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Cited by 281

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Water-based hybrid coatings toward mechanically flexible, super-hydrophobic and flame-retardant polyurethane foam nanocomposites with high-efficiency and reliable fire alarm response

Guo, Kun-Yu, Wu, Qian, Mao, Min, Chen, Heng, Zhang, Guo-Dong, Zhao, Li, Gao, Jie-Feng, Song, Pingan, Tang, Long-Cheng·2020·Composites Part B: Engineering

Abstract

Abstract Flammability feature of combustible polymer foam materials often causes massive casualties and property loss, and it is therefore urgent to develop a green and high-efficiency strategy that can reduce or avoid the fire blaze disasters. Here, an extremely simple water-based coating approach is proposed to prepare mechanically flexible, super-hydrophobic and flame-retardant polyurethane (PU) foam nanocomposites with high-efficiency fire warning response. The hybrid ammonium polyphosphate (APP)/graphene oxide (GO) is decorated onto the PU foam surface via electrostatic interactions followed by surface silane functionalization. Interestingly, the silane and APP molecules present selective distributions on the GO and thus form micro-/nano- rough surface with low water affinity to achieve super-hydrophobicity (e.g. water contact angle of ~158.4°). Meanwhile, such hybrid APP/GO/silane coatings produce synergistic flame resistance for the PU foam materials, which is attributed to the formation of compact and uniform P-Si elements co-covered rGO layer on the foam surface. Further, the hybrid coatings can provide high-efficiency fire warning response under complicated conditions, e.g. flame detection response time of only ~2.0 s and excellent fire early warning time in pre-combustion (e.g. 11.2 s at 300 °C). Therefore, this work provides new perspectives to design and develop multi-functional coatings for fire safety and prevention applications.

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Metadata

Authors
Guo, K.-Y., Wu, Q., Mao, M., Chen, H., Zhang, G.-D., Zhao, L., Gao, J.-F., Song, P., & Tang, L.-C.
Venue
Composites Part B: Engineering
Publisher
Elsevier BV
Published
2020-07
Volume
193
Pages
108017
ISSN
1359-8368 (ISSN-L)
OpenAlex
W3014223841
Cited by
281
References
41
FWCI
16.07
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Water-based hybrid coatings toward mechanically flexible, super-hydrophobic and flame-retardant polyurethane foam nanocomposites with high-efficiency and reliable fire alarm response. https://app.cochat.ai/papers/10.1016/j.compositesb.2020.108017
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Guo, K.-Y., Wu, Q., Mao, M., Chen, H., Zhang, G.-D., Zhao, L., Gao, J.-F., Song, P., & Tang, L.-C. (2020). Water-based hybrid coatings toward mechanically flexible, super-hydrophobic and flame-retardant polyurethane foam nanocomposites with high-efficiency and reliable fire alarm response. Composites Part B: Engineering. https://doi.org/10.1016/j.compositesb.2020.108017

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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