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Cited by 373

The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.

Rational design 2D/2D BiOBr/CDs/g-C3N4 Z-scheme heterojunction photocatalyst with carbon dots as solid-state electron mediators for enhanced visible and NIR photocatalytic activity: Kinetics, intermediates, and mechanism insight

Zhang, Mingming, Lai, Cui, Li, Bisheng, Huang, Danlian, Zeng, Guangming, Xu, Piao, Qin, Lei, Liu, Shiyu, Liu, Xigui, Yi, Huan, Li, Minfang, Chu, Chengcheng, Chen, Zhang·2019·Journal of Catalysis

Abstract

Abstract Rapid recombination of photogenerated carriers and narrow visible light absorption range are two main defects in graphitic carbon nitride (g-C3N4)-based photocatalysts. To address these problems, construction of Z-scheme 2D/2D BiOBr/CDs/g-C3N4 heterojunction photocatalysts with carbon dots as solid-state electron mediators has been investigated. The resultant BiOBr/CDs/g-C3N4 hybrids exhibits remarkable interfacial charge transfer abilities and a broadened solar light absorption range owing to the short charge transport distance and the up-converted photoluminescence character of CDs. Simultaneously, the enhanced specific surface area and nanosheet structure impart more active sites to BiOBr/CDs/g-C3N4 composites. As a result, BiOBr/CDs/g-C3N4 composites reveal significant enhancement in the activity of photodegradation of ciprofloxacin (CIP) and tetracycline (TC) under visible and near infrared (NIR) light irradiation. Moreover, the photodegradation efficiency of BiOBr/CDs/g-C3N4 hybrids was significantly enhanced over that of pristine BiOBr nanosheets and g-C3N4 ultrathin nanosheets. The photocatalytic mechanism is expounded according to free radical capture experiments and electron spin resonance spin-trapping tests and the photodegradation intermediates of CIP were detected by liquid chromatography–mass/mass spectrometry. Moreover, BiOBr/CDs/g-C3N4 composites show excellent photostability and reusability after four runs for CIP degradation.

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Metadata

Authors
Zhang, M., Lai, C., Li, B., Huang, D., Zeng, G., Xu, P., Qin, L., Liu, S., Liu, X., Yi, H., Li, M., Chu, C., & Chen, Z.
Venue
Journal of Catalysis
Publisher
Elsevier BV
Published
2019-01
Volume
369
Pages
469-481
ISSN
0021-9517 (ISSN-L)
OpenAlex
W2904161432
Cited by
373
References
45
FWCI
8.77
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Rational design 2D/2D BiOBr/CDs/g-C3N4 Z-scheme heterojunction photocatalyst with carbon dots as solid-state electron mediators for enhanced visible and NIR photocatalytic activity: Kinetics, intermediates, and mechanism insight. https://app.cochat.ai/papers/10.1016/j.jcat.2018.11.029
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Zhang, M., Lai, C., Li, B., Huang, D., Zeng, G., Xu, P., Qin, L., Liu, S., Liu, X., Yi, H., Li, M., Chu, C., & Chen, Z. (2019). Rational design 2D/2D BiOBr/CDs/g-C3N4 Z-scheme heterojunction photocatalyst with carbon dots as solid-state electron mediators for enhanced visible and NIR photocatalytic activity: Kinetics, intermediates, and mechanism insight. Journal of Catalysis. https://doi.org/10.1016/j.jcat.2018.11.029

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