CoChat
Sign Up
Cited by 8Lignin and Wood ChemistryThermochemical Biomass Conversion ProcessesCoal Properties and Utilization

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

The influence of solvent on the pyrolysis of organosolv lignins extracted from willow

Open access
Wang, Wenli, Liu, Yichen, Wang, Yue, Liu, Longfei, Hu, Changwei·2022·Energy Conversion and Management: X
DOI 10.1016/j.ecmx.2021.100139
Open this paper in CoChat — free accountOpen PDF

Abstract

The targeted application of lignin needs deeper understanding of its physicochemical property. Herein, three kinds of organosolv lignin samples were obtained from willow using three typical organosolv-water co-solvents, and their properties and pyrolysis behaviors were studied by various characterization methods. It was found that the used solvents exerted different effects on lignin samples: lignin extracted from ethyl acetate-water co-solvent possessed more functional groups containing oxygen, and lignin extracted from γ-butyrolactone-water co-solvent contained more large-molecule fragments; the degradation temperature with the maximum rate in thermogravimetric analysis were 352, 384, and 398 ℃ for lignin samples extracted by ethyl acetate/tetrahydrofuran/γ-butyrolactone-water co-solvent, respectively. The cleavage of Cα-Cβ linkage performed more acutely in pyrolysis of lignin extracted from γ-butyrolactone-water co-solvent, while the linkage of C1-Cα in lignin extracted by ethyl acetate/tetrahydrofuran-water co-solvent was more fragile. With regard to the mono-phenolic products, the pyrolysis of lignin extracted from ethyl acetate-water co-solvent yielded guaiacol and 4-methylguaiacol dominantly, and lignin extracted by tetrahydrofuran-water co-solvent produced more guaiacol, 4-ethylguaiacol, and 4-methylguaiacol while lignin extracted by γ-butyrolactone-water co-solvent yielded the maximum amount of 4-methylguaiacol. In addition, the pyrolysis of lignin samples extracted by γ-butyrolactone-water co-solvent yielded only H2, CH4 and CO as gaseous products while the other two yielded H2, CH4, CO and CO2.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1016/j.ecmx.2021.100139

Cites

3 of 3 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Flagged first, then by citations

