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Biosorption of Cr(III) ions by eggshells
Abstract
The paper presents results of studies carried out on sorption of Cr(III) ions from aqueous solutions by eggshells as a low-cost sorbent. It was found that crushed eggshells possess relatively high sorption capacity, when comparing with other sorbents, that was evaluated as 21-160 mg/g. The effect of process parameters: pH, temperature, initial concentration of Cr(III) ions on the process kinetics was studied. It was found that the equilibrium of the process was reached after 60 min. Also equilibrium studies were performed: the effect of sorbent concentration and equilibrium Cr(III) concentration was studied. The maximum experimentally determined sorption capacity 160 mg/g was obtained at low sorbent concentration at 20 degrees C and pH 5. It was found that sorption capacity increased with the increase of Cr(III) concentration, temperature and sorbent concentration. Mathematical models describing kinetics and equilibrium of sorption were proposed. The process kinetics was described with pseudo-second-order pattern and equilibrium was described with Langmuir-type equation, and the influence of sorbate concentration, with an empirical dependence. The models were positively verified. Eggshells were able to remove the concentration of Cr(III) ions below the acceptable level, i.e. at 40 degrees C, at the initial concentration of metal ions 100 mg/kg, at sorbent concentration 15 g/l.
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“Accordingly, there have been a number studies evaluating eggshells as immobilising agents for heavy metals such as chromium(III) and lead [104–106].”
From Progress towards Sustainable Utilisation and Management of Food Wastes in the Global Economy (2016) · cites this paper as [105]
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Michalak, I., Witek‐Krowiak, A., Chojnacka, K., & Bhatnagar, A. (2015) · Reviews in Inorganic Chemistry · doi:10.1515/revic-2015-0003 · Cited by 29
Self-citationChicken Eggshells Remove Pb(II) Ions from Synthetic Wastewater
Vijayaraghavan, K., & Joshi, U. M. (2013) · Environmental Engineering Science · doi:10.1089/ees.2012.0038 · Cited by 29
“Several other chitin-based biomaterials have also been used in metal biosorption, which includes shells of hen egg (Chojnacka, 2005; Vijayaraghavan et al. , 2005a), shrimp (Chio et al. , 2009), and oyster (Hsu, 2009).”
Modeling Bisphenol A Removal from Aqueous Solution by Activated Carbon and Eggshell
Zazouli, M. A., Veisi, F., & Veisi, A. (2013) · Majallah-i dānishgāh-i ̒ulūm-i pizishkī-i Māzandarān/Journal of Mazandaran University of Medical Sciences · Cited by 27
Application and efficacy of low-cost adsorbents for metal removal from contaminated water: A review
Gupta, G., Khan, J., & Singh, N. (2021) · Materials Today Proceedings · doi:10.1016/j.matpr.2021.01.316 · Cited by 26
Seid, S. M., & Gonfa, G. H. (2022) · Environmental Challenges · doi:10.1016/j.envc.2022.100574 · Cited by 27
“This value is in the range of the values reported for eggshell based adsorbent (21-160 mg/g) ( Chojnacka, 2005 ) and guar gum-nano zinc oxide composite (55.56 mg/g) ( Khan et al., 2017 )”
InfluentialPazos, M. M., Branco, M., Neves, I. C., Sanromán, M. Á., & Tavares, T. (2010) · Chemical Engineering & Technology · doi:10.1002/ceat.201000203 · Cited by 27
Utilization to Remove Pb (II) Ions from Aqueous Environments Using Waste Fish Bones by Ion Exchange
Kızılkaya, B., & Teki̇nay, A. A. (2014) · Journal of Chemistry · doi:10.1155/2014/739273 · Cited by 27
“The concentration of protons at lower pH is higher; thus, more groups are bound with protons and therefore fewer groups are available for metal ions to bind with [27].”
BackgroundKamkum, P., Atiwongsangthong, N., Muanghlua, R., & Vittayakorn, N. (2015) · Ceramics International · doi:10.1016/j.ceramint.2015.03.189 · Cited by 26
“Many researchers have proposed the effectiveness of using eggshells for heavy metal sorption such as Cu, Cr and Cd [5–8] and for the removal of dye effluents [9,10].”
