Coordination of N-methylpyrrolidone to iron(II)
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Addition of N-methyl pyrrolidone (NMP), a cyclic tertiary amide, has been shown to enhance the catalytic activity of iron in cross-coupling reactions which enables the formation of catalytically active monomeric ferrates by coordination.
“In fact, the addition of N-methyl pyrrolidone (NMP), a cyclic tertiary amide, has been shown to enhance the catalytic activity of iron in cross-coupling reactions which enables the formation of catalytically active monomeric ferrates by coordination.70–73”
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Muñoz, S. B., Daifuku, S. L., Sears, J. D., Baker, T. M., Carpenter, S. H., Brennessel, W. W., & Neidig, M. L. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802087 · Cited by 81 · see citing works
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Naolou, T., Lendlein, A., & Neffe, A. T. (2019) · Frontiers in Chemistry · doi:10.3389/fchem.2019.00346 · Cited by 5 · see citing works
- Authors
- Ding, K., Zannat, F., Morris, J. C., Brennessel, W. W., & Holland, P. L.
- Affiliations
- University of Rochester (US)
- Corresponding author
- Holland, Patrick L.
- Venue
- Journal of Organometallic Chemistry
- Publisher
- Elsevier BV
- Published
- 2009-12
- Volume
- 694
- Issue
- 26
- Pages
- 4204-4208
- ISSN
- 0022-328X (ISSN-L)
- OpenAlex
- W2092620032
- Cited by
- 52
- References
- 35
- Citations by year
- 2026: 2 · 2024: 9 · 2023: 4 · 2022: 1 · 2021: 4 · 2020: 3 · 2019: 3 · 2018: 8 · 2017: 3 · 2016: 1 · 2015: 4 · 2014: 2 · 2013: 4 · 2012: 1
- FWCI
- 0.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Organometallic Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Catalytic Cross-Coupling Reactions
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
- Keywords
- N-methyl-2-pyrrolidone, iron(II) complexes, cosolvents, iron catalysis, cross-coupling, β-diketiminate ligands, ligand exchange, crystal structure, trigonal pyramidal geometry, catalyst precursors
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