Ordered bilayer ruthenium–platinum core-shell nanoparticles as carbon monoxide-tolerant fuel cell catalysts
Open accessAbstract
Fabricating subnanometre-thick core-shell nanocatalysts is effective for obtaining high surface area of an active metal with tunable properties. The key to fully realize the potential of this approach is a reliable synthesis method to produce atomically ordered core-shell nanoparticles. Here we report new insights on eliminating lattice defects in core-shell syntheses and opportunities opened for achieving superior catalytic performance. Ordered structural transition from ruthenium hcp to platinum fcc stacking sequence at the core-shell interface is achieved via a green synthesis method, and is verified by X-ray diffraction and electron microscopic techniques coupled with density functional theory calculations. The single crystalline Ru cores with well-defined Pt bilayer shells resolve the dilemma in using a dissolution-prone metal, such as ruthenium, for alleviating the deactivating effect of carbon monoxide, opening the door for commercialization of low-temperature fuel cells that can use inexpensive reformates (H2 with CO impurity) as the fuel.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The ordered catalyst layer can provide independent channels.
“To address this issue, the concept of an ordered catalyst layer was proposed, which could provide independent channels [251].”
From Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly (2023) · cites this paper as [251]
Cites
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652 · see citing works
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732 · see citing works
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307 · see citing works
Special points for Brillouin-zone integrations
Monkhorst, H. J., & Pack, J. D. (1976) · Physical Review B · doi:10.1103/physrevb.13.5188 · Cited by 71,721 · see citing works
Ab initio molecular dynamics for liquid metals
Kresse, G., & Häfner, J. (1993) · Physical review. B, Condensed matter · doi:10.1103/physrevb.47.558 · Cited by 45,654 · see citing works
Perdew, J. P., Chevary, J. A., Vosko, S. H., Jackson, K. A., Pederson, M. R., Singh, D. J., & Fiolhais, C. (1992) · Physical review. B, Condensed matter · doi:10.1103/physrevb.46.6671 · Cited by 22,222 · see citing works
Perdew, J. P., Chevary, J. A., Vosko, S. H., Jackson, K. A., Pederson, M. R., Singh, D. J., & Fiolhais, C. (1993) · Physical review. B, Condensed matter · doi:10.1103/physrevb.48.4978.2 · Cited by 17,150 · see citing works
High-precision sampling for Brillouin-zone integration in metals
Methfessel, M., & Paxton, A. T. (1989) · Physical review. B, Condensed matter · doi:10.1103/physrevb.40.3616 · Cited by 7,842 · see citing works
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885 · see citing works
Gasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876 · see citing works
Formation of hollow nanocrystals through the nanoscale kirkendall \neffect
Yin, Y., Rioux, R. M., Erdonmez, C. K., Hughes, S. M., Somorjai, G. A., & Alivisatos, A. P. (2004) · eScholarship (California Digital Library) · Cited by 3,537 · see citing works
Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
Borup, R. L., Meyers, J. P., Pivovar, B. S., Kim, Y. S., Mukundan, R., Garland, N., Myers, D. J., Wilson, M. S., Garzón, F. H., Wood, D. L., et al. (2007) · Chemical Reviews · doi:10.1021/cr050182l · Cited by 3,412 · see citing works
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
Strasser, P., Koh, S., Anniyev, T., Greeley, J., More, K., Yu, C., Liu, Z., Kaya, S., Nordlund, D., Ogasawara, H., et al. (2010) · Nature Chemistry · doi:10.1038/nchem.623 · Cited by 2,984 · see citing works
Denton, A. R., & Ashcroft, N. W. (1991) · Physical Review A · doi:10.1103/physreva.43.3161 · Cited by 2,606 · see citing works
Effect of Strain on the Reactivity of Metal Surfaces
Mavrikakis, M., Hammer, B., & Nørskov, J. K. (1998) · Physical Review Letters · doi:10.1103/physrevlett.81.2819 · Cited by 2,385 · see citing works
Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
Alayoǧlu, S., Nilekar, A. U., Mavrikakis, M., & Eichhorn, B. W. (2008) · Nature Materials · doi:10.1038/nmat2156 · Cited by 1,244 · see citing works
Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106 · see citing works
Surface segregation energies in transition-metal alloys
Ruban, A. V., Skriver, H. L., & Nørskov, J. K. (1999) · Physical review. B, Condensed matter · doi:10.1103/physrevb.59.15990 · Cited by 1,033 · see citing works
Fuel Cells: Principles, Types, Fuels, and Applications
Carrette, L., Friedrich, K. A., & Stimming, U. (2000) · ChemPhysChem · doi:10.1002/1439-7641(20001215)1:4 · Cited by 922 · see citing works
Smigelskas, A. (1947) · Cited by 846 · see citing works
Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt<sub>3</sub>Ni Nanopolyhedra
Zhang, J., Yang, H., Fang, J., & Zou, S. (2010) · Nano Letters · doi:10.1021/nl903717z · Cited by 788 · see citing works
Wang, J. X., Inada, H., Wu, L., Zhu, Y., Choi, Y., Liu, P., Zhou, W.-P., & Adzic, R. R. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9067645 · Cited by 719 · see citing works
Self-citationDependence of PEM fuel cell performance on catalyst loading
Gasteiger, H. A., Panels, J. E., & Yan, S. G. (2004) · Journal of Power Sources · doi:10.1016/j.jpowsour.2003.09.013 · Cited by 670 · see citing works
Core‐Protected Platinum Monolayer Shell High‐Stability Electrocatalysts for Fuel‐Cell Cathodes
Sasaki, K., Naohara, H., Cai, Y., Choi, Y. M., Liu, P., Vukmirovic, M. B., Wang, J. X., & Adzic, R. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004287 · Cited by 596 · see citing works
Self-citationRecent Advances in Preferential Oxidation of CO Reaction over Platinum Group Metal Catalysts
Liu, K., Wang, A., & Zhang, T. (2012) · ACS Catalysis · doi:10.1021/cs200418w · Cited by 462 · see citing works
Study of the Exchange Current Density for the Hydrogen Oxidation and Evolution Reactions
Neyerlin, K. C., Gu, W., Jorné, J., & Gasteiger, H. A. (2007) · Journal of The Electrochemical Society · doi:10.1149/1.2733987 · Cited by 445 · see citing works
High voltage stability of nanostructured thin film catalysts for PEM fuel cells
Debe, M. K., Schmoeckel, A. K., Vernstrom, G. D., & Atanasoski, R. T. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.05.033 · Cited by 420 · see citing works
Gottesfeld, S., & Pafford, J. (1988) · Journal of The Electrochemical Society · doi:10.1149/1.2095401 · Cited by 378 · see citing works
Hong, J. W., Kang, S. W., Choi, B., Kim, D., Lee, S. B., & Han, S. W. (2012) · ACS Nano · doi:10.1021/nn2046828 · Cited by 367 · see citing works
Surface Strain versus Substrate Interaction in Heteroepitaxial Metal Layers: Pt on Ru(0001)
Schlapka, A., Lischka, M., Groß, A., Käsberger, U., & Jakob, P. (2003) · Physical Review Letters · doi:10.1103/physrevlett.91.016101 · Cited by 354 · see citing works
Electrocatalysis of CO tolerance in hydrogen oxidation reaction in PEM fuel cells
Lee, S. J., Mukerjee, S., Ticianelli, E. A., & McBreen, J. (1999) · Electrochimica Acta · doi:10.1016/s0013-4686(99)00052-3 · Cited by 286 · see citing works
Preferential CO Oxidation in Hydrogen: Reactivity of Core−Shell Nanoparticles
Nilekar, A. U., Alayoǧlu, S., Eichhorn, B. W., & Mavrikakis, M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101108w · Cited by 282 · see citing works
Wang, J. X., Ma, C., Choi, Y., Su, D., Zhu, Y., Liu, P., Si, R., Vukmirovic, M. B., Zhang, Y., & Adžić, R. R. (2011) · Journal of the American Chemical Society · doi:10.1021/ja204518x · Cited by 269 · see citing works
Self-citation(2009) · Springer eBooks · doi:10.1007/978-3-540-76735-0_8 · Cited by 267 · see citing works
Alayoǧlu, S., Zavalij, P. Y., Eichhorn, B. W., Wang, Q., Frenkel, A. I., & Chupas, P. J. (2009) · ACS Nano · doi:10.1021/nn900242v · Cited by 247 · see citing works
Pem fuel cells for transportation and stationary power generation applications
Cleghorn, S. (1997) · International Journal of Hydrogen Energy · doi:10.1016/s0360-3199(97)00016-5 · Cited by 243 · see citing works
Transmission Electron Energy Loss Spectrometry in Materials Science and The EELS Atlas
(2004) · Wiley eBooks · doi:10.1002/3527605495 · Cited by 216 · see citing works
Brankovic, S. R., Wang, J. X., & Adžić, R. R. (2001) · Electrochemical and Solid-State Letters · doi:10.1149/1.1414943 · Cited by 209 · see citing works
