MnO2 decoration onto the guava leaves: A sustainable and cost-effective material for methylene blue dye removal
Open accessAbstract
Excessive number of dyes in water is becoming the main cause of water pollution, which is very important to remove because it is harmful. Dye contaminated water is being treated by various methods. Adsorption method can be considered best for the study of dye removal due to several technological reasons. The adsorption method has also been emphasized in this study. In the present work, a nano-bio-composite was fabricated by growing manganese oxide nanoparticles on abundant cellulosic guava leaf powder. This allows nanocomposite to be prepared in large quantities at nominal cost. The characterization technique confirmed the irregular growth of manganese oxide nanoparticles onto the guava leaf powder. The electrostatic and non-electrostatic interactions was confirmed in between manganese oxide nanoparticles and the carbon structure of guava leaf powder. The massive functional groups were found to be in the prepared nano-bio-composite. The grain size of prepared material was in nano range. The developed nano-bio-composite was used to remove methylene blue from water. This showed a very good adsorptive capacity for methylene blue. The analyzed adsorption data was modelled through isotherms, kinetics and thermodynamics models. The nature of the adsorption process was determined to be spontaneous and exothermic. The reusability test was carried out for five adsorption-desorption cycles. The reusability results suggested the better removal efficiency (%) in the first two cycles with only 20 % reduction in removal efficiency (%). The leaching test result revealed the good stability of MnO2/GL at neutral pH. It was a unique and cheap adsorbent of its kind, which had not been noticed anywhere before.
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Recent improvements in the integration of nanomaterials with other substances have enhanced their adsorption effectiveness and decreased manufacturing costs, hence increasing their accessibility for large-scale applications.
“Recent improvements in the integration of nanomaterials with other substances have enhanced their adsorption effectiveness and decreased manufacturing costs, hence increasing their accessibility for large-scale applications.114”
From Emerging nanotechnology approaches for sustainable water treatment and heavy metals removal: a comprehensive review (2025) · cites this paper as [114]
The Introduction says combining nanoparticles with other materials can reduce cost and increase production and adsorption efficiency. It also describes biomass as affordable and available in bulk, but does not establish that these improvements have increased accessibility for large-scale applications. (LLM, conf=0.83)
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Cites
Dye and its removal from aqueous solution by adsorption: A review
Yagub, M. T., Sen, T. K., Afroze, S., & Ang, H. M. (2014) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2014.04.002 · Cited by 4,357 · see citing works
Effective removal of anionic textile dyes using adsorbent synthesized from coffee waste
Wong, S. L., Ghafar, N. A., Ngadi, N., Razmi, F. A., Inuwa, I. M., Mat, R., & Amin, N. A. S. (2020) · Scientific Reports · doi:10.1038/s41598-020-60021-6 · Cited by 427 · see citing works
The phytochemistry and medicinal value of Psidium guajava (guava)
Naseer, S., Hussain, S., Naeem, N., Pervaiz, M. A., & Rahman, M. (2018) · Clinical Phytoscience · doi:10.1186/s40816-018-0093-8 · Cited by 393 · see citing works
Investigation of Congo Red Toxicity towards Different Living Organisms: A Review
Siddiqui, S. I., Allehyani, E. S., Al‐Harbi, S. A., et al. (2023) · Processes · doi:10.3390/pr11030807 · Cited by 299 · see citing works
Kumar, N., Pandey, A., Rosy, R., & Sharma, Y. C. (2023) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2023.104054 · Cited by 215 · see citing works
Alrefaee, S. H., Aljohani, M., Alkhamis, K., Shaaban, F., El-Desouky, M. G., El-Bindary, A. A., & El-Bindary, M. A. (2023) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2023.122206 · Cited by 189 · see citing works
Siddiqui, S. I., Manzoor, O., Mohsin, M., & Chaudhry, S. A. (2019) · Environmental Research · doi:10.1016/j.envres.2018.11.044 · Cited by 184 · see citing works
