Engineering crystalline architecture in PLA/PBAT-based blend films through PDLA and talc for high-performance sustainable packaging
Abstract
The limited thermal stability, barrier performance, and inherent brittleness of polylactic acid (PLA) films restrict their widespread use in sustainable food packaging applications compared with conventional polyolefins. Although blending PLA with the compostable polymer poly(butylene adipate-co-terephthalate) (PBAT) is an effective approach in improving flexibility and melt processability, the intrinsically low crystallinity of PLA persists, resulting in suboptimal thermal and barrier properties. To address this challenge, a scalable dual-nucleation strategy was developed by combining poly(D-lactic acid) (PDLA)-induced stereocomplex crystallization with talc-promoted heterogeneous nucleation to enhance the crystallization behavior and functional performance of PLA/PBAT blend films. Films with varying PDLA and talc contents were fabricated via industrially relevant blown film extrusion. FTIR, XRD, and DSC analysis confirmed the formation of thermally stable PLA stereocomplex crystals in the presence of PDLA, leading to increased crystallinity. The addition of talc further accelerated heterogeneous nucleation, promoting faster crystallization and more compact crystalline structures in both the PLA and PBAT phases. In the modified film, improved mechanical properties and thermal stability were observed, while barrier measurements revealed reduced water vapor and oxygen transmission rates. Accelerated shelf-life testing of banana chips stored at 45 °C for 23 days confirmed better moisture control, texture retention, and oxidative stability. Overall, this work establishes PDLA-talc nucleated PLA/PBAT films as a sustainable, bio-based packaging candidate for food applications.
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Cites
Poly(lactide) Stereocomplexes: Formation, Structure, Properties, Degradation, and Applications
Tsuji, H. (2005) · Macromolecular Bioscience · doi:10.1002/mabi.200500062 · Cited by 1,366 · see citing works
Kister, G., Cassanas, G., & Vert, M. (1998) · Polymer · doi:10.1016/s0032-3861(97)00229-2 · Cited by 695 · see citing works
Arruda, L. C., Magaton, M., Bretas, R. E. S., & Ueki, M. M. (2015) · Polymer Testing · doi:10.1016/j.polymertesting.2015.02.005 · Cited by 397 · see citing works
Wang, X., Peng, S., Chen, H., Yu, X., & Zhao, X. (2019) · Composites Part B Engineering · doi:10.1016/j.compositesb.2019.107028 · Cited by 396 · see citing works
Crystallization kinetics of poly(lactic acid)-talc composites
Battegazzore, D., Bocchini, S., & Frache, A. (2011) · eXPRESS Polymer Letters · doi:10.3144/expresspolymlett.2011.84 · Cited by 346 · see citing works
Pan, P., Yang, J., Shan, G., Bao, Y., Weng, Z., 曹阿民, Yazawa, K., & Inoue, Y. (2011) · Macromolecules · doi:10.1021/ma201906a · Cited by 263 · see citing works
Chen, J., Rong, C., Lin, T., Chen, Y., Wu, J., You, J., Wang, H., & Li, Y. (2021) · Macromolecules · doi:10.1021/acs.macromol.0c02861 · Cited by 211 · see citing works
Nguyen, H., Tran, T. H., Hào, L. T., Jeon, H., Koo, J. M., Shin, G., Hwang, D. S., Hwang, S. Y., Park, J., & Oh, D. X. (2021) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2021.118421 · Cited by 174 · see citing works
Jiang, L., Liu, B., & Zhang, J. (2009) · Industrial & Engineering Chemistry Research · doi:10.1021/ie900576f · Cited by 139 · see citing works
Zhang, J., Sato, H., Tsuji, H., Noda, I., & Ozaki, Y. (2004) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2004.11.033 · Cited by 118 · see citing works
Nakayama, D., Wu, F., Mohanty, A. K., Hirai, S., & Misra, M. (2018) · ACS Omega · doi:10.1021/acsomega.8b00823 · Cited by 106 · see citing works
Puchalski, M., Kwolek, S., Szparaga, G., Chrzanowski, M., & Krucińska, I. (2017) · Polymers · doi:10.3390/polym9010018 · Cited by 101 · see citing works
Edible coating and post-frying centrifuge step effect on quality of vacuum-fried banana chips
Sothornvit, R. (2011) · Journal of Food Engineering · doi:10.1016/j.jfoodeng.2011.07.010 · Cited by 93 · see citing works
Park, H.-S., & Hong, C.-K. (2021) · Polymers · doi:10.3390/polym13111851 · Cited by 85 · see citing works
