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Comparison of disperse and reactive dye removals by chemical coagulation and Fenton oxidation
Abstract
The composition of wastewater from the dyeing and textile processes is highly variable depending on the dyestuff type and typically has high COD and color. This study examined the decolorization of some of the most commonly used disperse and reactive dyestuffs by combination of chemical coagulation and Fenton oxidation. In addition, performances between Fe3+ coagulation and Fenton oxidation of dye solutions were compared by measuring COD and dye removals, distributions of zeta potential, concentration of suspended solid were investigated. Fenton oxidation in combination with Fe3+ coagulation has shown to effectively remove COD and dye. About 90% of COD and 99% of dye removals were obtained at the optimum conditions. Compared to reactive dyes, disperse dyes have lower solubility, higher suspended solids concentrations and lower SCOD/TCOD ratios. The COD and dye removed per unit Fe3+ coagulant added for disperse dye solutions were higher than those for reactive dye solutions. Therefore, the disperse dye solutions are more easily decolorized by chemical coagulation than reactive dye solutions. Conversely, reactive dye solutions have higher applicability of Fenton oxidation than disperse dye solutions due to their higher solubility, lower suspended solids concentrations and higher SCOD/TCOD ratios. The COD and dye removed per Fe2+ Fenton reagent added for reactive dye solutions are respectively higher than those for disperse dye solutions.
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Stand-alone coagulation/flocculation/precipitation in treating textile/dye waste is relatively ineffective; only 50% removal was achieved using either alum or ferrous sulfate for an azo reactive yellow dye.
“Their stand alone application in treating textile/dye waste is, however, relatively ineffective 79,101,163 , for example, only 50% removal was achieved using either alum or ferrous sulfate for an azo reactive yellow dye.79”
From Hybrid Treatment Systems for Dye Wastewater (2007) · cites this paper as [101]
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Metadata
- Authors
- Kim, T.-H., Park, C., Yang, J., & Kim, S.
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2004-08
- Volume
- 112
- Issue
- 1-2
- Pages
- 95-103
- ISSN
- 0304-3894
- Cited by
- 321
- References
- 0
- Language
- en
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