Impact of water matrix on the removal of micropollutants by advanced oxidation technologies
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Competition kinetics is proposed in co-existing matrices if they have a similar or higher bimolecular rate constant with the reactive species.
“Competition kinetics is proposed in co-existing matrices if they have a similar or higher bimolecular rate constant with the reactive species [21-23].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [23]
Section 2, “AOTs and matrix effects” (page unavailable), says that non-target species in water can compete with micropollutants for oxidants and reduce removal kinetics. The paper also lists reaction-rate constants in Table S2, but the passages do not propose a similar-or-higher bimolecular rate constant as the criterion for competition. (LLM, conf=0.82)
Experimental — accuracy not yet measuredCo-existing ions can have a positive effect if secondary radical species have high reactivity towards pollutants, and vice versa.
“In certain cases, the co-existing ions have a positive effect, if the secondary radical species had a high reactivity towards the pollutants and vice versa [23,24].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [23]
Degradation depends on the bimolecular rate constant of reactive species with the target compound.
“Hence, the degradation depends on the bimolecular rate constant of reactive species with the target compound.”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [23]
Co-existing ions affect degradation efficiency through competition kinetics with reactive species.
“All these ions affected the degradation efficiency aligned with competition kinetics with the reactive species.”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [23]
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Flagged first, then by citations
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Cited by
Sorted by citations
Heterogeneous Fenton catalysts: A review of recent advances
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“As a radical species-mediated process, these ions might have an impact on the removal efficiency [21–23].”
- Authors
- Lado Ribeiro, A. R., Moreira, N. F. F., Li Puma, G., & Silva, A. M. T.
- Affiliations
- Universidade do Porto (PT)
- Venue
- Chemical Engineering Journal
- Publisher
- Elsevier BV
- Published
- 2019-05
- Volume
- 363
- Pages
- 155-173
- ISSN
- 1385-8947 (ISSN-L)
- OpenAlex
- W2910988618
- Cited by
- 574
- References
- 170
- Citations by year
- 2026: 68 · 2025: 66 · 2024: 76 · 2023: 89 · 2022: 75 · 2021: 83 · 2020: 76 · 2019: 39
- FWCI
- 23.98
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Chemical Engineering Journal (publishedVersion)
- Nova Science Publishers (Nova Science Publishers, Inc.) (submittedVersion, other-oa)
- Loughborough University Institutional Repository (Loughborough University) (submittedVersion, cc-by-nc-nd)
- Loughborough University Research Repository (Loughborough University) (submittedVersion, cc-by-nc-nd)
- Funders
- European Regional Development Fund
- Fundação para a Ciência e a Tecnologia (POCI-01-0145-FEDER-030521)
- Ministério da Ciência, Tecnologia e Ensino Superior (NORTE-01-0145-FEDER-031049)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Water Treatment and Disinfection
- Physical Sciences › Environmental Science › Pollution › Pharmaceutical and Antibiotic Environmental Impacts
- Keywords
- micropollutants, advanced oxidation processes, water matrix effects, dissolved organic matter, inorganic ions, UV/H2O2, Fenton oxidation, photocatalysis, ozonation, advanced wastewater treatment, reactive oxygen species, catalyst regeneration, iron complexation, nitrate, light attenuation, adsorption
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