Shi, X., Qin, J., Wang, L., Ren, L., Rong, F., Li, D., Wang, R., & Zhang, G. (2018) · RSC Advances · doi:10.1039/c8ra01570h · Cited by 81 · see citing works
Gao, P., & Masato, D. (2024) · Micromachines · doi:10.3390/mi15060776 · Cited by 70 · see citing works
Bianchi, M., Dorigato, A., Morreale, M., & Pegoretti, A. (2023) · Polymers · doi:10.3390/polym15040881 · Cited by 67 · see citing works
Ding, Y., Zhang, C., Luo, C., Chen, Y., Zhou, Y., Yao, B., Dong, L., Du, X., & Ji, J. (2021) · e-Polymers · doi:10.1515/epoly-2021-0022 · Cited by 65 · see citing works
Thermal, Mechanical and Micromechanical Analysis of PLA/PBAT/POE-g-GMA Extruded Ternary Blends
Aliotta, L., Gigante, V., Acucella, O., Signori, F., & Lazzeri, A. (2020) · Frontiers in Materials · doi:10.3389/fmats.2020.00130 · Cited by 62 · see citing works
Yan, K., Kong, J., Yu, L., Yang, J., Zeng, X., Bai, W., Qian, M., & Dong, H. (2025) · Food Chemistry · doi:10.1016/j.foodchem.2025.143979 · Cited by 60 · see citing works
Prasong, W., Muanchan, P., Ishigami, A., Thumsorn, S., Kurose, T., & Itô, H. (2020) · Journal of Nanomaterials · doi:10.1155/2020/8040517 · Cited by 59 · see citing works
Lee, C., Pang, M. M., Koay, S. C., Choo, H. L., & Tshai, K. Y. (2020) · SN Applied Sciences · doi:10.1007/s42452-020-2172-y · Cited by 51 · see citing works
Tensile properties of PLA/PBAT blends and PLA fibre-reinforced PBAT composite
Sritham, E., Phunsombat, P., & Chaishome, J. (2018) · MATEC Web of Conferences · doi:10.1051/matecconf/201819203014 · Cited by 47 · see citing works
Physicochemical properties and surface free energy of ground talc
TERADA, K. (2004) · Solid State Ionics · doi:10.1016/j.ssi.2004.03.032 · Cited by 43 · see citing works
Recent Advances in PBAT (Nano) Composite Materials for Food Packaging: A Comprehensive Review
Venkatesan, R., Mayakrishnan, V., Alrashed, M. M., & Kim, S. (2025) · Journal of Applied Polymer Science · doi:10.1002/app.57163 · Cited by 42 · see citing works
Yan, J.-Y., Zheng, Y., Zhou, Y.-Q., Liu, Y., Tan, H., Fu, Q., & Ding, M.-M. (2023) · Polymer · doi:10.1016/j.polymer.2023.125985 · Cited by 39 · see citing works
Aaliya, B., Sunooj, K. V., Navaf, M., Akhila, P. P., Sudheesh, C., Sabu, S., Sasidharan, A., Mir, S. A., George, J., & Khaneghah, A. M. (2021) · Applied Food Research · doi:10.1016/j.afres.2021.100013 · Cited by 39 · see citing works
Self-citationFormation of Stereocomplex Crystal and Its Effect on the Morphology and Property of PDLA/PLLA Blends
Su, X., Feng, L., & Yu, D. (2020) · Polymers · doi:10.3390/polym12112515 · Cited by 37 · see citing works
Compatibilization of PLA/PBAT blends with epoxidized canola oil for 3D printing applications
Wahbi, M., Litke, Q., Levin, D. B., Liu, S., France, K. J. D., & Kontopoulou, M. (2024) · Materials Advances · doi:10.1039/d4ma00233d · Cited by 32 · see citing works
George, J., Kumar, R., Jayaprahash, C., Ramakrishna, A., Sabapathy, S. N., & Bawa, A. S. (2006) · Journal of Applied Polymer Science · doi:10.1002/app.24888 · Cited by 29 · see citing works
Self-citationJi, N., Hu, G., Li, J., & Ren, J. (2019) · RSC Advances · doi:10.1039/c8ra09856e · Cited by 26 · see citing works
Helanto, K., Talja, R. A., & Rojas, O. J. (2021) · Journal of Applied Polymer Science · doi:10.1002/app.51225 · Cited by 25 · see citing works
Ahmadi, H., Looijmans, S. F. S. P., van Maris, M. P. F. H. L., Schmit, P., Maraghechi, S., Anderson, P. D., & Cardinaels, R. (2025) · Macromolecules · doi:10.1021/acs.macromol.4c02836 · Cited by 25 · see citing works
Storage stability of banana chips in polypropylene based nanocomposite packaging films
Manikantan, M. R., Sharma, R., Kasturi, R., & Varadharaju, N. (2012) · Journal of Food Science and Technology · doi:10.1007/s13197-012-0839-0 · Cited by 24 · see citing works
Scalable Continuous Manufacturing Process of Stereocomplex PLA by Twin-Screw Extrusion
Alhaj, M., & Narayan, R. (2023) · Polymers · doi:10.3390/polym15040922 · Cited by 22 · see citing works
Lazaro‐Hdez, C., Puerta, A. P. V., Gómez-Caturla, J., Sánchez‐Nacher, L., Boronat, T., & Martínez, J. I. (2025) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2025.142034 · Cited by 22 · see citing works
