Cited by 96Biofuel production and bioconversionThermochemical Biomass Conversion ProcessesAnaerobic Digestion and Biogas Production

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A kinetic model for hydrothermal pretreatment of sugarcane straw

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dos Santos Rocha, Martha Suzana Rodrigues, Pratto, Bruna, de Sousa, Ruy, Almeida, Renata Maria Rosas Garcia, Cruz, Antonio José Gonçalves da·2017·Bioresource Technology

DOI 10.1016/j.biortech.2016.12.087

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Abstract

This work presents kinetic models of cellulose and hemicellulose extraction during hydrothermal pretreatment of sugarcane straw. Biomass was treated under conditions of 180, 195, and 210°C, using a solid/liquid ratio of 1:10 (w/v). In this study, cellobiose, glucose, formic acid and hydroxymethylfurfural (from cellulosic fraction) and xylose, arabinose, acetic acid, glucuronic acid and furfural (from hemicellulosic fraction) were taken into account in the kinetic parameters determination. The global search algorithm Simulated Annealing was used to fit the models. At 195°C/15min, 85% of hemicellulose and 21% of cellulose removal was reached. For the confidence regions, it was observed that it can be broad, which is coherent with the fact that the parameters are highly correlated. Kinetic models proposed for both cellulosic and hemicellulosic fractions degradation fitted well to the experimental data.

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Optimization by Simulated Annealing
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“( )/ = · + · − ( + ) · (3) Degradation Products (D) Furfural (F)”
Background
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Authors: dos Santos Rocha, M. S. R., Pratto, B., de Sousa, R., Almeida, R. M. R. G., & Cruz, A. J. G. D.
Affiliations: Universidade Federal de São Carlos (BR)
Universidade Federal de Alagoas (BR)
Corresponding author: Cruz, Antonio José Gonçalves da
ORCID: Pratto, Bruna
Almeida, Renata Maria Rosas Garcia
Cruz, Antonio José Gonçalves da
Venue: Bioresource Technology
Publisher: Elsevier BV
Published: 2017-03
Volume: 228
Pages: 176-185
ISSN: 0960-8524 (ISSN-L)
DOI: 10.1016/j.biortech.2016.12.087
OpenAlex: W2567293112
Cited by: 96
References: 46
Citations by year: 2026: 4 · 2025: 5 · 2024: 10 · 2023: 9 · 2022: 13 · 2021: 9 · 2020: 18 · 2019: 8 · 2018: 9 · 2017: 11
FWCI: 4.50
Type: journal article
Language: en
Open access: bronze
doi.org
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/open-access/userlicense/1.0/ (vor, 674 d)
Locations: Bioresource Technology (publishedVersion)
PubMed (publishedVersion)
Funders: Conselho Nacional de Desenvolvimento Científico e Tecnológico
Ministério da Educação
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
Ministério da Ciência, Tecnologia e Inovação
Topics: Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Anaerobic Digestion and Biogas Production
Keywords: hydrothermal pretreatment, sugarcane straw, cellulose degradation, hemicellulose degradation, simulated annealing, kinetic parameter estimation, 5-hydroxymethylfurfural, furfural, cellobiose, xylose, arabinose, glucuronic acid, acetic acid, formic acid
MeSH terms: Cellulose, Hydrolysis, Kinetics, Polysaccharides, Refuse Disposal, Biomass, Saccharum

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A kinetic model for hydrothermal pretreatment of sugarcane straw

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