The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Formation of hierarchical Bi2MoO6/ln2S3 S-scheme heterojunction with rich oxygen vacancies for boosting photocatalytic CO2 reduction
Abstract
Abstract Employing photocatalytic technology to promote CO2 photoreduction into carbon fuels is of great significance to the field of renewable energy. Herein, the hierarchical Bi2MoO6@In2S3 heterostructured nanotubes rich in surface oxygen vacancies (SOVs) are synthesized by a multi-step control strategy for visible-light-driven CO2 reduction. The combination of density functional theory (DFT) calculations and in-situ X-ray photoelectron spectroscopy (ISI-XPS) confirms the existence of the S-scheme charge transfer mechanism and SOVs, which will accelerate the separation of charges and ameliorate the redox capability. Additionally, the unique hierarchical hollow architectures also effectively promote the efficiency of light utilization and provide abundant reactive sites. Consequently, the optimized Bi2MoO6-SOVs@In2S3 heterogeneous nanotubes display remarkable activity under visible light irradiation, with the yield rate and selectivity for CO-generation are 28.54 μmol g-1 h-1 and 94.1%, respectively. This work provides new opportunities for the design of hierarchical hollow heterojunctions with an S-scheme charge transfer mechanism for effective photocatalytic CO2 reduction.
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Cites
Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst
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Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction
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Cited by
Role of oxygen vacancy in metal oxides for photocatalytic CO2 reduction
Jiang, W., Loh, H., Low, B. Q. L., Zhu, H., Low, J., Heng, J. Z. X., Tang, K. Y., Li, Z., Loh, X. J., Ye, E., et al. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122079 · Cited by 401
Metadata
- Authors
- Yu, B., Wu, Y., Meng, F., Wang, Q., Jia, X., Wasim Khan, M., Huang, C., Zhang, S., Yang, L., & Wu, H.
- Venue
- Chemical Engineering Journal
- Publisher
- Elsevier BV
- Published
- 2022-02
- Volume
- 429
- Pages
- 132456
- ISSN
- 1385-8947 (ISSN-L)
- OpenAlex
- W3199842505
- Cited by
- 308
- References
- 35
- FWCI
- 10.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yu, B., Wu, Y., Meng, F., Wang, Q., Jia, X., Wasim Khan, M., Huang, C., Zhang, S., Yang, L., & Wu, H. (2022). Formation of hierarchical Bi2MoO6/ln2S3 S-scheme heterojunction with rich oxygen vacancies for boosting photocatalytic CO2 reduction. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2021.132456
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