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The determination of 2-phenylphenol in the presence of 4-chlorophenol using nano-Fe3O4/ionic liquid paste electrode as an electrochemical sensor

Karimi-Maleh, Hassan, Fakude, Colani T., Mabuba, Nonhlagabezo, Peleyeju, Gbenga M., Arotiba, Omotayo A.·2019·Journal of Colloid and Interface Science

Abstract

A voltammetric sensor was fabricated for the determination of 2-phenylphenol (2-PP) as a water pollutant. The sensor was prepared by modifying carbon paste electrode (CPE) with a composite of Fe3O4 nanoparticles (Fe3O4-NPs) and ionic liquid (n-hexyl-3-methylimidazolium hexafluorophosphate; (HMPF6)). The Fe3O4-NPs was synthesized by co-precipitation and characterized by FESEM, MAP, AFM and XRD methods. The presence of Fe3O4-NPs and HMPF6 in CPE improved the catalytic activity of the electrode towards the oxidation of 2-PP. The Fe3O4-NPs/HMPF6/CPE displayed two well separated oxidation signals in a solution containing 2-PP and 4-chlorophenol (4-CP). A peak separation of 380 mV was obtained, which implies that the sensor can be used for the simultaneous determination of the two water contaminants. The Fe3O4-NPs/HMPF6/CPE displayed a linear dynamic range 0.01-520 μM for 2-PP. The sensor showed good recovery data for the analysis of 2-PP and 4-CL in orange rind, lemon rind and different water samples.

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Metadata

Authors
Karimi-Maleh, H., Fakude, C. T., Mabuba, N., Peleyeju, G. M., & Arotiba, O. A.
Venue
Journal of Colloid and Interface Science
Publisher
Elsevier BV
Published
2019-10
Volume
554
Pages
603-610
ISSN
0021-9797 (ISSN-L)
OpenAlex
W2961659600
Cited by
286
References
1
FWCI
18.59
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The determination of 2-phenylphenol in the presence of 4-chlorophenol using nano-Fe3O4/ionic liquid paste electrode as an electrochemical sensor. https://app.cochat.ai/papers/10.1016/j.jcis.2019.07.047
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Karimi-Maleh, H., Fakude, C. T., Mabuba, N., Peleyeju, G. M., & Arotiba, O. A. (2019). The determination of 2-phenylphenol in the presence of 4-chlorophenol using nano-Fe3O4/ionic liquid paste electrode as an electrochemical sensor. Journal of Colloid and Interface Science. https://doi.org/10.1016/j.jcis.2019.07.047

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