Removal of phosphate from aqueous solutions by adsorption onto Ca(OH)2 treated natural clinoptilolite
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A Ca(OH)2-modified zeolite-based adsorbent had a high adsorption capacity for phosphate (167.7 mg/g).
“Mitrogiannis et al.20 successfully prepared a zeolite-based adsorbent modified by Ca(OH)2. They found that the Ca(OH)2-modified adsorbent had high adsorption capacity for phosphate (167.7 mg·g–1).”
From Use of Eggshell-Catalyzed Biochar Adsorbents for Pb Removal from Aqueous Solution (2022) · cites this paper as [20]
The Methods (section 2.1) confirm that the authors prepared a Ca(OH)₂-treated natural zeolite adsorbent. The Conclusions (section 4) describe its phosphate adsorption capacity as good, but report 7.57 mg P/g at 200 mg P/L, not the claimed 167.7 mg/g. (LLM, conf=0.90)
Experimental — accuracy not yet measuredThe -OH group took part in the chemical adsorption process of P.
“After adsorption, the peak at 3641 cm -1 vanished, and it was shown that the -OH took part in the chemical adsorption process of P.”
From Adsorption Removal of Phosphate from Rural Domestic Sewage by Ca-Modified Biochar Derived from Waste Eggshell and Sawdust (2023) · cites this paper as [36]
Chemisorption was the main rate-limiting step of P adsorption by E-C.
“Based on the analysis of the pseudo-second-order theory and the chemisorption characteristics of E-C adsorbent materials, chemisorption was the main rate-limiting step of P adsorption by E-C [ 10 , 24 ].”
From Efficient Adsorption Removal of Phosphate from Rural Domestic Sewage by Waste Eggshell-Modified Peanut Shell Biochar Adsorbent Materials (2023) · cites this paper as [24]
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- Authors
- Mitrogiannis, D., Psychoyou, M., Baziotis, I., Inglezakis, V. J., Koukouzas, N., Tsoukalas, N., Palles, D., Kamitsos, E., Oikonomou, G., & Markou, G.
- Affiliations
- Agricultural University of Athens (GR)
- Nazarbayev University (KZ)
- Centre for Research and Technology Hellas (GR)
- National Hellenic Research Foundation (GR)
- Institute of Geology and Mineral Exploration (GR)
- Corresponding author
- Mitrogiannis, Dimitris
- ORCID
- Venue
- Chemical Engineering Journal
- Publisher
- Elsevier BV
- Published
- 2017-07
- Volume
- 320
- Pages
- 510-522
- ISSN
- 1385-8947 (ISSN-L)
- OpenAlex
- W2596518995
- Cited by
- 292
- References
- 61
- Citations by year
- 2026: 21 · 2025: 33 · 2024: 35 · 2023: 42 · 2022: 40 · 2021: 39 · 2020: 23 · 2019: 24 · 2018: 23 · 2017: 11
- FWCI
- 23.09
- Type
- journal article
- Language
- en
- Open access
- Locations
- Chemical Engineering Journal (publishedVersion)
- Strathprints: The University of Strathclyde institutional repository (University of Strathclyde) (submittedVersion)
- National Hellenic Research Foundation Helios Repository (National Hellenic Research Foundation) (submittedVersion)
- Nazarbayev University Repository (Nazarbayev University) (submittedVersion)
- Topics
- Physical Sciences › Environmental Science › Waste Management and Disposal › Phosphorus and nutrient management
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Health Sciences › Medicine › Nephrology › Parathyroid Disorders and Treatments
- Keywords
- phosphate removal, phosphate adsorption, clinoptilolite, calcium hydroxide pretreatment, natural zeolite, phosphorus recovery, wastewater treatment, slow-release fertilizer, adsorption kinetics, intraparticle diffusion, ligand exchange, calcium phosphate precipitation, surfactant interference, carbonate interference
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