The DOI matches its Crossref record; 59 of the 59 references it cites were found in a registry or an index.
Adsorption mechanism of hexavalent chromium onto layered double hydroxides-based adsorbents: A systematic in-depth review
Open accessAbstract
An attempt has been made in this review to provide some insights into the possible adsorption mechanisms of hexavalent chromium onto layered double hydroxides-based adsorbents by critically examining the past and present literature. Layered double hydroxides (LDH) nanomaterials are typical dual-electronic adsorbents because they exhibit positively charged external surfaces and abundant interlayer anions. A high positive zeta potential value indicates that LDH has a high affinity to Cr(VI) anions in solution through electrostatic attraction. The host interlayer anions (i.e., Cl-, NO3-, SO42-, and CO32-) provide a high anion exchange capacity (53-520 meq/100 g) which is expected to have an excellent exchangeable capacity to Cr(VI) oxyanions in water. Regarding the adsorption-coupled reduction mechanism, when Cr(VI) anions make contact with the electron-donor groups in the LDH, they are partly reduced to Cr(III) cations. The reduced Cr(III) cations are then adsorbed by LDH via numerous interactions, such as isomorphic substitution and complexation. Nonetheless, the adsorption-coupled reduction mechanism is greatly dependent on: (1) the nature of divalent and trivalent salts utilized in LDH preparation, and the types of interlayer anions (i.e., guest intercalated organic anions), and (3) the adsorption experiment conditions. The low Brunauer-Emmett-Teller specific surface area of LDH (1.80-179 m2/g) suggests that pore filling played an insignificant role in Cr(VI) adsorption. The Langmuir maximum adsorption capacity of LDH (Qomax) toward Cr(VI) was significantly affected by the natures of used inorganic salts and synthetic methods of LDH. The Qomax values range from 16.3 mg/g to 726 mg/g. Almost all adsorption processes of Cr(VI) by LDH-based adsorbent occur spontaneously (ΔG° <0) and endothermically (ΔH° >0) and increase the randomness (ΔS° >0) in the system. Thus, LDH has much potential as a promising material that can effectively remove anion pollutants, especially Cr(VI) anions in industrial wastewater.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The adsorption of gases on plane surfaces of glass, mica and platinum
Langmuir, I. (1918) · Journal of the American Chemical Society · doi:10.1021/ja02242a004 · Cited by 23,242
Tran, H. N., You, S.-J., Hosseini-Bandegharaei, A., & Chao, H.-P. (2017) · Water Research · doi:10.1016/j.watres.2017.04.014 · Cited by 2,902
Self-citationActivated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water
Mohan, D., & Pittman Jr., C. U. (2006) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2006.06.060 · Cited by 1,855
Role of nanomaterials in water treatment applications: A review
Santhosh, C., Velmurugan, V., Jacob, G., Jeong, S. K., Grace, A. N., & Bhatnagar, A. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.08.053 · Cited by 1,256
Volesky, B. (2007) · Water Research · doi:10.1016/j.watres.2007.05.062 · Cited by 948
Rajasulochana, P., & Preethy, V. (2016) · Resource-Efficient Technologies · doi:10.1016/j.reffit.2016.09.004 · Cited by 769
Constantino, V. R. L., & Pinnavaia, T. J. (1995) · Inorganic Chemistry · doi:10.1021/ic00108a020 · Cited by 641
Biosorbents for hexavalent chromium elimination from industrial and municipal effluents
Saha, B., & Orvig, C. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.06.005 · Cited by 568
Lei, C., Zhu, X., Zhu, B., Jiang, C., Le, Y., & Yu, J. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2016.09.070 · Cited by 507
Nanomaterials for removal of toxic elements from water
Lu, F., & Astruc, D. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.003 · Cited by 446
Cited by
Banana peel as a biosorbent for the decontamination of water pollutants. A review
Akpomie, K. G., & Conradie, J. (2020) · Environmental Chemistry Letters · doi:10.1007/s10311-020-00995-x · Cited by 239
Jeyasubramanian, K., Thangagiri, B., Sakthivel, A., Dhaveethu Raja, J., Seenivasan, S., Vallinayagam, P., Madhavan, D., Malathi Devi, S., & Rathika, B. (2021) · Fuel · doi:10.1016/j.fuel.2021.120243 · Cited by 197
Xing, X., Alharbi, N. S., Ren, X., & Chen, C. (2022) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2022.107325 · Cited by 79
Metadata
- Authors
- Tran, H. N., Nguyen, D. T., Le, G. T., Tomul, F., Lima, E. C., Woo, S. H., Sarmah, A. K., Nguyen, H. Q., Nguyen, P. T., Nguyen, D. D., Nguyen, T. V., Vigneswaran, S., Vo, D.-V. N., & Chao, H.-P.
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2019-07
- Volume
- 373
- Pages
- 258-270
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W2918669605
- Cited by
- 268
- References
- 59
- FWCI
- 11.81
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Adsorption mechanism of hexavalent chromium onto layered double hydroxides-based adsorbents: A systematic in-depth review. https://app.cochat.ai/papers/10.1016/j.jhazmat.2019.03.018
- The paper
- Tran, H. N., Nguyen, D. T., Le, G. T., Tomul, F., Lima, E. C., Woo, S. H., Sarmah, A. K., Nguyen, H. Q., Nguyen, P. T., Nguyen, D. D., Nguyen, T. V., Vigneswaran, S., Vo, D.-V. N., & Chao, H.-P. (2019). Adsorption mechanism of hexavalent chromium onto layered double hydroxides-based adsorbents: A systematic in-depth review. Journal of Hazardous Materials. https://doi.org/10.1016/j.jhazmat.2019.03.018
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
