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Unveiling the active sites of graphene-catalyzed peroxymonosulfate activation
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“Theoretical modelling by density functional theory (DFT) further illustrates that defective sites (edge sites, vacancy defects, and voids, etc.) and distorted carbon species that maintain intact sp 2 -hybridization and confine π-electrons and spins in localized area can demonstrate high catalytic potential.57”
From Sustainable remediation with an electroactive biochar system: mechanisms and perspectives (2020) · cites this paper as [57]
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“Theoretically, the PMS molecule (HO-OSO3 -) was able to be cleaved into SO4 •-over ketonic C=O group.57”
From Sustainable remediation with an electroactive biochar system: mechanisms and perspectives (2020) · cites this paper as [57]
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“Calcinating temperature was adopted to readily regulate degrees of defects within carbon lattice.57”
From Sustainable remediation with an electroactive biochar system: mechanisms and perspectives (2020) · cites this paper as [57]
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Metadata
- Authors
- Duan, X., Sun, H., Ao, Z., Zhou, L., Wang, G., & Wang, S.
- Affiliations
- Curtin University (AU)
- Edith Cowan University (AU)
- University of Technology Sydney (AU)
- Corresponding author
- Sun, Hongqi
- Ao, Zhimin
- Wang, Shaobin
- Venue
- Carbon
- Publisher
- Elsevier BV
- Published
- 2016-10
- Volume
- 107
- Pages
- 371-378
- ISSN
- 0008-6223 (ISSN-L)
- OpenAlex
- W2408898971
- Cited by
- 498
- References
- 43
- Citations by year
- 2026: 32 · 2025: 60 · 2024: 62 · 2023: 61 · 2022: 82 · 2021: 69 · 2020: 53 · 2019: 39 · 2018: 20 · 2017: 17 · 2016: 2
- FWCI
- 15.41
- Type
- journal article
- Language
- en
- Open access
- green
- ro.ecu.edu.au
- Locations
- Carbon (publishedVersion)
- Australasian Journal of Paramedicine (submittedVersion)
- Adelaide Research & Scholarship (AR&S) (University of Adelaide) (submittedVersion)
- eSpace (Curtin University) (submittedVersion)
- Funders
- Australian Research Council (ARC DP130101319, DP150103026)
- National Computational Infrastructure
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Keywords
- peroxymonosulfate activation, reduced graphene oxide, active site, oxygen vacancies, catalytic oxidation, oxygen-containing functional groups, adsorption energy
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