Self-citationDetector geometry, thermal diffuse scattering and strain effects in ADF STEM imaging
Hillyard, S., & Silcox, J. (1995) · Ultramicroscopy · doi:10.1016/0304-3991(94)00173-k · Cited by 197 · see citing works
Preferential Oxidation of Carbon Monoxide Catalyzed by Platinum Nanoparticles in Mesoporous Silica
Fukuoka, A., Kimura, J., Oshio, T., Sakamoto, Y., & Ichikawa, M. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0703123 · Cited by 185 · see citing works
Xin, H. L., Mundy, J. A., Liu, Z., Cabezas, R., Hovden, R., Kourkoutis, L. F., Zhang, J., Subramanian, N. P., Makharia, R. R., Wagner, F. T., et al. (2011) · Nano Letters · doi:10.1021/nl203975u · Cited by 173 · see citing works
Pan, C., Dassenoy, F., Casanove, M., Philippot, K., Amiens, C., Lecante, P., Mosset, A., & Chaudret, B. N. (1999) · The Journal of Physical Chemistry B · doi:10.1021/jp992072m · Cited by 136 · see citing works
Antolini, E. (2010) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-010-1124-7 · Cited by 103 · see citing works
Wang, J. X., Brankovic, S. R., Zhu, Y., Hanson, J. C., & Adžić, R. R. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1579481 · Cited by 96 · see citing works
Self-citationLow-Coordination Sites in Oxygen-Reduction Electrocatalysis: Their Roles and Methods for Removal
Cai, Y., Ma, C., Zhu, Y., Wang, J. X., & Adzic, R. R. (2011) · Langmuir · doi:10.1021/la200753z · Cited by 80 · see citing works
Self-citationPtxRu1−x/Ru(0001) surface alloys—formation and atom distribution
Hoster, H. E., Bergbreiter, A., Erne, P. M., Hager, T., Rauscher, H., & Behm, R. J. (2008) · Physical Chemistry Chemical Physics · doi:10.1039/b802169d · Cited by 76 · see citing works
Transmission electron energy loss spectrometry in materials science and the EELS atlas
Ahn, C. C. (2004) · Cited by 53 · see citing works
Controlled Synthesis and Characterization of Rucore−PtshellBimetallic Nanoparticles
Hwang, B., Sarma, L. S., Chen, C., Bock, C., Lai, F., Chang, S., Yen, S.-C., Liu, D., Sheu, H., & Lee, J. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp807154a · Cited by 47 · see citing works
Displacement reaction of Pt on carbon-supported Ru nanoparticles in hexachloroplatinic acids
Hsieh, Y.-C., Chang, L.-C., Wu, P., Chang, Y.-M., & Lee, J. (2011) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2011.01.017 · Cited by 29 · see citing works
Self-citationSun, K., Liu, J., Nag, N. K., & Browning, N. D. (2002) · Catalysis Letters · doi:10.1023/a:1021428003587 · Cited by 29 · see citing works
Interaction of CO and deuterium with bimetallic, monolayer Pt-island/film covered Ru(0001) surfaces
Hartmann, H., Diemant, T., Bansmann, J., & Behm, R. J. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp41434a · Cited by 24 · see citing works
Cheng, T. T. H., Jia, N., & He, P. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3356939 · Cited by 23 · see citing works
Self-citationOxygen adsorption on Pt/Ru(0001) layers
Jakob, P., Schlapka, A., & Gazdzicki, P. (2011) · The Journal of Chemical Physics · doi:10.1063/1.3598957 · Cited by 19 · see citing works
Relative Humidity Effect on Anode Durability in PEMFC Startup/Shutdown Processes
He, P., Cheng, T. T. H., Bashyam, R., Young, A. P., & Knights, S. (2010) · ECS Transactions · doi:10.1149/1.3484620 · Cited by 10 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Das, S., Pérez‐Ramírez, J., Gong, J., Dewangan, N., Hidajat, K., Gates, B. C., & Kawi, S. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00713j · Cited by 884 · see citing works
Catalysis of Alloys: Classification, Principles, and Design for a Variety of Materials and Reactions
Nakaya, Y., & Furukawa, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00356 · Cited by 419 · see citing works
Wang, A., He, X.-J., Lu, X. F., Xu, H., Tong, Y., & Li, G. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201410792 · Cited by 282 · see citing works
Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly
Mo, S., Du, L., Huang, Z., Chen, J., Zhou, Y., Wu, P., Meng, L., Wang, N., Xing, L., Zhao, M., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00190-w · Cited by 277 · see citing works
“To address this issue, the concept of an ordered catalyst layer was proposed, which could provide independent channels [251].”
