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A kinetic model for hydrothermal pretreatment of sugarcane straw
Open accessAbstract
This work presents kinetic models of cellulose and hemicellulose extraction during hydrothermal pretreatment of sugarcane straw. Biomass was treated under conditions of 180, 195, and 210°C, using a solid/liquid ratio of 1:10 (w/v). In this study, cellobiose, glucose, formic acid and hydroxymethylfurfural (from cellulosic fraction) and xylose, arabinose, acetic acid, glucuronic acid and furfural (from hemicellulosic fraction) were taken into account in the kinetic parameters determination. The global search algorithm Simulated Annealing was used to fit the models. At 195°C/15min, 85% of hemicellulose and 21% of cellulose removal was reached. For the confidence regions, it was observed that it can be broad, which is coherent with the fact that the parameters are highly correlated. Kinetic models proposed for both cellulosic and hemicellulosic fractions degradation fitted well to the experimental data.
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“Dos Santos Rocha etal. [50] developed a more complex pathway to describe the decomposition of cellulose derived from sugarcane straw, considering cellobiose, glucose, formic acid, and hydroxymethylfurfural (HMF) in the reaction mechanism.”
From Hydrothermal Carbonization of Organic Waste and Biomass: A Review on Process, Reactor, and Plant Modeling (2021) · cites this paper as [50]
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“The model fits well experimental data in a temperature range between 180 and 195 °C, while it overestimates the degradation at 210 °C since it does not consider the difference between crystalline and amorphous cellulose.”
From Hydrothermal Carbonization of Organic Waste and Biomass: A Review on Process, Reactor, and Plant Modeling (2021) · cites this paper as [50]
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Metadata
- Authors
- dos Santos Rocha, M. S. R., Pratto, B., de Sousa, R., Almeida, R. M. R. G., & Cruz, A. J. G. D.
- Affiliations
- Universidade Federal de São Carlos (BR)
- Universidade Federal de Alagoas (BR)
- Corresponding author
- Cruz, Antonio José Gonçalves da
- Venue
- Bioresource Technology
- Publisher
- Elsevier BV
- Published
- 2017-03
- Volume
- 228
- Pages
- 176-185
- ISSN
- 0960-8524 (ISSN-L)
- OpenAlex
- W2567293112
- Cited by
- 96
- References
- 46
- Citations by year
- 2026: 4 · 2025: 5 · 2024: 10 · 2023: 9 · 2022: 13 · 2021: 9 · 2020: 18 · 2019: 8 · 2018: 9 · 2017: 11
- FWCI
- 4.50
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Bioresource Technology (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Conselho Nacional de Desenvolvimento Científico e Tecnológico
- Ministério da Educação
- Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
- Ministério da Ciência, Tecnologia e Inovação
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
- Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Anaerobic Digestion and Biogas Production
- Keywords
- hydrothermal pretreatment, sugarcane straw, cellulose degradation, hemicellulose degradation, simulated annealing, kinetic parameter estimation, 5-hydroxymethylfurfural, furfural, cellobiose, xylose, arabinose, glucuronic acid, acetic acid, formic acid
- MeSH terms
- Cellulose, Hydrolysis, Kinetics, Polysaccharides, Refuse Disposal, Biomass, Saccharum
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