The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Diverse nanocelluloses prepared from TEMPO-oxidized wood cellulose fibers: Nanonetworks, nanofibers, and nanocrystals
Open accessAbstract
Abstract When wood cellulose fibers are oxidized with NaClO and catalytic amounts of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and NaBr in water at pH 10, significant amounts of sodium carboxylate groups (≤1.7 mmol/g) are introduced into the oxidized celluloses. The original fibrous morphologies and cellulose I crystal structures are unchanged by oxidation. The TEMPO-oxidized cellulose fibers can be converted to partially fibrillated nanonetworks, completely individualized cellulose nanofibers with high aspect ratios, and needle-like cellulose nanocrystals with low aspect ratios by controlling the conditions of mechanical disintegration in water. It is therefore possible to prepare diverse nanocelluloses with different morphologies and properties from the same TEMPO-oxidized cellulose fibers, for various end uses and applications. All TEMPO-oxidized nanocelluloses contain large amounts of carboxylate groups. These provide scaffolds for versatile surface modification of nanocelluloses by simple ion exchange of sodium for other metal ions and alkylammonium ions.
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Cites
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Moon, R. J., Martini, A., Nairn, J., Simonsen, J., & Youngblood, J. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00108b · Cited by 6,756
Cellulose nanocrystals: chemistry, self-assembly, and applications
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Nanocelluloses: A New Family of Nature‐Based Materials
Klemm, D., Kramer, F., Moritz, S., Lindström, T., Ankerfors, M., Gray, D., & Dorris, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201001273 · Cited by 4,465
TEMPO-oxidized cellulose nanofibers
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Self-citationMicrofibrillated cellulose and new nanocomposite materials: a review
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Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose
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Self-citationPääkkö, M., Ankerfors, M., Kosonen, H., Nykänen, A., Ahola, S., Österberg, M., Ruokolainen, J., Laine, J., Larsson, P. T., Ikkala, O., et al. (2007) · Biomacromolecules · doi:10.1021/bm061215p · Cited by 1,962
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Self-citationCellulose Nanopaper Structures of High Toughness
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Metadata
- Authors
- Isogai, A., & Zhou, Y.
- Venue
- Current Opinion in Solid State and Materials Science
- Publisher
- Elsevier BV
- Published
- 2019-04
- Volume
- 23
- Issue
- 2
- Pages
- 101-106
- ISSN
- 1359-0286 (ISSN-L)
- OpenAlex
- W2909821471
- Cited by
- 253
- References
- 44
- FWCI
- 1.38
- Type
- journal article
- Language
- en
- Open access
- bronze
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