Reactions of (E)-N- [2-(benzyliminomethyl)phenyl]-2,6-diisopropylaniline with diethylzinc: Synthesis, characterization and catalytic studies for ring-opening polymerization of ε-caprolactone
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The producing PLA by dinuclear complex 48 had the broader Ð value than that by mononuclear complex 49.
“However, the producing PLA by dinuclear complex 48 had the broader Ð value than that by mononuclear complex 49.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [85]
The high catalytic activity of dinuclear Ti complexes was ascribed to the bridging isopropoxide groups that adjusted the crowded heptacoordinated transition state.
“The high catalytic activity of dinuclear Ti complexes was ascribed to the bridging isopropoxide groups that adjusted the crowded heptacoordinated transition state.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [85]
Dinuclear complex 48 exhibited higher catalytic activity (approximately 60-fold for kobs value) than did complex 49.
“Dinuclear complex 48 exhibited higher catalytic activity (approximately 60fold for k obs value) than did complex 49.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [85]
Cites
Bimetallic Anilido-Aldimine Zinc Complexes for Epoxide/CO2 Copolymerization
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Characterization of a 1:1 Cu−O2Adduct Supported by an Anilido Imine Ligand
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Self-citation(E)-N-[2-(Benzyliminomethyl)phenyl]-2,6-diisopropylaniline
Liu, Y.-C., Lin, C., Chen, H.-L., et al. (2009) · Acta Crystallographica Section E Structure Reports Online · doi:10.1107/s1600536809042202 · Cited by 5 · see citing works
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Wu, L.-J., Lee, W., Kumar Ganta, P., Chang, Y.-L., Chang, Y.-C., & Chen, H.-Y. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214847 · Cited by 96 · see citing works
- Authors
- Wang, C.-H., Li, C.-Y., Lin, C.-H., Liu, Y.-C., & Ko, B.-T.
- Affiliations
- Chung Yuan Christian University (TW)
- Corresponding author
- Ko, Bao-Tsan
- Venue
- Inorganic Chemistry Communications
- Publisher
- Elsevier BV
- Published
- 2011-09
- Volume
- 14
- Issue
- 9
- Pages
- 1456-1460
- ISSN
- 1387-7003 (ISSN-L)
- OpenAlex
- W2031935159
- Cited by
- 25
- References
- 16
- Citations by year
- 2023: 1 · 2022: 2 · 2018: 3 · 2017: 4 · 2016: 3 · 2015: 1 · 2014: 2 · 2013: 4 · 2012: 4
- FWCI
- 1.44
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Inorganic Chemistry Communications (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- diethylzinc, zinc complexes, ε-caprolactone, ring-opening polymerization, 2,6-diisopropylaniline, 4-dimethylaminopyridine, controlled polymerization, polycaprolactone, polyethylene glycol
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