Self-citationMa, S., Li, H., Hu, B., Cheng, X., Fu, Q., & Yu, S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01482 · Cited by 263 · see citing works
Single Crystalline Co3O4 Nanocrystals Exposed with Different Crystal Planes for Li-O2 Batteries
Su, D., Dou, S. X., & Wang, G. (2014) · Scientific Reports · doi:10.1038/srep05767 · Cited by 260 · see citing works
Self-citationReaction mechanism for oxygen evolution on RuO2, IrO2, and RuO2@IrO2 core-shell nanocatalysts
Ma, Z., Zhang, Y., Liu, S., Xu, W., Wu, L., Hsieh, Y.-C., Liu, P., Zhu, Y., Sasaki, K., Renner, J., et al. (2017) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2017.10.062 · Cited by 250 · see citing works
Self-citationHou, J., Yang, M., Ke, C., Wei, G., Priest, C. M., Qiao, Z., Wu, G., & Zhang, J. (2019) · EnergyChem · doi:10.1016/j.enchem.2019.100023 · Cited by 246 · see citing works
Shabani, B., Hafttananian, M., Khamani, S., Ramiar, A., & Ranjbar, A. A. (2019) · Journal of Power Sources · doi:10.1016/j.jpowsour.2019.03.097 · Cited by 246 · see citing works
Elbert, K., Hu, J., Ma, Z., Zhang, Y., Chen, G., An, W., Liu, P., Isaacs, H. S., Adzic, R. R., & Wang, J. X. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01670 · Cited by 241 · see citing works
Self-citationElectrocatalysts for PEM Fuel Cells
Ioroi, T., Siroma, Z., Yamazaki, S., & Yasuda, K. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201801284 · Cited by 226 · see citing works
Li, H., Ma, S., Fu, Q., Liu, X., Wu, L., & Yu, S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03877 · Cited by 213 · see citing works
Self-citationAdding two active silver atoms on Au₂₅ nanoparticle.
Yao, C.-H., Chen, J.-S., Li, M., Liu, L., Yang, J.-L., & Wu, Z.-K. (2015) · Nano letters (Print) · doi:10.1021/nl504477t · Cited by 156 · see citing works
X-ray scattering characterisation of nanoparticles
Ingham, B. (2015) · Crystallography Reviews · doi:10.1080/0889311x.2015.1024114 · Cited by 189 · see citing works
Yang, X., Wang, Y., Wang, X., Mei, B., Luo, E., Li, Y., Meng, Q., Jin, Z., Jiang, Z., Liu, C., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202110900 · Cited by 182 · see citing works
Matin, M. A., Lee, E., Kim, H., Yoon, W., & Kwon, Y. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta03809j · Cited by 182 · see citing works
Zhang, S., Hao, Y., Su, D., Doan-Nguyen, V. V. T., Wu, Y., Li, J., Sun, S., & Murray, C. B. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5099066 · Cited by 179 · see citing works
Self-citationGao, W., Hood, Z. D., & Chi, M. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00596 · Cited by 180 · see citing works
Qin, X., Zhang, L., Xu, G., Zhu, S., Wang, Q., Gu, M. D., Zhang, X., Sun, C., Balbuena, P. B., Amine, K., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b01744 · Cited by 174 · see citing works
Ayers, K. E., Renner, J., Danilovic, N., Wang, J. X., Zhang, Y., Marić, R., & Yu, H. (2015) · Catalysis Today · doi:10.1016/j.cattod.2015.10.019 · Cited by 171 · see citing works
Self-citationLuo, H., Wang, K., Lin, F., Lv, F., Zhou, J., Zhang, W., Wang, D., Zhang, W., Zhang, Q., Gu, L., et al. (2023) · Advanced Materials · doi:10.1002/adma.202211854 · Cited by 162 · see citing works
Shaping electrocatalysis through tailored nanomaterials
Kang, Y., Yang, P., Marković, N. M., & Stamenković, V. R. (2016) · Nano Today · doi:10.1016/j.nantod.2016.08.008 · Cited by 154 · see citing works
Advanced electron microscopy characterization of nanomaterials for catalysis
Su, D. (2017) · Green Energy & Environment · doi:10.1016/j.gee.2017.02.001 · Cited by 149 · see citing works
Self-citationA review of core-shell nanostructured electrocatalysts for oxygen reduction reaction
Jiang, R., Tung, S. O., Tang, Z., Li, L., Ding, L., Xi, X., Liu, Y., Zhang, L., & Zhang, J. J. (2017) · Energy storage materials · doi:10.1016/j.ensm.2017.11.005 · Cited by 143 · see citing works
Fu, G., Xia, B. Y., Ma, R., Chen, Y., Tang, Y., & Lee, J. (2015) · Nano Energy · doi:10.1016/j.nanoen.2015.01.041 · Cited by 136 · see citing works
