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Glycolysis of poly(ethylene terephthalate) catalyzed by ionic liquids

Open access
Wang, Hui, Liu, Yanqing, Li, Zengxi, Zhang, Xiangping, Zhang, Suojiang, Zhang, Yanqiang·2009·European Polymer Journal

Abstract

Poly(ethylene terephthalate) (PET) from an industrial manufacturer was depolymerized by ethylene glycol in the presence of a novel catalyst: ionic liquids. It was found that the purification process of the products in the glycolysis catalyzed by ionic liquids was simpler than that catalyzed by traditional compounds, such as metal acetate. Qualitative analysis showed that the main product in the glycolysis process was the bis(hydroxyethyl) terephthalate (BHET) monomer. Thermal analysis of the glycolysis products was carried out by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The influences of experimental parameters, such as the amount of catalyst, glycolysis time, reaction temperature, and water content in the catalyst on the conversion of PET, selectivity of BHET, and distribution of the products were investigated. Results show that reaction temperature is a critical factor in this process. In addition, a detailed reaction mechanism of the glycolysis of PET was proposed. (C) 2009 Elsevier Ltd. All rights reserved.

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Metadata

Authors
Wang, H., Liu, Y., Li, Z., Zhang, X., Zhang, S., & Zhang, Y.
Venue
European Polymer Journal
Publisher
Elsevier BV
Published
2009-05
Volume
45
Issue
5
Pages
1535-1544
ISSN
0014-3057 (ISSN-L)
OpenAlex
W1978903529
Cited by
284
References
0
FWCI
6.97
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Glycolysis of poly(ethylene terephthalate) catalyzed by ionic liquids. https://app.cochat.ai/papers/10.1016/j.eurpolymj.2009.01.025
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Wang, H., Liu, Y., Li, Z., Zhang, X., Zhang, S., & Zhang, Y. (2009). Glycolysis of poly(ethylene terephthalate) catalyzed by ionic liquids. European Polymer Journal. https://doi.org/10.1016/j.eurpolymj.2009.01.025

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