Dimethyl ether synthesis via methanol and syngas over rare earth metals modified zeolite Y and dual Cu–Mn–Zn catalysts
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The increase in weak acid sites for La3+ beyond 12LaHY may be related to the presence of EFAL, because the presence of EFAL would increase the weak acid content.
“Further increasing the exchanged content of La3+, the strong acid sites further decrease (which can be seen from Table 5) while the weak acid sites increase, this may be related to the presence of EFAL, because the presence of EFAL would increases the weak acid content26.”
From The effect of positioning cations on acidity and stability of the framework structure of Y zeolite (2016) · cites this paper as [26]
The presence of EFAL would increase the weak acid content.
“whose presence would increases the weak acid content26.”
From The effect of positioning cations on acidity and stability of the framework structure of Y zeolite (2016) · cites this paper as [26]
La3+ is easier moved to sodalite cage and coordinates with framework O3 (which leads to cell expansion) than AE2+ after calcination.
“Both of which indicate that La3+ is easier moved to sodalite cage and coordinates with framework O326 (which leads to cell expansion) than that of AE2+ after calination.”
From The effect of positioning cations on acidity and stability of the framework structure of Y zeolite (2016) · cites this paper as [26]
Dealumination takes place due to the poor stability of AE2+, whose presence increases the weak acid content.
“whereas, the dealumination takes place due to the poor stability of AE2+, whose presence would increases the weak acid content26.”
From The effect of positioning cations on acidity and stability of the framework structure of Y zeolite (2016) · cites this paper as [26]
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- Authors
- Jin, D., Zhu, B., Hou, Z., Fei, J., Lou, H., & Zheng, X.
- Affiliations
- Zhejiang University (CN)
- Corresponding author
- Hou, Zhaoyin
- Venue
- Fuel
- Publisher
- Elsevier BV
- Published
- 2007-12
- Volume
- 86
- Issue
- 17-18
- Pages
- 2707-2713
- ISSN
- 0016-2361 (ISSN-L)
- OpenAlex
- W1995004199
- Cited by
- 165
- References
- 35
- Citations by year
- 2026: 3 · 2025: 1 · 2024: 10 · 2023: 4 · 2022: 7 · 2021: 9 · 2020: 5 · 2019: 15 · 2018: 9 · 2017: 12 · 2016: 19 · 2015: 9 · 2014: 6 · 2013: 9 · 2012: 8
- FWCI
- 3.54
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Fuel (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
- Keywords
- dimethyl ether synthesis, methanol dehydration, CO hydrogenation, syngas, zeolite Y, ion exchange, dual catalyst, catalyst stability, zeolite acidity
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