Plasmonic gas and chemical sensing
Tittl, A., Giessen, H. W., & Liu, N. (2014) · Nanophotonics · doi:10.1515/nanoph-2014-0002 · Cited by 135 · see citing works
Yang, C., He, H., Jiang, Q., Liu, X., Shah, S. P., Huang, H., & Li, W. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.09.243 · Cited by 132 · see citing works
Towards maximized utilization of iridium for the acidic oxygen evolution reaction
Ledendecker, M., Geiger, S., Hengge, K. A., Lim, J., Cherevko, S., Mingers, A. M., Göhl, D., Fortunato, G. V., Jalalpoor, D., Schüth, F., et al. (2019) · Nano Research · doi:10.1007/s12274-019-2383-y · Cited by 129 · see citing works
Fan, Z., Zhu, Y., Huang, X. B., Han, Y., Wang, Q., Liu, Q., Huang, Y., Gan, C. L., & Zhang, H. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201500993 · Cited by 126 · see citing works
Self-citationHigh CO-Tolerant Ru-Based Catalysts by Constructing an Oxide Blocking Layer
Wang, T., Li, L.-Y., Chen, L., Sheng, T., Chen, L., Wang, Y., Zhang, P., Hong, Y., Ye, J., Lin, W., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c00602 · Cited by 124 · see citing works
Lee, M. J., Kang, J. S., Kang, Y. S., Chung, D. Y., Shin, H., Ahn, C., Park, S., Kim, M., Kim, S., Lee, K., et al. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02580 · Cited by 120 · see citing works
Li, H., & Yu, S. (2019) · Advanced Materials · doi:10.1002/adma.201803503 · Cited by 112 · see citing works
Zhang, S., Pei, A., Li, G., Zhu, L., Li, G., Wu, F., Lin, S., Chen, W., Chen, B. H., & Luque, R. (2022) · Green Chemistry · doi:10.1039/d1gc04799j · Cited by 112 · see citing works
Lu, G., Yang, H., Zhu, Y., Huggins, T. M., Ren, Z. J., Liu, Z., & Zhang, W. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06231k · Cited by 110 · see citing works
Self-citationDutta, A., & Ouyang, J. (2015) · ACS Catalysis · doi:10.1021/cs501365y · Cited by 107 · see citing works
Cho, H., Kim, S. M., Kang, Y. S., Kim, J., Jang, S., Kim, M., Park, H., Bang, J. W., Seo, S., Suh, K. Y., et al. (2015) · Nature Communications · doi:10.1038/ncomms9484 · Cited by 108 · see citing works
Core–Shell-Structured Low-Platinum Electrocatalysts for Fuel Cell Applications
Wang, R., Wang, H., Luo, F., & Liao, S. (2018) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0013-0 · Cited by 100 · see citing works
Duan, Y., Zhang, X., Gao, F., Kong, Y., Duan, Y., Yang, X., Yu, X., Wang, Y., Qin, S., Chen, Z., et al. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202217275 · Cited by 101 · see citing works
Hu, J., Wu, L., Kuttiyiel, K. A., Goodman, K. R., Zhang, C., Zhu, Y., Vukmirovic, M. B., White, M. G., Sasaki, K., & Adzic, R. R. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04999 · Cited by 94 · see citing works
Self-citationYe, S., Feng, J., & Li, G. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02263 · Cited by 94 · see citing works
Self-citationControlled Synthesis of Pd/Pt Core Shell Nanoparticles Using Area-selective Atomic Layer Deposition
Cao, K., Zhu, Q., Shan, B., & Chen, R. (2015) · Scientific Reports · doi:10.1038/srep08470 · Cited by 93 · see citing works
High Performance Pt Monolayer Catalysts Produced via Core-Catalyzed Coating in Ethanol
Zhang, Y., Hsieh, Y.-C., Volkov, V. V., Su, D., An, W., Si, R., Zhu, Y., Liu, P., Wang, J. X., & Adžić, R. R. (2014) · ACS Catalysis · doi:10.1021/cs401091u · Cited by 91 · see citing works
Self-citationSu, D., Dou, S. X., & Wang, G. (2015) · NPG Asia Materials · doi:10.1038/am.2014.130 · Cited by 88 · see citing works
Self-citationDang, D., Zou, H., Xiong, Z., Hou, S., Shu, T., Nan, H., Zeng, X., Zeng, J., & Liao, S. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00030 · Cited by 88 · see citing works
Kwon, H. C., Kim, M., Grote, J., Cho, S. J., Chung, M. W., Kim, H., Won, D. H., Žeradjanin, A. R., Mayrhofer, K. J. J., Choi, M., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b09211 · Cited by 87 · see citing works
Kinetic‐Oriented Construction of MoS2 Synergistic Interface to Boost pH‐Universal Hydrogen Evolution
