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Spin-crossover in cobalt(II) imine complexes
Open accessAbstract
Whereas there are hundreds of known iron(II) spin-crossover compounds, only a handful of cobalt(II) spin-crossover compounds have been discovered to date, and hardly an in depth study on any of them exists. This review begins with an introduction into the theoretical aspects to be considered when discussing spin-crossover compounds in general and cobalt(II) systems in particular. It is followed by case studies on [Co(bpy)3] 2+ and [Co(terpy)2] 2+ (bpy = 2,2 � -bipyridine, terpy = 2,2 � :6 � ,2 �� -terpyridine) presenting and discussing results from magnetic susceptibility measurements, X-ray crystallography, optical spectroscopy, and EPR spectroscopy.
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Self-citationSpin Crossover in Transition Metal Compounds II
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Structure:function relationships in molecular spin-crossover complexes
Halcrow, M. A. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15046d · Cited by 953
Digital Information Processing in Molecular Systems
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Nandy, A., Duan, C., Taylor, M. G., Liu, F., Steeves, A. H., & Kulik, H. J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00347 · Cited by 358
Biasin, E., van Driel, T. B., Kjær, K. S., Dohn, A. O., Christensen, M., Harlang, T., Chabera, P., Liu, Y., Uhlig, J., Pápai, M., et al. (2016) · Physical Review Letters · doi:10.1103/physrevlett.117.013002 · Cited by 108
Metadata
- Authors
- Krivokapic, I., Zerara, M., Daku, M. L., Vargas, A., Enachescu, C., Ambrus, C., Tregenna-Piggott, P., Amstutz, N., Krausz, E., & Hauser, A.
- Venue
- Coordination Chemistry Reviews
- Publisher
- Elsevier BV
- Published
- 2007-02
- Volume
- 251
- Issue
- 3-4
- Pages
- 364-378
- ISSN
- 0010-8545 (ISSN-L)
- OpenAlex
- W2156493660
- Cited by
- 264
- References
- 18
- FWCI
- 3.38
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Krivokapic, I., Zerara, M., Daku, M. L., Vargas, A., Enachescu, C., Ambrus, C., Tregenna-Piggott, P., Amstutz, N., Krausz, E., & Hauser, A. (2007). Spin-crossover in cobalt(II) imine complexes. Coordination Chemistry Reviews. https://doi.org/10.1016/j.ccr.2006.05.006
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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