A general approach to the design of high-performance near-infrared (NIR) D-π-A type fluorescent dyes
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The number of Br atoms, as a weak electron-withdrawing group, may effectively shift the emission peak to a longer wavelength as a result of electron delocalization between the D and A moieties of PSP molecules.
“It can be inferred that the number of the Br atom, as a weak electron-withdrawing group, may effectively shift the emission peak to a longer wavelength as a result of electron delocalization between the D and A moieties of PSP molecules [40].”
From Red-light excited efficient metal-free near-infrared room-temperature phosphorescent films (2022) · cites this paper as [40]
Stronger electron delocalization ability of a molecule with D-A structure is more favorable to produce longer-wavelength emission.
“Existing studies show that the stronger the electron delocalization ability of the molecule with the D-A structure, the more favorable it is to produce longer-wavelength emission [40].”
From Red-light excited efficient metal-free near-infrared room-temperature phosphorescent films (2022) · cites this paper as [40]
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References 134 · Cited by 119
- Authors
- Luo, X., Li, J., Zhao, J., Gu, L., Qian, X., & Yang, Y.
- Affiliations
- East China Normal University (CN)
- East China University of Science and Technology (CN)
- Corresponding author
- Qian, Xuhong
- Yang, Youjun
- Venue
- Chinese Chemical Letters
- Publisher
- Elsevier BV
- Published
- 2019-04
- Volume
- 30
- Issue
- 4
- Pages
- 839-846
- ISSN
- 1001-8417 (ISSN-L)
- OpenAlex
- W2922226239
- Cited by
- 119
- References
- 134
- Citations by year
- 2026: 11 · 2025: 14 · 2024: 12 · 2023: 16 · 2022: 17 · 2021: 21 · 2020: 20 · 2019: 8
- FWCI
- 5.96
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chinese Chemical Letters (publishedVersion)
- Funders
- National Natural Science Foundation of China (21574039, 21822805)
- Shanghai Municipal Science and Technology Commission (18DZ1112703)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Physical Sciences › Chemistry › Spectroscopy › Molecular Sensors and Ion Detection
- Keywords
- near-infrared fluorescent dyes, D-π-A dyes, bioimaging, theranostics, HOMO-LUMO gap, internal conversion, dye aggregation, water solubility
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