Cited by 16TiO2 Photocatalysis and Solar CellsElectrocatalysts for Energy ConversionAdvanced Photocatalysis Techniques

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Nanocomposites of nickel selenide supported on cube-shaped lidless graphitic boxes as efficient counter electrodes for quasi-solid-state dye-sensitized solar cells

Feng, Chuanqi, Jin, Zhitong, Zhang, Meirong, Wang, Zhong-Sheng·2018·Electrochimica Acta

DOI 10.1016/j.electacta.2018.05.177

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Abstract

Abstract To obtain an efficient electrocatalyst with high conductivity and hence excellent electrocatalytic performance, nanocomposites of nickel selenide supported on cube-shaped lidless graphitic boxes (Graphitic-boxes/NiSe) are prepared as the counter electrode (CE) of quasi-solid-state dye-sensitized solar cells (QSDSSCs). In view of the extraordinary three-dimensional electron transportation pathway and high specific surface area for the cube-shaped graphitic boxes, good catalytic ability of NiSe, and their synergetic effect, the Graphitic-boxes/NiSe nanocomposite exhibits excellent electrocatalytic activity towards the reduction of I 3 − . Furthermore, the Graphitic-boxes/NiSe nanocomposite shows impressive electrochemical stability against the iodine-based electrolyte compared with NiSe and Pt. The QSDSSC with the Graphitic-boxes/NiSe CE yields power conversion efficiency of 8.26%, which is superior to the graphitic boxes CE (2.01%) and the NiSe CE (7.45%) as well, and exhibits good long-term stability.

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Authors: Feng, C., Jin, Z., Zhang, M., & Wang, Z.-S.
Affiliations: Fudan University (CN)
Corresponding author: Wang, Zhong-Sheng
ORCID: Feng, Chuanqi
Jin, Zhitong
Wang, Zhong-Sheng
Venue: Electrochimica Acta
Publisher: Elsevier BV
Published: 2018-08
Volume: 281
Pages: 237-245
ISSN: 0013-4686 (ISSN-L)
DOI: 10.1016/j.electacta.2018.05.177
OpenAlex: W2807267555
Cited by: 16
References: 56
Citations by year: 2025: 1 · 2024: 2 · 2022: 3 · 2021: 4 · 2020: 1 · 2019: 5
FWCI: 0.58
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/legal/tdmrep-license (tdm)
Locations: Electrochimica Acta (publishedVersion)
Funders: Fudan University
Science and Technology Commission of Shanghai Municipality (168014342, 2011-iChEM)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
Keywords: nickel selenide, counter electrode, quasi-solid-state dye-sensitized solar cells, electrocatalysis, iodide reduction, electrochemical stability, nanocomposites, power conversion efficiency, long-term stability

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Nanocomposites of nickel selenide supported on cube-shaped lidless graphitic boxes as efficient counter electrodes for quasi-solid-state dye-sensitized solar cells

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