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Recent advances in N-heterocyclic carbene-catalyzed radical reactions
Abstract
Abstract The N-heterocyclic carbene (NHC)-catalyzed reactions involving two-electron reaction pathway have been well-established. However, the development of NHC-catalyzed radical reactions is still in its infancy in terms of reaction types and enantioselectivity. In the past decade, several elegant NHC-catalyzed radical reactions have been developed, including NHC-catalyzed oxidation of aldehydes to esters, reductive coupling reactions using Breslow intermediate as SET reductant and NHC-catalyzed reactions via radical homoenolates, dienoaltes and trienolates. This review summarizes the recent advances in NHC-catalyzed reactions involving radical intermediates.
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Citations
Cites
Pyruvate Ferredoxin Oxidoreductase and Its Radical Intermediate
Ragsdale, S. W. (2003) · Chemical Reviews · doi:10.1021/cr020423e · Cited by 259
Cited by
Liu, K., Schwenzer, M., & Studer, A. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c03996 · Cited by 325
Metadata
- Authors
- Dai, L., & Ye, S.
- Venue
- Chinese Chemical Letters
- Publisher
- Elsevier BV
- Published
- 2021-02
- Volume
- 32
- Issue
- 2
- Pages
- 660-667
- ISSN
- 1001-8417 (ISSN-L)
- OpenAlex
- W3075119080
- Cited by
- 201
- References
- 1
- FWCI
- 8.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dai, L., & Ye, S. (2021). Recent advances in N-heterocyclic carbene-catalyzed radical reactions. Chinese Chemical Letters. https://doi.org/10.1016/j.cclet.2020.08.027
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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