Hu, J., Zhang, C., Yang, P. F., Xiao, J., Deng, T., Liu, Z., Huang, B., Leung, M. K. H., & Yang, S. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201908520 · Cited by 84 · see citing works
Tsai, H.-C., Hsieh, Y.-C., Yu, T. H., Lee, Y.-J., Wu, Y.-H., Merinov, B. V., Wu, P., Chen, S., Adžić, R. R., & Goddard, W. A. (2015) · ACS Catalysis · doi:10.1021/cs501020a · Cited by 81 · see citing works
Self-citationGu, J., Guo, Y., Jiang, Y., Zhu, W. D., Xu, Y., Zhao, Z., Liu, J., Li, W., Jin, C., Yan, C., et al. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b04587 · Cited by 82 · see citing works
Self-citationHu, S., Tian, M., Ribeiro, E. L., Duscher, G., & Mukherjee, D. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.11.078 · Cited by 81 · see citing works
Pavlišič, A., Jovanovič, P., Šelih, V. S., Šala, M., Bele, M., Dražić, G., Arčon, I., Hočevar, S. B., Kokalj, A., Hodnik, N., et al. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00557 · Cited by 82 · see citing works
Review—On Atomic Layer Deposition: Current Progress and Future Challenges
Mallick, B. C., Hsieh, C., Yin, K., Gandomi, Y. A., & Huang, K. (2019) · ECS Journal of Solid State Science and Technology · doi:10.1149/2.0201903jss · Cited by 78 · see citing works
Sub‐3 nm Intermetallic Ordered Pt3In Clusters for Oxygen Reduction Reaction
Wang, Q., Zhao, Z. L., Zhang, Z., Feng, T., Zhong, R., Xu, H., Pantelides, S. T., & Gu, M. D. (2019) · Advanced Science · doi:10.1002/advs.201901279 · Cited by 77 · see citing works
Qin, J., Liu, N., Chen, L., Wu, K., Zhao, Q., Liu, B., & Ye, Z. (2022) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.2c05110 · Cited by 77 · see citing works
Siller-Ceniceros, A. A., Sanchez-Castro, M. E., Morales‐Acosta, D., Torres‐Lubián, J. R., Eduardo Martínez, G., & Rodríguez‐Varela, F. J. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.03.023 · Cited by 75 · see citing works
Kwok, H. Y. H., Wang, Y. F., Tsang, A. C. H., & Leung, D. Y. C. (2018) · Applied Energy · doi:10.1016/j.apenergy.2018.02.141 · Cited by 73 · see citing works
Yang, Y. K., Huang, H., Shen, B., Jin, L., Jiang, Q., Yang, L. L., & He, H. (2019) · Inorganic Chemistry Frontiers · doi:10.1039/c9qi01448a · Cited by 70 · see citing works
Tzelepis, S., Kavadias, K. A., Marnellos, G. E., & Xydis, G. A. (2021) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2021.111543 · Cited by 69 · see citing works
Fan, Z., Luo, Z., Chen, Y., Wang, J. X., Li, B., Zong, Y., & Zhang, H. (2016) · Small · doi:10.1002/smll.201601787 · Cited by 69 · see citing works
Self-citationZhang, Q., Kusada, K., Wu, D., Ogiwara, N., Yamamoto, T., Toriyama, T., Matsumura, S., Kawaguchi, S., Kubota, Y., Honma, T., et al. (2019) · Chemical Science · doi:10.1039/c9sc00496c · Cited by 67 · see citing works
Nanodendrites of platinum-group metals for electrocatalytic applications
Chaudhari, N. K., Joo, J., Kwon, H., Kim, B., Kim, H. Y., Joo, S. H., & Lee, K. (2018) · Nano Research · doi:10.1007/s12274-018-2161-2 · Cited by 66 · see citing works
Ordered Porous Pd Octahedra Covered with Monolayer Ru Atoms
Ge, J., He, D., Bai, L., You, R., Lu, H., Lin, Y., Tan, C., Kang, Y., Xiao, B., Wu, Y. S., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08956 · Cited by 65 · see citing works
Recent advances of ruthenium-based electrocatalysts for hydrogen energy
Hu, C., Xu, F., Tan, Y., & Huang, X. (2023) · Trends in Chemistry · doi:10.1016/j.trechm.2023.01.002 · Cited by 61 · see citing works
Kim, M. S., Tran, D. T., Nguyen, T. H., Dinh, V. A., Kim, N. H., & Lee, J. H. (2022) · Energy & environment materials · doi:10.1002/eem2.12366 · Cited by 62 · see citing works
Chen, G., Dai, Z., Sun, L., Zhang, L., Liu, S., Bao, H., Bi, J., Yang, S., & Ma, F. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00226j · Cited by 61 · see citing works
Huynh, T. T., Huynh, Q., Nguyen, Q. V., & Pham, H. Q. (2023) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c03518 · Cited by 60 · see citing works
