Hydration kinetics in hybrid binders: Early reaction stages
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The alkali excitation reaction explains the formation of the precipitates: dissolution of SiO2 and Al2O3 in fly ash in a strong alkali environment; CaO reacting with silicate and aluminate monomers to form reaction products and C-A-S-H and C-S-H; Na+ balancing charge and being absorbed by the silica-alumina phase to form N-A-S-H; and some Ca2+ displacing Na+ to form C-A-S-H.
“The alkali excitation reaction can explain the formation of the above precipitates: (i) The dissolution of SiO 2 and Al 2 O 3 in fly ash in a strong alkali environment; (ii) A small amount of CaO in fly ash reacts with silicate and aluminate monomers to form reaction products; (iii) Some CaO reacts with silicate and aluminate monomers to form C-A-S-H, and some CaO reacts with silicate monomers to”
From Expansive Soil Stabilization Using Alkali-Activated Fly Ash (2023) · cites this paper as [40]
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One-part alkali-activated materials: A review
Luukkonen, T., Abdollahnejad, Z., Yliniemi, J., Kinnunen, P., & Illikainen, M. (2018) · Cement and Concrete Research · doi:10.1016/j.cemconres.2017.10.001 · Cited by 1,456 · see citing works
Expansive Soil Stabilization Using Alkali-Activated Fly Ash
Wang, H., Liu, T., Yan, C., & Wang, J. (2023) · Processes · doi:10.3390/pr11051550 · Cited by 41 · see citing works
- Authors
- Garcia-Lodeiro, I., Fernandez-Jimenez, A., & Palomo, A.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- ORCID
- Palomo, A.
- Venue
- Cement and Concrete Composites
- Publisher
- Elsevier BV
- Published
- 2013-05
- Volume
- 39
- Pages
- 82-92
- ISSN
- 0958-9465 (ISSN-L)
- OpenAlex
- W2119024071
- Cited by
- 224
- References
- 0
- Citations by year
- 2026: 12 · 2025: 25 · 2024: 24 · 2023: 20 · 2022: 27 · 2021: 23 · 2020: 25 · 2019: 15 · 2018: 13 · 2017: 12 · 2016: 9 · 2015: 12 · 2014: 6 · 2013: 1
- FWCI
- 19.11
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Cement and Concrete Composites (publishedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (acceptedVersion)
- Topics
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Physical Sciences › Materials Science › Materials Chemistry › Magnesium Oxide Properties and Applications
- Physical Sciences › Engineering › Civil and Structural Engineering › Geotechnical Engineering and Soil Stabilization
- Keywords
- hydration kinetics, hybrid binders, fly ash, Portland cement, alkali activation, calcium silicate hydrate, N-A-S-H gel, C-A-S-H gel, secondary phases
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