Experimental determination of the solubility product of magnesite at 50 to 200°C
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The evaporative concentration mechanism cannot explain the precipitation of anhydrous Mg carbonates, and kinetic considerations are needed to justify the formation of these minerals.
“Therefore, the evaporative concentration mechanism cannot explain the precipitation of anhydrous Mg carbonates, and kinetic considerations are needed to justify the formation of these minerals.24,25”
From Mechanisms of Mg carbonates precipitation and implications for CO <sub>2</sub> capture and utilization/storage (2023) · cites this paper as [24]
The lower dielectric constant of the medium assisted the dehydration of Mg2+ cations, inducing a homogeneous classical nucleation in bulk solution (not on substrate surfaces), which does not exclude the formation of amorphous and intermediate crystalline phases.
“It was suggested that the lower dielectric constant of the medium (compared to pure water) assisted the dehydration of the Mg 2+ cations, inducing a homogeneous classical nucleation in bulk solution (not on substrate surfaces), which do not exclude the formation of amorphous and intermediate crystalline phases.”
From Mechanisms of Mg carbonates precipitation and implications for CO <sub>2</sub> capture and utilization/storage (2023) · cites this paper as [24]
Room temperature precipitation of disordered dolomite and high Mg calcite has been achieved by partially replacing water with ethanol.
“The room temperature precipitation of disordered dolomite and high Mg calcite has been achieved by partially replacing water with ethanol.”
From Mechanisms of Mg carbonates precipitation and implications for CO <sub>2</sub> capture and utilization/storage (2023) · cites this paper as [24]
Reacting systems with 75 vol% ethanol, 50 mM MgCl2·6H2O, 10 mM CaCl2·H2O, and 50 mM NaHCO3 yielded protodolomite with close stoichiometry (44 mol% of Mg) to ordered dolomite at 25 °C.
“Reacting systems with 75 vol% of ethanol, 50 mM of MgCl 2 •6H 2 O, 10 mM of CaCl 2 •H 2 O, and 50 mM of NaHCO 3 yielded protodolomite with close stoichiometry (44 mol% of Mg) to the ordered dolomite at 25 °C.”
From Mechanisms of Mg carbonates precipitation and implications for CO <sub>2</sub> capture and utilization/storage (2023) · cites this paper as [24]
The 75 vol% ethanol solution decreased the solvation energy by 4.2-8.4 kJ mol-1, thus assisting the dolomitization reactions.
“Thus, it was argued that the 75 vol% ethanol solution decreased the solvation energy in 4.2-8.4kJ mol -1 , thus assisting the dolomitization reactions.24”
From Mechanisms of Mg carbonates precipitation and implications for CO <sub>2</sub> capture and utilization/storage (2023) · cites this paper as [24]
The Gibbs free energy of the magnesite formation reaction at 25 °C and 1 bar is -1026.48 ± 2 kJ mol-1.
“The Gibbs free energy of this reaction at 25 °C, and 1 bar is -1026.48± 2 kJ mol -1 .23”
From Mechanisms of Mg carbonates precipitation and implications for CO <sub>2</sub> capture and utilization/storage (2023) · cites this paper as [23]
Hydromagnesite is considered to be a metastable phase that transforms to magnesite.
“Although hydromagnesite is considered to be a metastable phase that transforms to magnesite (Be ´ne ´zeth et al., 2011), we found no textural or crystallographic evidence of cogenetic magnesite in the hydrous magnesium carbonates.”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Bénézeth et al., 2011
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- Authors
- Bénézeth, P., Saldi, G. D., Dandurand, J.-L., & Schott, J.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Bénézeth, Pascale
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 2011-06
- Volume
- 286
- Issue
- 1-2
- Pages
- 21-31
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2018304277
- Cited by
- 154
- References
- 3
- Citations by year
- 2026: 10 · 2025: 15 · 2024: 9 · 2023: 6 · 2022: 8 · 2021: 16 · 2020: 9 · 2019: 9 · 2018: 15 · 2017: 9 · 2016: 11 · 2015: 5 · 2014: 13 · 2013: 10 · 2012: 8
- FWCI
- 9.07
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- HAL (submittedVersion)
- Funders
- Agence Nationale de la Recherche
- CHIST-ERA
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
- Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
- Keywords
- magnesite, solubility product, thermodynamic properties, CO2 sequestration, NaCl solution, Gibbs energy of formation, enthalpy, entropy, heat capacity, temperature dependence
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