Yan, L., Wang, W., Chen, X., Zhang, Y., Han, Y., Cheng, Y., Chen, X., Liu, K., Wang, Y., Zhang, Q., et al. (2019) · Nano Research · doi:10.1007/s12274-019-2273-3 · Cited by 59 · see citing works
Self-citationLin, F., Luo, H., Li, L., Lv, F., Chen, Y., Zhang, Q., Han, X., Wang, D., Li, M., Luo, Y., et al. (2024) · Nature Synthesis · doi:10.1038/s44160-024-00685-4 · Cited by 66 · see citing works
Shan, A., Chen, Z., Li, B., Chen, C., & Wang, R. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta05812g · Cited by 58 · see citing works
Surface Anion Promotes Pt Electrocatalysts with High CO Tolerance in Fuel-Cell Performance
Cheng, H., Xia, J., Wang, M., Wang, C., Gui, R., Cao, X., Zhou, T., Zheng, X., Chu, W., Wu, H., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c09147 · Cited by 57 · see citing works
CO Oxidation Prefers the Eley–Rideal or Langmuir–Hinshelwood Pathway: Monolayer vs Thin Film of SiC
Sinthika, S., Vala, S. T., Kawazoe, Y., & Thapa, R. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b11384 · Cited by 56 · see citing works
He, C., & Tao, J. (2016) · RSC Advances · doi:10.1039/c5ra25367e · Cited by 55 · see citing works
An, W., & Liu, P. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01656 · Cited by 56 · see citing works
Self-citationWang, T., Chen, Z., Yu, S., Sheng, T., Ma, H., Chen, L., Rauf, M., Xia, H., Zhou, Z., & Sun, S. (2017) · Energy & Environmental Science · doi:10.1039/c7ee02641b · Cited by 56 · see citing works
Ning, L., Liu, X., Deng, M., Huang, Z., Zhu, A., Zhang, Q. G., & Liu, Q. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.11.188 · Cited by 56 · see citing works
Wang, Y., Wang, J., Han, G., Du, C., Sun, Y., Du, L., An, M., Yin, G., Gao, Y., & Song, Y. (2018) · Applied Surface Science · doi:10.1016/j.apsusc.2018.12.211 · Cited by 56 · see citing works
Self-citationHu, J., Kuttiyiel, K. A., Sasaki, K., Zhang, C., & Adžić, R. R. (2018) · Journal of The Electrochemical Society · doi:10.1149/2.0471815jes · Cited by 54 · see citing works
Meng, Y., Yin, J., Jiao, T., Bai, J., Zhang, L., Su, J., Liu, S., Bai, Z., Cao, M., & Peng, Q. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.112010 · Cited by 54 · see citing works
Kübler, M., Jurzinsky, T., Ziegenbalg, D., & Cremers, C. (2017) · Journal of Power Sources · doi:10.1016/j.jpowsour.2017.07.114 · Cited by 54 · see citing works
Zou, J., Wu, M., Ning, S., Huang, L., Kang, X., & Chen, S. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b01270 · Cited by 54 · see citing works
Wang, H., Gao, J., Chen, C., Zhao, W., Zhang, Z., Li, D., Chen, Y., Wang, C., Zhu, C., Ke, X., et al. (2023) · Nano-Micro Letters · doi:10.1007/s40820-023-01102-9 · Cited by 53 · see citing works
Wang, J. X., Zhang, Y., Capuano, C. B., & Ayers, K. E. (2015) · Scientific Reports · doi:10.1038/srep12220 · Cited by 53 · see citing works
Self-citationPark, J., Choi, S., Oh, A., Jin, H., Joo, J., Baik, H., & Lee, K. (2019) · Nanoscale Horizons · doi:10.1039/c8nh00520f · Cited by 53 · see citing works
Random alloy and intermetallic nanocatalysts in fuel cell reactions
Zhang, J., Shen, L., Jiang, Y., & Sun, S. (2020) · Nanoscale · doi:10.1039/d0nr05475e · Cited by 53 · see citing works
Towards bridging thermo/electrocatalytic CO oxidation: from nanoparticles to single atoms
Wei, K., Wang, X., & Ge, J. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00868a · Cited by 50 · see citing works
Chen, G., Kuttiyiel, K. A., Su, D., Li, M., Wang, C.-H., Buceta, D., Du, C., Gao, Y., Yin, G., Sasaki, K., et al. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b00500 · Cited by 50 · see citing works
Self-citationDang, D., Zhang, L., Zeng, X., Tian, X., Qu, C., Nan, H., Shu, T., Hou, S., Yang, L., Zeng, J., et al. (2017) · Journal of Power Sources · doi:10.1016/j.jpowsour.2017.04.050 · Cited by 49 · see citing works
Carbon monoxide powered fuel cell towards H2-onboard purification
