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Cited by 9TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.

Substitutionally rhodium(IV)-doped titania showing photocatalytic activity toward organics oxidation under visible-light irradiation

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Yang, Shubin, Ohtani, Bunsho·2021·Catalysis Today

Abstract

Abstract In this study, an aqueous solution containing rhodium(IV) (Rh(IV)) was prepared by oxidation of rhodium(III) (Rh(III)) with solid sodium bismuthate in nitric acid and then used as a medium for hydrothermal titania preparation to obtain rhodium-doped titania (Rh-TiO2) composite. Rh(IV) species were observed in Rh-TiO2 in XPS analysis. Effect of rhodium/titanium molar ratio (Rh/Ti) on the photocatalytic activity was studied. The obtained characteristics suggest successful rhodium substitution and doping of titania to give visible-light absorption. The Rh-TiO2 composite exhibits enhanced photocatalytic activity for acetic acid decomposition and 2-propanol oxidation under UV–vis (> 290 nm) and visible-light (> 450 nm) irradiation, respectively. The enhanced photocatalytic activity is attributable to the visible-light absorption induced by rhodium doping. These results indicate that Rh-TiO2 photocatalyst materials could be promising materials for high-efficiency photooxidation reactions under visible-light irradiation.

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Metadata

Authors
Yang, S., & Ohtani, B.
Affiliations
  • Yantai University (CN)
  • Hokkaido University (JP)
Corresponding author
Yang, Shubin
Venue
Catalysis Today
Publisher
Elsevier BV
Published
2021-11
Volume
380
Pages
25-31
ISSN
0920-5861 (ISSN-L)
OpenAlex
W3173678663
Cited by
9
References
35
Citations by year
2025: 1 · 2024: 1 · 2023: 1 · 2022: 6
FWCI
0.38
Type
journal article
Language
en
Open access
Locations
  • Catalysis Today (publishedVersion)
  • Institutional Repositories DataBase (IRDB) (submittedVersion, cc-by-nc-nd)
  • Hokkaido University Collection of Scholarly and Academic Papers (Hokkaido University) (submittedVersion, cc-by-nc-nd)
Funders
Chinese Academy of Sciences (PECL2019KF014)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
  • Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
Keywords
Rh/TiO2, photocatalysis, visible light photocatalysis, hydrothermal synthesis, acetic acid decomposition, 2-propanol oxidation

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CoChat. (2026). Citation check: Substitutionally rhodium(IV)-doped titania showing photocatalytic activity toward organics oxidation under visible-light irradiation. https://app.cochat.ai/papers/10.1016/j.cattod.2021.06.001
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Yang, S., & Ohtani, B. (2021). Substitutionally rhodium(IV)-doped titania showing photocatalytic activity toward organics oxidation under visible-light irradiation. Catalysis Today. https://doi.org/10.1016/j.cattod.2021.06.001

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