Xue, J., Tu, H., Shi, J., An, Y., Wan, H., & Bu, X. (2023) · International Journal of Minerals Metallurgy and Materials · doi:10.1007/s12613-022-2582-5 · Cited by 22 · see citing works
Meng, M., Wang, S., Xiao, M., & Meng, Y. (2023) · Sustainable polymer & energy · doi:10.35534/spe.2023.10006 · Cited by 21 · see citing works
Effect of PBAT on Property of PLA/PHB Film Used for Fruits and Vegetables
Ma, X., Wang, Y., Wang, J., & Xu, Y. (2016) · MATEC Web of Conferences · doi:10.1051/matecconf/20178802009 · Cited by 19 · see citing works
Advances in PLA/PBAT-based blend film in food packaging applications: A review
Patil, S., Chawla, R., de Souza, C. K., Ezati, P., Kalita, P., & Roy, S. (2026) · Food Packaging and Shelf Life · doi:10.1016/j.fpsl.2026.101715 · Cited by 18 · see citing works
Ammawath, W., Man, Y. B. C., Yusof, S., & Rahman, R. A. (2002) · Journal of the Science of Food and Agriculture · doi:10.1002/jsfa.1233 · Cited by 18 · see citing works
Behera, K., Tsai, C.-H., Liao, X.-B., & Chiu, F. (2024) · Polymers · doi:10.3390/polym16141971 · Cited by 17 · see citing works
Mai, Q., Zhou, H., & Ou, L. (2021) · Metals · doi:10.3390/met11040651 · Cited by 16 · see citing works
Azevedo, J. V. C., Dorp, E. R., Grimmig, R., Hausnerová, B., & Möginger, B. (2022) · Polymers · doi:10.3390/polym14101939 · Cited by 15 · see citing works
Raju, A. P., George, J., Guthige, M. R., Navaf, M., Sunooj, K. V., Kumar, R., & Semwal, A. D. (2024) · Food Packaging and Shelf Life · doi:10.1016/j.fpsl.2024.101368 · Cited by 13 · see citing works
Self-citationPromoting Effect of Synergetic Nucleating Agent on Crystallization Behavior of Polylactic Acid
Hu, Y., Shen, H., Ni, H., Liu, Y., Zhang, L., & Ju, G. (2025) · Journal of Applied Polymer Science · doi:10.1002/app.56796 · Cited by 8 · see citing works
Biaxial Stretching of PBAT/PLA Blends for Improved Mechanical Properties
Rodriguez, N., Gillor, O., Güvendiren, M., & Axe, L. (2025) · Polymers · doi:10.3390/polym17192651 · Cited by 8 · see citing works
Mokoena, L. S., & Mofokeng, J. P. (2024) · Polymer Engineering and Science · doi:10.1002/pen.26919 · Cited by 7 · see citing works
Smrithy, P. B., George, J., Raju, A. P., Guthige, M. R., Chandrika, G. M., Vasudevan, V., Urs, R. M., & Kumar, R. (2025) · Sustainable Food Technology · doi:10.1039/d5fb00286a · Cited by 7 · see citing works
Self-citationKamdi, H. S., Sivaranjani, S., & Rao, P. S. (2025) · Food and Humanity · doi:10.1016/j.foohum.2025.100781 · Cited by 4 · see citing works
Obtention and Characterization of Bio-Based Composite PBAT/PLA Active Trays for Fresh Food Packaging
Jiménez-Ariza, T., Castellanos-González, S., Garavito, J., & Castellanos, D. A. (2026) · Polymers · doi:10.3390/polym18050665 · Cited by 2 · see citing works
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Zhao, X., Yi, W., Wang, B., Liao, X., Chunxun, L., Fu, D., He, Z., Huang, H., Cao, Z., Peng, Z., et al. (2026) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2026.112460
Ma, J., Long, Z., Huang, J., Li, T., Wang, Y., Wang, S., Zhang, X., & Dong, W. (2026) · Polymer Engineering and Science · doi:10.1002/pen.70927
- Authors
- Bharathan, S. P., Guthige, M. R., Kumar, S., Kumar, R., & George, J.
- Affiliations
- Defence Food Research Laboratory (IN)
- Corresponding author
- George, Johnsy
- Venue
- International Journal of Biological Macromolecules
- Publisher
- Elsevier BV
- Published
- 2026-09
- Volume
- 374
- Pages
- 153379
- ISSN
- 0141-8130 (ISSN-L)
- OpenAlex
- W7167498156
- Cited by
- 2
- References
- 51
- Citations by year
- 2026: 2
- FWCI
- 3.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- International Journal of Biological Macromolecules (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › Nanocomposite Films for Food Packaging
- Keywords
- polylactic acid, poly(butylene adipate-co-terephthalate), poly(D-lactide), talc, stereocomplex crystallization, heterogeneous nucleation, blown film extrusion, food packaging, barrier properties, water vapor transmission, oxygen barrier, shelf life, banana chips, bio-based packaging, crystallinity
- MeSH terms
- Crystallization, Phthalic Acids, Polyesters, Talc, Food Packaging
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