Critical review on adsorptive removal of antibiotics: Present situation, challenges and future perspective

Abstract

This review gives a proper dedicated understanding of the contamination level, sources, and biological dangers related with different classes of antibiotics in consumable water. The literature on the adsorption of antibiotics is relatively uncommon and developments are still under progression, especially for adsorbents other than activated carbon. Also, adsorption technique has already been applied vastly for water treatment. Notwithstanding significant progressions, designed natural wastewater treatment frameworks are just bearably effective (48-77%) in the expulsion of antibiotics. Hence, the compilation of available literature especially for antibiotic adsorption was much needed. Moreover, the conventional adsorbents have some limitations of their own. In this study, the main focus was laid on unconventional adsorbents such as Biochar, Biopolymers, Carbon Nanotubes, Clays, Metal-Organic Frameworks, Microalgae and some miscellaneous adsorbents. The mechanism of adsorption by the unconventional adsorbents includes electrostatic interactions, π-π bonding, weak Van der Waal forces, H-bonding and surface complexation, which was similar to that of conventional adsorbents and hence these unconventional adsorbents can easily replace the costlier conventional adsorbents with even better adsorption efficiency. This paper also briefly discussed the thermodynamics, adsorption equilibrium; isotherm and kinetics of adsorption. This review paper seizes the critical advances of adsorption phenomenon at various interfaces and lays the foundation for current scenario associated with further progress. Besides, this study would help in understanding the antibiotic adsorption, cost estimation and future goals that will attract the young the researchers of this field.