Li, Y., Xian, W., Mei, B., Wang, Y., Luo, Z., Luo, E., Yang, X., Shi, Z., Liang, L., Jin, Z., et al. (2021) · 中国科学通报：英文版 · doi:10.1016/j.scib.2021.02.006 · Cited by 48 · see citing works
John, S. S., Atkinson, R. W., Unocic, K. A., Unocic, R. R., Zawodzinski, T. A., & Papandrew, A. B. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01432 · Cited by 48 · see citing works
Gloag, L., Benedetti, T. M., Cheong, S., Webster, R. F., Marjo, C. E., Gooding, J. J., & Tilley, R. D. (2018) · Nanoscale · doi:10.1039/c8nr03341b · Cited by 48 · see citing works
A novel Pt–Co alloy hydrogen anode catalyst with superlative activity, CO-tolerance and robustness
Shi, G., Yano, H., Tryk, D. A., Watanabe, M., Iiyama, A., & Uchida, H. (2016) · Nanoscale · doi:10.1039/c6nr00778c · Cited by 47 · see citing works
Potentiodynamic dissolution study of PtRu/C electrocatalyst in the presence of methanol
Jovanovič, P., Šelih, V. S., Šala, M., Hočevar, S. B., Ruiz‐Zepeda, F., Hodnik, N., Bele, M., & Gaberšček, M. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.06.109 · Cited by 46 · see citing works
Wu, T. S., Wang, X., Emre, A. E., Fan, J., Min, Y., Xu, Q., & Sun, S. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.06.056 · Cited by 44 · see citing works
Du, C., Gao, X., Zhuang, Z., Cheng, C., Zheng, F., Li, X., & Chen, W. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.03.198 · Cited by 45 · see citing works
Bifunctional CO oxidation over Mn-mullite anchored Pt sub-nanoclusters via atomic layer deposition
Liu, X., Tang, Y., Shen, M., Li, W., Chu, S., Shan, B., & Chen, R. (2018) · Chemical Science · doi:10.1039/c7sc05486f · Cited by 44 · see citing works
Hu, Q., Cao, K., Lang, Y., Chen, R., Chu, S., Jia, L., Yue, J., & Shan, B. (2019) · Catalysis Science & Technology · doi:10.1039/c9cy00212j · Cited by 44 · see citing works
Liu, X., Du, J., Shao, Y., Zhao, S., & Yao, K.-F. (2017) · Scientific Reports · doi:10.1038/s41598-017-10630-5 · Cited by 41 · see citing works
Baz, A., & Holewinski, A. (2020) · Journal of Catalysis · doi:10.1016/j.jcat.2020.02.003 · Cited by 42 · see citing works
Colloidal Metal Nanocrystals with Metastable Crystal Structures
Janssen, A., Nguyen, Q. N., & Younan Xia, A. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202017076 · Cited by 41 · see citing works
Electrocatalysts for Formic Acid-Powered PEM Fuel Cells: Challenges and Prospects
Cheng, H., Wang, J., Wu, C. K., & Liu, Z. (2023) · Energy Material Advances · doi:10.34133/energymatadv.0067 · Cited by 40 · see citing works
Self-citationSurface/Interfacial Catalysis of (Metal)/Oxide System: Structure and Performance Control
Jiang, W., Ji, W., & Au, C. (2018) · ChemCatChem · doi:10.1002/cctc.201701958 · Cited by 38 · see citing works
- Authors
- Hsieh, Y.-C., Zhang, Y., Su, D., Volkov, V., Si, R., Wu, L., Zhu, Y., An, W., Liu, P., He, P., Ye, S., Adzic, R. R., & Wang, J. X.
- Affiliations
- Brookhaven National Laboratory (US)
- Ballard Power Systems (Canada) (CA)
- Corresponding author
- Wang, Jia X
- ORCID
- Venue
- Nature Communications
- Published
- 2013-09-18
- Volume
- 4
- Issue
- 1
- Pages
- 2466-2466
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2132374840
- Cited by
- 229
- References
- 54
- Citations by year
- 2026: 5 · 2025: 7 · 2024: 12 · 2023: 17 · 2022: 16 · 2021: 15 · 2020: 18 · 2019: 30 · 2018: 22 · 2017: 23 · 2016: 20 · 2015: 37 · 2014: 6 · 2013: 1
- FWCI
- 7.76
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Nature Communications (publishedVersion)
- PubMed (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- Funders
- U.S. Department of Energy (DEAC-02-98CH10886, -AC02-98 CH 10886, DE-AC02-)
- National Science Council
- Shanghai Educational Development Foundation
- National Chiao Tung University
- Brookhaven National Laboratory (AC-02-98CH10886, DE-AC02- 98CH10886)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Keywords
- CO tolerance, fuel cell catalysts, ruthenium dissolution, crystal defects, green synthesis, low-temperature fuel cells, reformate fuel, catalyst stability
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
