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Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production

Open access
Wang, Tongzhou, Cao, Xuejie, Jiao, Lifang·2021·eScience

Abstract

Electrochemical water splitting is a sustainable and feasible strategy for hydrogen production but is hampered by the sluggish anodic oxygen evolution reaction (OER). Herein, an effective approach is introduced to significantly decrease the cell voltage by replacing the anodic OER with a urea oxidation reaction (UOR). A Ni2P/NiMoP nanosheet catalyst with a hierarchical architecture is uniformly grown on a nickel foam (NF) substrate through a simple hydrothermal and phosphorization method. The Ni2P/NiMoP achieves impressive HER activity, with a low overpotential of only 22 mV at 10 mA cm–2 and a low Tafel slope of 34.5 mV dec–1. In addition, the oxidation voltage is significantly reduced from 1.49 V to 1.33 V after the introduction of 0.33 M urea. Notably, a two-electrode electrolyzer employing Ni2P/NiMoP as a bifunctional catalyst exhibits a current density of 10 mA cm–2 at a cell voltage of 1.35 V and excellent long-term durability after 80 h.

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Metadata

Authors
Wang, T., Cao, X., & Jiao, L.
Venue
eScience
Publisher
Elsevier BV
Published
2021-11
Volume
1
Issue
1
Pages
69-74
ISSN
2667-1417 (ISSN-L)
OpenAlex
W3199203614
Cited by
386
References
5
FWCI
13.20
Type
journal article
Language
en
Open access
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CoChat. (2026). Citation check: Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production. https://app.cochat.ai/papers/10.1016/j.esci.2021.09.002
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Wang, T., Cao, X., & Jiao, L. (2021). Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production. eScience. https://doi.org/10.1016/j.esci.2021.09.002

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