Siddiqui, S. I., & Chaudhry, S. A. (2019) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2019.03.161 · Cited by 167 · see citing works
Altalhi, T., Ibrahim, M. M., Mersal, G. A. M., Mahmoud, M. H. H., Kumeria, T., El‐Desouky, M. G., El-Bindary, A. A., & El‐Bindary, M. A. (2022) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2022.133160 · Cited by 158 · see citing works
El‐Desouky, M. G., Alayyafi, A. A., Al‐Hazmi, G. A. A., & El-Bindary, A. A. (2024) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2024.124392 · Cited by 157 · see citing works
Alsuhaibani, A. M., Alayyafi, A. A., Albedair, L. A., El‐Desouky, M. G., & El-Bindary, A. A. (2024) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2024.124252 · Cited by 136 · see citing works
Wan, X., Yang, S., Cai, Z., et al. (2019) · Nanomaterials · doi:10.3390/nano9060847 · Cited by 135 · see citing works
Alsuhaibani, A. M., Alayyafi, A. A., Albedair, L. A., El‐Desouky, M. G., & El-Bindary, A. A. (2024) · Materials Today Sustainability · doi:10.1016/j.mtsust.2024.100732 · Cited by 128 · see citing works
Almahri, A., Abou‐Melha, K. S., Katouah, H. A., Al-Bonayan, A. M., Saad, F. A., El‐Desouky, M. G., & El-Bindary, A. A. (2023) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2023.136238 · Cited by 116 · see citing works
Analysis of environmental impact of activated carbon production from wood waste
Kim, M. H., Jeong, I. T., Park, S. B., & Kim, J. W. (2018) · Environmental Engineering Research · doi:10.4491/eer.2018.104 · Cited by 97 · see citing works
Handbook of Textile Effluent Remediation
Yusuf, M. (2018) · doi:10.1201/9780429505478 · Cited by 63 · see citing works
Silver based hybrid nanocomposite: A novel antibacterial material for water cleansing
Abdulla, N. K., Siddiqui, S. I., Fatima, B., Sultana, R., Tara, N., Hashmi, A. A., Ahmad, R., Mohsin, M., Nirala, R. K., Linh, N. T., et al. (2020) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2020.124746 · Cited by 61 · see citing works
Al‐Hazmi, G. A. A., El–Zahhar, A. A., El‐Desouky, M. G., El‐Bindary, M. A., & El-Bindary, A. A. (2022) · Environmental Technology · doi:10.1080/09593330.2022.2121181 · Cited by 61 · see citing works
Ullah, A. K. M. A., Haque, M. M., Akter, M., et al. (2020) · Materials Research Express · doi:10.1088/2053-1591/ab6c20 · Cited by 53 · see citing works
Preparation of intercalated MXene by TPAOH and its adsorption characteristics towards U(VI)
Wang, Z.-C., Yang, P.-F., He, X.-X., & Yu, Q.-L. (2024) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/s10967-024-09429-2 · Cited by 51 · see citing works
The impact of water pollution on the health of older people
Bochynska, S., Duszewska, A. M., Maciejewska-Jeske, M., Wrona, M., Szeliga, A., Budzik, M. P., Szczęsnowicz, A., Bala, G., Trzcinski, M., Męczekalski, B., et al. (2024) · Maturitas · doi:10.1016/j.maturitas.2024.107981 · Cited by 49 · see citing works
Tara, N., Siddiqui, S. I., Bach, Q., & Chaudhry, S. A. (2020) · Materials Today Communications · doi:10.1016/j.mtcomm.2020.101560 · Cited by 48 · see citing works
Rathi, G., Siddiqui, S. I., Pham, Q. B., & Nam, V. T. (2020) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2020.100332 · Cited by 46 · see citing works
Fatima, B., Siddiqui, S. I., Ahmed, R., et al. (2019) · Desalination and Water Treatment · doi:10.5004/dwt.2019.24393 · Cited by 45 · see citing works
Effects of Na+/H2O2 on nitrogen removal and sludge activity: Performance and mechanism
Zhang, L., Jiang, S., Jia, Y., et al. (2024) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2024.113194 · Cited by 44 · see citing works
Magnetic activated carbon: A promising approach for the removal of methylene blue from wastewater
Vaddi, D. R., Ramanaiah, M., & Geddapu, S. (2024) · Desalination and Water Treatment · doi:10.1016/j.dwt.2024.100146 · Cited by 43 · see citing works
Joshiba, G. J., Kumar, P. S., Rangasamy, G., et al. (2022) · Environmental Research · doi:10.1016/j.envres.2022.114317 · Cited by 39 · see citing works
Góralczyk-Bińkowska, A., Długoński, A., Bernat, P., et al. (2021) · Scientific Reports · doi:10.1038/s41598-021-03446-x · Cited by 34 · see citing works
Podder, M. S., & Majumder, C. B. (2015) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2015.08.025 · Cited by 32 · see citing works
Dabhane, H., Chatur, S., Jadhav, G., et al. (2021) · Environmental Chemistry and Ecotoxicology · doi:10.1016/j.enceco.2021.04.002 · Cited by 29 · see citing works