Research works printed but not linked: 39

  1. Silvestre, 2020, Fodder radish (Raphanus sativus L.) seed cake as a feedstock for pyrolysis, Ind Crops Prod, 154, 10.1016/j.indcrop.2020.112689 · DOI
  2. Fu, 2021, Kinetics of hydrolysis of microalgae biomass during hydrothermal pretreatment, Biomass Bioenergy, 149, 10.1016/j.biombioe.2021.106074 · DOI
  3. Sikarwar, 2016, An overview of advances in biomass gasification, Energy Environ Sci, 9, 2939, 10.1039/C6EE00935B · DOI
  4. Bach, 2017, Pyrolysis characteristics and kinetics of biomass torrefied in various atmospheres, Energy Convers Manage, 141, 72, 10.1016/j.enconman.2016.04.097 · DOI
  5. Chen, 2020, Sustainable biohythane production from algal bloom biomass through two-stage fermentation: Impacts of the physicochemical characteristics and fermentation performance, Int J Hydrogen Energy, 45, 34461, 10.1016/j.ijhydene.2020.02.027 · DOI
  6. Garg, 2016, Pyrolysis of babool seeds (Acacia nilotica) in a fixed bed reactor and bio-oil characterization, Renewable Energy, 96, 167, 10.1016/j.renene.2016.04.059 · DOI
  7. Hu, 2017, Upgrading of bio-oil via acid-catalyzed reactions in alcohols — A mini review, Fuel Process Technol, 155, 2, 10.1016/j.fuproc.2016.08.020 · DOI
  8. Mu, 2013, Lignin Pyrolysis Components and Upgrading—Technology Review, Bioenergy Res, 6, 1183, 10.1007/s12155-013-9314-7 · DOI
  9. Jiang, 2014, Selective conversion of lignin in corncob residue to monophenols with high yield and selectivity, Green Chem, 16, 4257, 10.1039/C4GC00620H · DOI
  10. Vispute, 2010, Renewable Chemical Commodity Feedstocks from Integrated Catalytic Processing of Pyrolysis Oils, Science, 330, 1222, 10.1126/science.1194218 · DOI
  11. Hosseinaei, 2016, Role of Physicochemical Structure of Organosolv Hardwood and Herbaceous Lignins on Carbon Fiber Performance, ACS Sustainable Chem Eng, 4, 5785, 10.1021/acssuschemeng.6b01828 · DOI
  12. Wang, 2020, Effect of Ni(NO3)2 Pretreatment on the Pyrolysis of Organsolv Lignin Derived from Corncob Residue, Processes., 9, 23, 10.3390/pr9010023 · DOI
  13. Zhang, 2020, Relationship between the formation of oligomers and monophenols and lignin structure during pyrolysis process, Fuel, 276, 10.1016/j.fuel.2020.118048 · DOI
  14. Xu, 2020, Biomass Fractionation and Lignin Fractionation towards Lignin Valorization, ChemSusChem, 13, 4284, 10.1002/cssc.202001491 · DOI
  15. Ragauskas, 2014, Lignin valorization: improving lignin processing in the biorefinery, Science, 344, 1246843, 10.1126/science.1246843 · DOI
  16. Wang, 2015, Pyrolysis behaviors of four lignin polymers isolated from the same pine wood, Bioresour Technol, 182, 120, 10.1016/j.biortech.2015.01.127 · DOI · Paper page
  17. Inkrod, 2018, Characteristics of Lignin Extracted from Different Lignocellulosic Materials via Organosolv Fractionation, Bioenergy Res, 11, 277, 10.1007/s12155-018-9895-2 · DOI
  18. Rosado, 2021, Structural Characteristics of the Guaiacyl-Rich Lignins From Rice (Oryza sativa L.) Husks and Straw. Front, Plant Sci., 12
  19. Jiang, 2016, Comparison of the Structural Characteristics of Cellulolytic Enzyme Lignin Preparations Isolated from Wheat Straw Stem and Leaf, ACS Sustainable Chem Eng, 5, 342, 10.1021/acssuschemeng.6b01710 · DOI
  20. Zhang, 2018, Performances of Several Solvents on the Cleavage of Inter- and Intramolecular Linkages of Lignin in Corncob Residue, ChemSusChem, 11, 1494, 10.1002/cssc.201800309 · DOI
  21. Karimi, 2016, A critical review of analytical methods in pretreatment of lignocelluloses: Composition, imaging, and crystallinity, Bioresour Technol, 200, 1008, 10.1016/j.biortech.2015.11.022 · DOI
  22. Liu, 2021, Effect of MgCl2 solution pretreatment on pubescens conversion at room temperature, Renewable Energy, 171, 287, 10.1016/j.renene.2021.02.104 · DOI
  23. Mostofian, 2016, Local Phase Separation of Co-solvents Enhances Pretreatment of Biomass for Bioenergy Applications, J Am Chem Soc, 138, 10869, 10.1021/jacs.6b03285 · DOI
  24. Wang, 2009, Comparison of the pyrolysis behavior of lignins from different tree species, Biotechnol Adv, 27, 562, 10.1016/j.biotechadv.2009.04.010 · DOI
  25. Lv, 2018, Structure characterization and pyrolysis behavior of organosolv lignin isolated from corncob residue, J Anal Appl Pyrol, 136, 115, 10.1016/j.jaap.2018.10.016 · DOI
  26. Soongprasit, 2020, Phenol-derived products from fast pyrolysis of organosolv lignin, Energy Rep, 6, 151, 10.1016/j.egyr.2020.08.040 · DOI · Paper page
  27. Wang, 2019, Room temperature pretreatment of pubescens by AlCl3 aqueous solution, Journal of Energy Chemistry., 31, 138, 10.1016/j.jechem.2018.06.005 · DOI
  28. Shen, 2010, Study on the pyrolytic behaviour of xylan-based hemicellulose using TG–FTIR and Py–GC–FTIR, J Anal Appl Pyrol, 87, 199, 10.1016/j.jaap.2009.12.001 · DOI
  29. Vamvuka, 2003, Pyrolysis characteristics and kinetics of biomass residuals mixtures with lignite☆, Fuel, 82, 1949, 10.1016/S0016-2361(03)00153-4 · DOI
  30. Banks, 2016, Impact of Potassium and Phosphorus in Biomass on the Properties of Fast Pyrolysis Bio-oil, Energy Fuels, 30, 8009, 10.1021/acs.energyfuels.6b01044 · DOI
  31. Wang, 2020, Torrefaction at 200 degrees C of Pubescens Pretreated with AlCl3 Aqueous Solution at Room Temperature, ACS Omega, 5, 27709, 10.1021/acsomega.0c04426 · DOI
  32. Miettinen, 2017, Characterization of fast pyrolysis oil from short-rotation willow by high-resolution Fourier transform ion cyclotron resonance mass spectrometry, Fuel, 207, 189, 10.1016/j.fuel.2017.06.053 · DOI
  33. Asmadi, 2011, Gas- and solid/liquid-phase reactions during pyrolysis of softwood and hardwood lignins, J Anal Appl Pyrol, 92, 417, 10.1016/j.jaap.2011.08.003 · DOI · Paper page
  34. Dai, 2019, Mechanism study on the pyrolysis of the typical ether linkages in biomass, Fuel, 249, 146, 10.1016/j.fuel.2019.03.099 · DOI
  35. Chen, 2018, Co-production of oligosaccharides and fermentable sugar from wheat straw by hydrothermal pretreatment combined with alkaline ethanol extraction, Ind Crops Prod, 111, 78, 10.1016/j.indcrop.2017.10.014 · DOI
  36. Van den Bosch, 2015, Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps, Energy Environ Sci, 8, 1748, 10.1039/C5EE00204D · DOI
  37. del Río, 2012, Structural characterization of wheat straw lignin as revealed by analytical pyrolysis, 2D-NMR, and reductive cleavage methods, J Agric Food Chem, 60, 5922, 10.1021/jf301002n · DOI
  38. Kang, 2012, Isolation and structural characterization of lignin from cotton stalk treated in an ammonia hydrothermal system, Int J Mol Sci, 13, 15209, 10.3390/ijms131115209 · DOI
  39. Fu, 2019, Identification and structural characterization of oligomers formed from the pyrolysis of biomass, J Anal Appl Pyrol, 144, 10.1016/j.jaap.2019.104696 · DOI

