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Microporous Metal-Organic Framework Materials for Gas Separation
Open accessAbstract
Gas separation is a very important industrial process for manufacturing chemicals, fuels, plastics, and polymers but is also energy intensive through the traditional cryogenic distillations. Adsorptive gas separation by porous materials can potentially fulfill the energy-efficient separation economy. Metal-organic frameworks (MOFs), a new generation of porous materials, have been demonstrated for their promise in addressing important gas separations. In this review, we outline the uniqueness and basic design principles of MOF chemistry for gas separation in terms of their specific pore chemistry and molecular recognition. The finely tuned micropores for the high sieving effects and immobilized functional sites on pore surfaces for specific recognition of gas molecules have enabled us to develop a variety of microporous MOFs for many gas separations with both high separation selectivity and productivity. We highlight the major progress and achievements in this very important topic, which will further facilitate the extensive research endeavors and promote their industrial implementation for gas separation.
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Seven chemical separations to change the world
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Self-citationA titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules
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Cited by
Li, D., Yadav, A., Zhou, H., Roy, K., Thanasekaran, P., & Lee, C. (2024) · Global Challenges · doi:10.1002/gch2.202300244 · Cited by 437
Ye, Y., Xian, S., Cui, H., Tan, K., Gong, L., Liang, B., Pham, T., Pandey, H., Krishna, R., Lan, P. C., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c10620 · Cited by 359
Optimizing Pore Space for Flexible-Robust Metal–Organic Framework to Boost Trace Acetylene Removal
Wang, J., Zhang, Y., Zhang, P., Hu, J., Lin, R.-B., Deng, Q., Zeng, Z., Xing, H., Deng, S., & Chen, B. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c02594 · Cited by 253
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Metadata
- Authors
- Lin, R.-B., Xiang, S., Zhou, W., & Chen, B.
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2020-02
- Volume
- 6
- Issue
- 2
- Pages
- 337-363
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W2983039574
- Cited by
- 942
- References
- 8
- FWCI
- 31.25
- Type
- journal article
- Language
- en
- Open access
- bronze
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