The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Reaction mechanism for oxygen evolution on RuO2, IrO2, and RuO2@IrO2 core-shell nanocatalysts
Open accessAbstract
Abstract Iridium dioxide, IrO2, is second to the most active RuO2 catalyst for the oxygen evolution reaction (OER) in acid, and is used in proton exchange membrane water electrolyzers due to its high durability. To improve the activity of IrO2-based catalysts, we prepared RuO2@IrO2 core-shell nanocatalysts using carbon-supported Ru as the template. At 1.48 V, the OER specific activity of RuO2@IrO2 is threefold that of IrO2. While the activity volcano plots over wide range of materials have been reported, zooming into the top region to clarify the rate limiting steps of most active catalysts is important for further activity enhancement. Here, we verified theory-proposed sequential water dissociation pathway in which the O O bond forms on a single metal site, not via coupling of two adsorbed intermediates, by fitting measured polarization curves using a kinetic equation with the free energies of adsorption and activation as the parameters. Consistent with theoretical calculations, we show that the OER activities of IrO2 and RuO2@IrO2 are limited by the formation of O adsorbed phase, while the OOH formation on the adsorbed O limits the reaction rate on RuO2.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
Fabbri, E., Habereder, A., Waltar, K., Kötz, R., & Schmidt, T. J. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00669k · Cited by 1,303
Reier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253
Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106
Wang, J. X., Inada, H., Wu, L., Zhu, Y., Choi, Y., Liu, P., Zhou, W.-P., & Adzic, R. R. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9067645 · Cited by 719
Self-citationCore‐Protected Platinum Monolayer Shell High‐Stability Electrocatalysts for Fuel‐Cell Cathodes
Sasaki, K., Naohara, H., Cai, Y., Choi, Y. M., Liu, P., Vukmirovic, M. B., Wang, J. X., & Adzic, R. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004287 · Cited by 596
Self-citationHsieh, Y.-C., Zhang, Y., Su, D., Volkov, V., Si, R., Wu, L., Zhu, Y., An, W., Liu, P., He, P., et al. (2013) · Nature Communications · doi:10.1038/ncomms3466 · Cited by 229
Self-citation
Cited by
Metallic nanostructures with low dimensionality for electrochemical water splitting
Li, L., Wang, P., Shao, Q., & Huang, X. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00013b · Cited by 1,049
Chen, S., Huang, H., Jiang, P., Yang, K., Diao, J., Gong, S., Liu, S., Huang, M., Wang, H., & Chen, Q. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b04922 · Cited by 574
Self-citationĎurovič, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.229708 · Cited by 436
Plevová, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.230072 · Cited by 278
Wang, Z., Xiao, B., Lin, Z., Shen, S., Xu, A., Du, Z., Chen, Y., & Zhong, W. (2021) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.06.042 · Cited by 141
Metadata
- Authors
- Ma, Z., Zhang, Y., Liu, S., Xu, W., Wu, L., Hsieh, Y.-C., Liu, P., Zhu, Y., Sasaki, K., Renner, J. N., Ayers, K. E., Adzic, R. R., & Wang, J. X.
- Venue
- Journal of Electroanalytical Chemistry
- Publisher
- Elsevier BV
- Published
- 2018-06
- Volume
- 819
- Pages
- 296-305
- ISSN
- 1572-6657 (ISSN-L)
- OpenAlex
- W2765193133
- Cited by
- 247
- References
- 8
- FWCI
- 3.63
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Reaction mechanism for oxygen evolution on RuO2, IrO2, and RuO2@IrO2 core-shell nanocatalysts. https://app.cochat.ai/papers/10.1016/j.jelechem.2017.10.062
- The paper
- Ma, Z., Zhang, Y., Liu, S., Xu, W., Wu, L., Hsieh, Y.-C., Liu, P., Zhu, Y., Sasaki, K., Renner, J. N., Ayers, K. E., Adzic, R. R., & Wang, J. X. (2018). Reaction mechanism for oxygen evolution on RuO2, IrO2, and RuO2@IrO2 core-shell nanocatalysts. Journal of Electroanalytical Chemistry. https://doi.org/10.1016/j.jelechem.2017.10.062
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