Cited by

Sorted by citations

Metadata

Authors
Wang, W., Liu, Y., Wang, Y., Liu, L., & Hu, C.
Affiliations
Sichuan University (CN)
Corresponding author
Hu, Changwei
ORCID
Venue
Energy Conversion and Management: X
Publisher
Elsevier BV
Published
2022-01
Volume
13
Pages
100139
ISSN
2590-1745 (ISSN-L)
DOI
10.1016/j.ecmx.2021.100139
OpenAlex
W3212872589
Cited by
8
References
3
Citations by year
2026: 1 · 2025: 1 · 2024: 4 · 2023: 1 · 2022: 1
FWCI
0.40
Type
journal article
Language
en
Open access
Licence
Locations
  • Energy Conversion and Management X (publishedVersion, cc-by-nc-nd)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
  • National Key Research and Development Program of China (2018YFB1501404)
  • Fundamental Research Funds for the Central Universities
  • Higher Education Discipline Innovation Project (B170307)
Topics
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Lignin and Wood Chemistry
  • Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
  • Physical Sciences › Energy › Fuel Technology › Coal Properties and Utilization
Keywords
organosolv lignin, willow, solvent effects, lignin pyrolysis, gamma-butyrolactone, ethyl acetate, tetrahydrofuran, lignin functional groups, lignin cleavage, guaiacol, 4-methylguaiacol, pyrolysis gas products, lignin extraction

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review