Cited by 139Atmospheric chemistry and aerosolsToxic Organic Pollutants ImpactAdvanced Combustion Engine Technologies

Characteristics of organic matter in PM2.5 in Shanghai

Feng, Jialiang, Chan, Chak K., Fang, Ming, Hu, Min, He, Lingyan, Tang, Xiaoyan·2006·Chemosphere

Abstract

Solvent extractable organic compounds (SEOC), organic carbon, elemental carbon and water soluble organic carbon (WSOC) in PM(2.5) samples collected in Shanghai, China in 2002 and 2003 were measured to determine the composition and sources of the organic matter in atmospheric aerosols. Distinct seasonal variations were detected with higher concentrations of organic matter in winter. The concentration of total carbon of about 20 microg m(-3) in winter was about three times the summer value. About 30% of the total carbon was water soluble. Unresolved complex mixture (UCM) and fatty acids were the most abundant components quantified in SEOC, similar to other Chinese cities previously studied. High ratio of UCM to n-alkanes (U:R) and the composition of triterpanes indicated that engine exhaust was a major source of the airborne organic matter. Emissions from coal burning had more impact in the rural areas, according to the U:R value and PAHs composition. Chemical mass balance (CMB) modeling shows that about half of the organic carbon was from engine exhaust and about 15% was from coal burning. No clear spatial variation in the concentration of the organic matter was found between urban and rural areas. Our results showed that due to the rapid urbanization and relocation of industrial plants from urban areas to rural areas in the past 20 years, air pollution in rural areas is becoming a serious problem in Shanghai and the Yangtze River delta.

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Crossref · 10.1016/j.chemosphere.2005.12.026

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Authors
Feng, J., Chan, C. K., Fang, M., Hu, M., He, L., & Tang, X.
Affiliations
  • Hong Kong University of Science and Technology (HK)
  • Peking University (CN)
Venue
Chemosphere
Publisher
Elsevier BV
Published
2006-08
Volume
64
Issue
8
Pages
1393-1400
ISSN
0045-6535 (ISSN-L)
OpenAlex
W2093047912
Cited by
139
References
32
Citations by year
2025: 1 · 2024: 4 · 2023: 5 · 2022: 7 · 2021: 4 · 2020: 7 · 2019: 3 · 2018: 4 · 2017: 10 · 2016: 5 · 2015: 17 · 2014: 6 · 2013: 9 · 2012: 11
FWCI
7.38
Type
journal article
Language
en
Open access
closed
Locations
  • Chemosphere (publishedVersion)
  • PubMed (publishedVersion)
Funders
National Natural Science Foundation of China
Topics
  • Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
  • Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Toxic Organic Pollutants Impact
  • Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Advanced Combustion Engine Technologies
Keywords
PM2.5, atmospheric organic matter, water-soluble organic carbon, elemental carbon, unresolved complex mixture, n-alkanes, triterpanes, fatty acids, polycyclic aromatic hydrocarbons, engine exhaust, coal combustion, chemical mass balance, seasonal variation, Shanghai, Yangtze River Delta
MeSH terms
Aerosols, Air Pollutants, China, Environmental Monitoring, Organic Chemicals, Particle Size, Seasons

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