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Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production
Open accessAbstract
Electrochemical water splitting is a sustainable and feasible strategy for hydrogen production but is hampered by the sluggish anodic oxygen evolution reaction (OER). Herein, an effective approach is introduced to significantly decrease the cell voltage by replacing the anodic OER with a urea oxidation reaction (UOR). A Ni2P/NiMoP nanosheet catalyst with a hierarchical architecture is uniformly grown on a nickel foam (NF) substrate through a simple hydrothermal and phosphorization method. The Ni2P/NiMoP achieves impressive HER activity, with a low overpotential of only 22 mV at 10 mA cm–2 and a low Tafel slope of 34.5 mV dec–1. In addition, the oxidation voltage is significantly reduced from 1.49 V to 1.33 V after the introduction of 0.33 M urea. Notably, a two-electrode electrolyzer employing Ni2P/NiMoP as a bifunctional catalyst exhibits a current density of 10 mA cm–2 at a cell voltage of 1.35 V and excellent long-term durability after 80 h.
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Cites
Electrolysis of low-grade and saline surface water
Tong, W., Forster, M., Dionigi, F., Dresp, S., Sadeghi Erami, R., Strasser, P., Cowan, A. J., & Farràs, P. (2020) · Nature Energy · doi:10.1038/s41560-020-0550-8 · Cited by 1,299
Metallic nanostructures with low dimensionality for electrochemical water splitting
Li, L., Wang, P., Shao, Q., & Huang, X. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00013b · Cited by 1,049
Multifunctional Transition Metal‐Based Phosphides in Energy‐Related Electrocatalysis
Li, Y., Dong, Z., & Jiao, L. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902104 · Cited by 603
Self-citationLiu, Y., Zhang, J., Li, Y., Qian, Q., Li, Z., Zhu, Y., & Zhang, G. (2020) · Nature Communications · doi:10.1038/s41467-020-15563-8 · Cited by 411
Gu, Y., Wu, A., Jiao, Y., Zheng, H., Wang, X., Xie, Y., Wang, L., Tian, C., & Fu, H. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202016102 · Cited by 363
Cited by
PEM water electrolysis for hydrogen production: fundamentals, advances, and prospects
Wang, T., Cao, X., & Jiao, L. (2022) · Carbon Neutrality · doi:10.1007/s43979-022-00022-8 · Cited by 389
Self-citationValence Oscillation of Ru Active Sites for Efficient and Robust Acidic Water Oxidation
Deng, L., Hung, S., Lin, Z., Zhang, Y., Zhang, C., Hao, Y., Liu, S., Kuo, C., Chen, H., Peng, J., et al. (2023) · Advanced Materials · doi:10.1002/adma.202305939 · Cited by 308
Synergistic Engineering of Doping and Vacancy in Ni(OH)2 to Boost Urea Electrooxidation
Qin, H., Ye, Y., Li, J., Jia, W., Zheng, S., Cao, X., Lin, G., & Jiao, L. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202209698 · Cited by 281
Self-citationDeng, L., Chen, H., Hung, S.-F., Zhang, Y., Yu, H., Chen, H.-Y., Li, L., & Peng, S. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.4c14529 · Cited by 281
Comprehensive overview of polyoxometalates for electrocatalytic hydrogen evolution reaction
Zeb, Z., Huang, Y., Chen, L., Zhou, W., Liao, M., Jiang, Y., Li, H., Wang, L., Wang, L., Wang, H., et al. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2023.215058 · Cited by 208
Metadata
- Authors
- Wang, T., Cao, X., & Jiao, L.
- Venue
- eScience
- Publisher
- Elsevier BV
- Published
- 2021-11
- Volume
- 1
- Issue
- 1
- Pages
- 69-74
- ISSN
- 2667-1417 (ISSN-L)
- OpenAlex
- W3199203614
- Cited by
- 386
- References
- 5
- FWCI
- 13.20
- Type
- journal article
- Language
- en
- Open access
- diamond
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