BackgroundSeparation of chromium(III) and chromium(VI) from environmental water samples using eggshell sorbent
Ghazy, S. E. (2008) · Indian Journal of Science and Technology · doi:10.17485/ijst/2008/v1i6.7 · Cited by 26
Adsorption of lignosulfonate compounds using powdered eggshell
Zulfikar, M. A., Mariske, E. D., & Djajanti, S. D. (2012) · DOAJ (DOAJ: Directory of Open Access Journals) · Cited by 25
Calcined eggshell as an inexpensive catalyst for partial oxidation of methane
Karoshi, G., Kolar, P., Shah, S. B., Gilleskie, G. L., & Das, L. (2015) · Journal of the Taiwan Institute of Chemical Engineers · doi:10.1016/j.jtice.2015.05.025 · Cited by 25
Elabbas, S., Adjeroud, N., Mandi, L., Berrekhis, F., Pons, M., Leclerc, J. P., & Ouazzani, N. (2020) · International Journal of Environmental & Analytical Chemistry · doi:10.1080/03067319.2020.1761963 · Cited by 24
“pH evolution during treatment The pH of the solution has an important role in the performance of the electrocoagulation and the sorption processes and its change during the treatment affects the treatment efficiency [27, 28] The different forms of Al (OH)3 present in the solution greatly depend upon the pH and concent…”
BackgroundAdsorption of Ni(II) Ion onto Calcined Eggshells: A Study of Equilibrium Adsorption Isotherm
Kristianto, H., Daulay, N., & Arie, A. A. (2019) · Indonesian Journal of Chemistry · doi:10.22146/ijc.29200 · Cited by 24
“Various heavy metals adsorption using eggshells has been done before, such as Cd(II) [12-13], Cr(III) [14], Cr(VI) [15], Fe(III) [16], Al(III), Fe(II), Zn(II) [17], Cu(II) [18-”
BackgroundMashangwa, T. D., Tekere, M., & Sibanda, T. (2017) · International Journal of Environmental Research · doi:10.1007/s41742-017-0017-3 · Cited by 23
“The pH of solutions accounts for the protonation of metal binding sites on the eggshells, calcium carbonate solubility, metal speciation in the solution, solubility of metal ions, and the concentration of the counter ions found on the functional groups of the biosorbent (Chojnacka 2005).”
BackgroundPathak, U., Jhunjhunwala, A., Roy, A., Das, P., Kumar, T., & Mandal, T. (2019) · Environmental Science and Pollution Research · doi:10.1007/s11356-019-06014-z · Cited by 22
“…aerobic and anaerobic microbial degradation (Vijayaraghavan et al. 2005; Batzias and Sidiras 2004), electrolysis (Tsai et al. 2006), advanced oxidation processes (Chojnacka 2005), ion exchange (Stadelman 2000) and adsorption (Dasgupta et al. 2015) have been adopted for aqueous phenol abolishment.”
MethodChromium adsorption on thermally activated adsorbent equipped from waste biomass
Hashem, M. A., Nayeen, M. J., Hossain, M. T., & Miem, M. M. (2024) · Waste Management Bulletin · doi:10.1016/j.wmb.2024.01.009 · Cited by 21
Removal of Lead, Copper, Zinc and Cadmium from Water Using Phosphate Rock
Corami, A., Mignardi, S., & Ferrini, V. (2008) · Acta Geologica Sinica - English Edition · doi:10.1111/j.1755-6724.2008.tb00724.x · Cited by 21
Saeid, A., & Chojnacka, K. (2018) · Elsevier eBooks · doi:10.1016/b978-0-12-813272-2.00004-5 · Cited by 21
Self-citationOninla, V. O., Olatunde, A. M., Babalola, J. O., Adesanmi, O. J., Towolawi, G. S., & Awokoya, K. N. (2018) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2018.05.030 · Cited by 20
Removal of Cr( iii )/Cr( vi ) from wastewater using defective porous boron nitride: a DFT study
Li, Q., Liu, Y., Yu, X., Li, L., Zhang, X., Lu, Z., Lin, J., Yang, X., & Huang, Y. (2018) · Inorganic Chemistry Frontiers · doi:10.1039/c8qi00416a · Cited by 19
Yusuff, A. S. (2017) · Journal of Environmental Science and Technology · doi:10.3923/jest.2017.120.130 · Cited by 19
Metadata
- Authors
- CHOJNACKA, K.
- Affiliations
- Wrocław University of Science and Technology (PL)
- Corresponding author
- CHOJNACKA, K
- ORCID
- CHOJNACKA, K
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2005-05-20
- Volume
- 121
- Issue
- 1-3
- Pages
- 167-173
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W2037136202
- Cited by
- 190
- References
- 20
- Citations by year
- 2026: 6 · 2025: 9 · 2024: 6 · 2023: 5 · 2022: 7 · 2021: 11 · 2020: 14 · 2019: 8 · 2018: 11 · 2017: 10 · 2016: 14 · 2015: 16 · 2014: 15 · 2013: 15 · 2012: 4
- FWCI
- 7.25
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Chromium effects and bioremediation
- Keywords
- biosorption, trivalent chromium, eggshell, low-cost adsorbent, heavy metal removal, sorption kinetics, pseudo-second-order kinetics, Langmuir isotherm, sorption equilibrium, pH effect, temperature effects, sorption capacity, wastewater treatment
- MeSH terms
- Adsorption, Animals, Biodegradation, Environmental, Chickens, Chromium, Egg Shell, Hydrogen-Ion Concentration, Kinetics, Models, Chemical, Temperature, Water Pollutants, Chemical, Water Pollution
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