Efficient recycling of sewage water in a polyester integrated industry: A case study
Xu, D. Y., Wu, S., Yan, A., et al. (2024) · Desalination and Water Treatment · doi:10.1016/j.dwt.2024.100508 · Cited by 29 · see citing works
Alzahrani, E. A., Dwivedi, P., Fatima, B., et al. (2024) · Journal of Saudi Chemical Society · doi:10.1016/j.jscs.2024.101858 · Cited by 20 · see citing works
Self-citationMatei, E., Predescu, C., Berbecaru, A. C., et al. (2011) · Cited by 18 · see citing works
TEMPO Driven Mild and Modular Route to Functionalized Microparticles
Hafeez, S., Barner, L., & Nebhani, L. (2018) · Macromolecular Rapid Communications · doi:10.1002/marc.201800169 · Cited by 18 · see citing works
Self-citationShehnaz, Prasher, I. B., Ahmad, N., et al. (2023) · Microorganisms · doi:10.3390/microorganisms11061435 · Cited by 16 · see citing works
Hafeez, S., & Nebhani, L. (2019) · Materials Today Communications · doi:10.1016/j.mtcomm.2019.100637 · Cited by 13 · see citing works
Self-citationAktar, J., & Ray, M. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.107707 · Cited by 13 · see citing works
Fatima, B., Alwan, B. A. M. A., Siddiqui, S. I., et al. (2021) · Water · doi:10.3390/w13223287 · Cited by 11 · see citing works
Hafeez, S., Khatri, V., Kashyap, H. K., et al. (2020) · New Journal of Chemistry · doi:10.1039/d0nj02882g · Cited by 9 · see citing works
Self-citationTEMPO driven thiol–ene reaction for the preparation of polymer functionalized silicon wafers
Hafeez, S., & Nebhani, L. (2021) · New Journal of Chemistry · doi:10.1039/d1nj00561h · Cited by 9 · see citing works
Self-citationBactericidal materials prepared via conjugation of responsive polymers to cysteine
Hafeez, S., Jaishankar, J., Srivastava, P., et al. (2020) · Materials Today Communications · doi:10.1016/j.mtcomm.2020.101813 · Cited by 7 · see citing works
Self-citationYadav, P., Hafeez, S., Jaishankar, J., et al. (2021) · Polymer Science Series A · doi:10.1134/s0965545x21050163 · Cited by 6 · see citing works
Self-citationZhai, Y., Xu, X., Wang, H., et al. (2015) · Water Science & Technology · doi:10.2166/wst.2015.020 · Cited by 4 · see citing works
Flagged first, then by citations
Research works printed but not linked: 3
- [3]Ahamad A. Siddiqui S.E. Singh P. Contamination of water: health risk assessment and treatment strategies 2021 Elsevier
- [9]Bistas E. Sanghavi D.K. StatPearls Methylene Blue 2024 Jan StatPearls Publishing Treasure Island (FL) [Updated 2023 Jun 26] https://www.ncbi.nlm.nih.gov/books/NBK557593/ 32491525
- [40]Hafeez S. Sulfur-based advance nanomaterials for water treatment Contamination of Water 2021 Academic Press, Elsevier 405 416
Cited by
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Hussein, E. B., Rasheed, F. A., Mohammed, A. S., & Kayani, K. F. (2025) · RSC Advances · doi:10.1039/d5ra06914a · Cited by 86 · see citing works
“114 In the last ten years, nanoremediation has been extensively used for the treatment of polluted locations, displaying considerable bene ts compared to traditional treatment techniques.”
- Authors
- Komby Abdulla, N., Alzahrani, E. A., Dwivedi, P., Goel, S., Hafeez, S., Khulbe, M., Ilahi Siddiqui, S., & Oh, S.
- Affiliations
- University of Ha'il (SA)
- University of Delhi (IN)
- Villanova University (US)
- Kyung Hee University (KR)
- Corresponding author
- Oh, Seungdae
- Venue
- Heliyon
- Publisher
- Elsevier BV
- Published
- 2024-07
- Volume
- 10
- Issue
- 14
- Pages
- e34267
- ISSN
- 2405-8440 (ISSN-L)
- PMC
- PMC11325273
- OpenAlex
- W4400495890
- Cited by
- 9
- References
- 43
- Citations by year
- 2026: 4 · 2025: 5
- FWCI
- 1.03
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Heliyon (publishedVersion, cc-by-nc-nd)
- PubMed Central (publishedVersion, cc-by-nc-nd)
- PubMed (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- Funders
- Ministry of Environment
- Ministry of Education, India
- Korea Environmental Industry and Technology Institute
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Environmental Science › Water Science and Technology › Coagulation and Flocculation Studies
- Keywords
- manganese oxide nanoparticles, methylene blue adsorption, dye removal, low-cost adsorbent, adsorption isotherms, adsorption kinetics, adsorption thermodynamics, adsorbent reusability, leaching stability, water pollution
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