial Scale Production of Low-Carbon-Fuels and Chemicals from Waste and Renewable Feedstocks (2016) · cites this paper as Yan et al., 2013
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- Authors
- Yan, Q., Wan, C., Street, J., Yan, D. W., Han, J., & Yu, F.
- Affiliations
- Mississippi State University (US)
- Mississippi School for Mathematics and Science (US)
- Wuhan University of Science and Technology (CN)
- Corresponding author
- Yu, Fei
- Venue
- Bioresource Technology
- Publisher
- Elsevier BV
- Published
- 2013-11
- Volume
- 147
- Pages
- 117-123
- ISSN
- 0960-8524 (ISSN-L)
- OpenAlex
- W2076168782
- Cited by
- 18
- References
- 18
- Citations by year
- 2026: 2 · 2024: 1 · 2023: 1 · 2022: 3 · 2020: 3 · 2019: 2 · 2018: 1 · 2017: 1 · 2016: 3 · 2014: 1
- FWCI
- 0.60
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Bioresource Technology (publishedVersion)
- PubMed (publishedVersion)
- Funders
- U.S. Department of Energy (DOE-DE-FG36-06GO86025, DE-FC2608NT01923)
- U.S. Department of Agriculture (AB567370MSU)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Keywords
- biomass-derived syngas, platinum catalysts, palladium catalysts, copper catalysts, gas hourly space velocity, CO2 poisoning, water vapor effect, catalyst stability, catalyst deactivation and regeneration
- MeSH terms
- Catalysis, Gases, Oxygen, Biomass
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