Recent advances in acid- and base-catalyzed organic synthesis in high-temperature liquid water
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Because of the high ionic product of water, a high H+ and OH- concentration is established in the HTL reaction medium, up to a factor of 1000 larger than at ambient conditions.
“Because of the high ionic product of water, Kw, a high H+ and OH– concentration is established in the reaction medium, up to a factor of 1000 larger than that at ambient conditions.”
From The Impact of Sulfur-Containing Inorganic Compounds during the Depolymerization of Lignin by Hydrothermal Liquefaction of Black Liquor (2024) · cites this paper as [29]
Many acid- or base-catalyzed reactions are accelerated under HTL conditions.
“As a result, many acid- or base-catalyzed reactions are accelerated.28,29”
From The Impact of Sulfur-Containing Inorganic Compounds during the Depolymerization of Lignin by Hydrothermal Liquefaction of Black Liquor (2024) · cites this paper as [29]
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Research works printed but not linked: 31
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Catalytic depolymerization of organosolv sugarcane bagasse lignin in cooperative ionic liquid pairs
Li, Y., Cai, Z., Liao, M., Long, J., Zhao, W., Chen, Y., & Li, X. (2017) · Catalysis Today · doi:10.1016/j.cattod.2017.04.059 · Cited by 40 · see citing works
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Wörner, M., Werner, L., Hornung, U., Islongo Canabarro, N., Baudouin, D., & Dahmen, N. (2024) · Energy & Fuels · doi:10.1021/acs.energyfuels.3c04737 · Cited by 21 · see citing works
- Authors
- Hunter, S. E., & Savage, P. E.
- Affiliations
- University of Michigan (US)
- Corresponding author
- Savage, Phillip E.
- Venue
- Chemical Engineering Science
- Publisher
- Elsevier BV
- Published
- 2004-11
- Volume
- 59
- Issue
- 22-23
- Pages
- 4903-4909
- ISSN
- 0009-2509 (ISSN-L)
- OpenAlex
- W2022838773
- Cited by
- 128
- References
- 0
- Citations by year
- 2026: 5 · 2025: 4 · 2024: 7 · 2023: 7 · 2022: 4 · 2021: 3 · 2020: 2 · 2019: 10 · 2018: 9 · 2017: 4 · 2016: 9 · 2015: 7 · 2014: 6 · 2013: 6 · 2012: 9
- FWCI
- 3.10
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Engineering Science (publishedVersion)
- Funders
- National Science Foundation
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Subcritical and Supercritical Water Processes
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
- Physical Sciences › Chemistry › Organic Chemistry › Microwave-Assisted Synthesis and Applications
- Keywords
- acid-catalyzed reactions, base-catalyzed reactions, solvent-free synthesis, product selectivity, reaction mechanism, water dissociation, green chemistry
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