Metal organic frameworks for hydrogen purification
Open accessAbstract
High purity hydrogen is one of the key factors in determining the lifetime of proton exchange membrane (PEM) fuel cells. However, the current industrial processes for producing high purity hydrogen are not only expensive, but also come with low energy efficiencies and productivity. Finding more cost-effective methods of purifying hydrogen is essential for ensuring wider scale deployment of PEM fuel cells. Among various hydrogen purification methods, adsorption in porous materials and membrane technologies are seen as two of the most promising candidates for the current industrial hydrogen purification methods, with metal organic frameworks (MOF) being particularly popular in research over the last decade. Despite many available reviews on MOFs, most focus on synthesis and production, with few reports focused on performance for hydrogen purification. This review describes the working principle and performance parameters of adsorptive separations and membrane materials and identifies MOFs that have been reported for hydrogen purification. The MOFs are summarised and their performance in separating hydrogen from common impurities (CO2, N2, CH4, CO) is compared systematically. The challenges of commercial application of MOFs for hydrogen purification are discussed. © 2020 Hydrogen Energy Publications LLC
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To date, zeolite 5A still remains the most competitive adsorbent for hydrogen purification by PSA.
“To date, zeolite 5A still remains the most competitive adsorbent for this application.380,381”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [380]
Section 4.1.4 (page not available) treats commercial zeolite 5A as a benchmark for hydrogen purification, and Section 4.4 describes its use in simulated PSA beds. Neither establishes that it remains the most competitive adsorbent; Section 4.1.4 instead reports that a comparison suggested UiO-66(Zr)-Br was the most promising material. (LLM, conf=0.84)
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Sorted by citations
Zeolites in Adsorption Processes: State of the Art and Future Prospects
Pérez-Botella, E., Valencia, S., & Rey, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00140 · Cited by 1,126 · see citing works
- Authors
- Mao, D., Griffin, J. M., Dawson, R., Fairhurst, A., & Bimbo, N.
- Affiliations
- Lancaster University (GB)
- Corresponding author
- Bimbo, Nuno
- Venue
- International Journal of Hydrogen Energy
- Publisher
- Elsevier BV
- Published
- 2021-07
- Volume
- 46
- Issue
- 45
- Pages
- 23380-23405
- ISSN
- 0360-3199 (ISSN-L)
- OpenAlex
- W3127212438
- Semantic Scholar
- ca4484b6bcbd7e04c03e10ca657368206d57d94f
- Cited by
- 49
- References
- 149
- Citations by year
- 2026: 7 · 2025: 17 · 2024: 9 · 2023: 9 · 2022: 5 · 2021: 2
- FWCI
- 2.02
- Type
- journal article
- Language
- en
- Open access
- green
- eprints.lancs.ac.uk
- Locations
- International Journal of Hydrogen Energy (publishedVersion)
- ePrints Soton (University of Southampton) (acceptedVersion)
- Lancaster EPrints (Lancaster University) (submittedVersion)
- Funders
- Innovate UK
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Engineering › Mechanical Engineering › Membrane Separation and Gas Transport
- Physical Sciences › Materials Science › Materials Chemistry › Covalent Organic Framework Applications
- Keywords
- metal-organic frameworks, hydrogen purification, hydrogen separation, adsorption, proton exchange membrane fuel cells, hydrogen impurities, carbon dioxide removal, nitrogen removal, methane removal, carbon monoxide removal, membrane materials, adsorption separation
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