Cited by 119Luminescence and Fluorescent MaterialsPhotochemistry and Electron Transfer StudiesMolecular Sensors and Ion Detection

A general approach to the design of high-performance near-infrared (NIR) D-π-A type fluorescent dyes

Luo, Xiao, Li, Jin, Zhao, Jie, Gu, Luyan, Qian, Xuhong, Yang, Youjun·2019·Chinese Chemical Letters

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Crossref · 10.1016/j.cclet.2019.03.012

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  • The number of Br atoms, as a weak electron-withdrawing group, may effectively shift the emission peak to a longer wavelength as a result of electron delocalization between the D and A moieties of PSP molecules.

    “It can be inferred that the number of the Br atom, as a weak electron-withdrawing group, may effectively shift the emission peak to a longer wavelength as a result of electron delocalization between the D and A moieties of PSP molecules [40].”
  • Stronger electron delocalization ability of a molecule with D-A structure is more favorable to produce longer-wavelength emission.

    “Existing studies show that the stronger the electron delocalization ability of the molecule with the D-A structure, the more favorable it is to produce longer-wavelength emission [40].”

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References 134 · Cited by 119

Authors
Luo, X., Li, J., Zhao, J., Gu, L., Qian, X., & Yang, Y.
Affiliations
  • East China Normal University (CN)
  • East China University of Science and Technology (CN)
Corresponding author
  • Qian, Xuhong
  • Yang, Youjun
Venue
Chinese Chemical Letters
Publisher
Elsevier BV
Published
2019-04
Volume
30
Issue
4
Pages
839-846
ISSN
1001-8417 (ISSN-L)
OpenAlex
W2922226239
Cited by
119
References
134
Citations by year
2026: 11 · 2025: 14 · 2024: 12 · 2023: 16 · 2022: 17 · 2021: 21 · 2020: 20 · 2019: 8
FWCI
5.96
Type
journal article
Language
en
Open access
closed
Locations
Chinese Chemical Letters (publishedVersion)
Funders
  • National Natural Science Foundation of China (21574039, 21822805)
  • Shanghai Municipal Science and Technology Commission (18DZ1112703)
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
  • Physical Sciences › Chemistry › Spectroscopy › Molecular Sensors and Ion Detection
Keywords
near-infrared fluorescent dyes, D-π-A dyes, bioimaging, theranostics, HOMO-LUMO gap, internal conversion, dye aggregation, water solubility

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