Synthesis of heterotactic PLA from rac-lactide using hetero-bimetallic Mg/Zn–Li systems
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Heterobimetallic complexes 80 and 81 exhibited higher catalytic activity than did homo-bimetallic complexes 83 and 84.
“Although the catalytic activity of complex 82 is difficult to compare with that of complex 80 and complex 81 because of different reaction conditions, heterobimetallic complexes 80 and 81 exhibited higher catalytic activity than did homo-bimetallic complexes 83 and 84.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [95]
Cites
Stereocontrolled ring-opening polymerisation of lactide
Stanford, M. J., & Dove, A. P. (2009) · Chemical Society Reviews · doi:10.1039/b815104k · Cited by 878 · see citing works
Thomas, C. M. (2010) · Chem. Soc. Rev. · doi:10.1039/b810065a · Cited by 853 · see citing works
Self-citationNature or Petrochemistry?—Biologically Degradable Materials
Mecking, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200301655 · Cited by 590 · see citing works
Biodegradable Polymeric Materials
Chiellini, E., & Solaro, R. (1996) · Advanced Materials · doi:10.1002/adma.19960080406 · Cited by 567 · see citing works
Synthesis of biodegradable polymers from renewable resources
Tschan, M. J. ‐., Brûlé, E., Haquette, P., & Thomas, C. M. (2011) · Polymer Chemistry · doi:10.1039/c2py00452f · Cited by 426 · see citing works
Self-citationTandem synthesis of alternating polyesters from renewable resources
Robert, C., Montigny, F. D., & Thomas, C. M. (2011) · Nature Communications · doi:10.1038/ncomms1596 · Cited by 256 · see citing works
Self-citationSelective Halogen−Magnesium Exchange Reaction via Organomagnesium Ate Complex
Inoue, A., Kitagawa, K., Shinokubo, H., & Oshima, K. (2001) · The Journal of Organic Chemistry · doi:10.1021/jo015597v · Cited by 245 · see citing works
Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds
Tilly, D., Chevallier, F., Mongin, F., & Gros, P. C. (2013) · Chemical Reviews · doi:10.1021/cr400367p · Cited by 132 · see citing works
Self-citationUchiyama, M., Furuyama, T., Kobayashi, M., Matsumoto, Y., & Tanaka, K. (2006) · Journal of the American Chemical Society · doi:10.1021/ja058246x · Cited by 116 · see citing works
Tandem catalysis: a new approach to polymers
Robert, C., & Thomas, C. M. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60287g · Cited by 113 · see citing works
Self-citationIida, T., Wada, T., Tomimoto, K., & Mase, T. (2001) · Tetrahedron Letters · doi:10.1016/s0040-4039(01)00861-9 · Cited by 110 · see citing works
Furuyama, T., Yonehara, M., Arimoto, S., Kobayashi, M., Matsumoto, Y., & Uchiyama, M. (2008) · Chemistry - A European Journal · doi:10.1002/chem.200800536 · Cited by 85 · see citing works
Synthesis and reactivity of lithium tri(quinolinyl)magnesates
Dumouchel, S., Mongin, F., Trécourt, F., & Quéguiner, G. (2003) · Tetrahedron · doi:10.1016/j.tet.2003.06.001 · Cited by 67 · see citing works
Walton, M. J., Lancaster, S. J., & Redshaw, C. (2014) · ChemCatChem · doi:10.1002/cctc.201402041 · Cited by 62 · see citing works
Fang, J., Tschan, M. J.-L., Roisnel, T., Trivelli, X., Gauvin, R. M., Thomas, C. M., & Maron, L. (2013) · Polym. Chem. · doi:10.1039/c2py20590d · Cited by 59 · see citing works
Self-citationTschan, M. J. ‐., Guo, J., Raman, S. K., Brûlé, E., Roisnel, T., Rager, M., Legay, R., Durieux, G., Rigaud, B., & Thomas, C. M. (2014) · Dalton Transactions · doi:10.1039/c3dt52629a · Cited by 52 · see citing works
Self-citationGallegos, C., Tabernero, V., Garcı́a-Valle, F. M., Mosquera, M. E. G., Cuenca, T., & Cano, J. (2013) · Organometallics · doi:10.1021/om400940f · Cited by 50 · see citing works
Homoleptic Zincate‐Promoted Room‐Temperature Halogen–Metal Exchange of Bromopyridines
Chau, N. T. T., Meyer, M., Komagawa, S., Chevallier, F., Fort, Y., Uchiyama, M., Mongin, F., & Gros, P. C. (2010) · Chemistry - A European Journal · doi:10.1002/chem.201001664 · Cited by 41 · see citing works
Self-citationWang, L., Pan, X., Yao, L., Tang, N., & Wu, J. (2011) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201001283 · Cited by 39 · see citing works
Sun, Y., Wang, L., Yu, D., Tang, N., & Wu, J. (2014) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2014.06.017 · Cited by 27 · see citing works
Synthesis and Coordination Properties of Chelating Dithiophenolate Ligands
Ballmann, J., Fuchs, M. G. G., Sebastian Dechert, B., John, M., & Meyer, F. (2008) · Inorganic Chemistry · doi:10.1021/ic801285u · Cited by 27 · see citing works
Pyridylmagnesiates: generation by bromine–metal exchange and enantioselective addition to aldehydes
Catel, D., Payen, O., Chevallier, F., Mongin, F., & Gros, P. C. (2012) · Tetrahedron · doi:10.1016/j.tet.2012.03.058 · Cited by 27 · see citing works
Self-citationWIDENING THE ROAD FOR C-C BONDS
RITTER, S. K. (2002) · Chemical & Engineering News · doi:10.1021/cen-v080n005.p026 · Cited by 24 · see citing works
Wang, L., Zhang, J., Yao, L., Tang, N., & Wu, J. (2011) · Inorganic Chemistry Communications · doi:10.1016/j.inoche.2011.03.011 · Cited by 16 · see citing works
Straightforward access to enantioenriched pyrazyl alcohols using chiral organomagnesiates
Payen, O., Chevallier, F., Mongin, F., & Gros, P. C. (2012) · Tetrahedron Asymmetry · doi:10.1016/j.tetasy.2012.11.003 · Cited by 16 · see citing works
Self-citationPan, X., Yang, X., Chen, L., Wu, J., & Tang, N. (2010) · Inorganic Chemistry Communications · doi:10.1016/j.inoche.2010.04.025 · Cited by 11 · see citing works
Drumright, R. E., Gruber, P. R., & Henton, D. E. (2000) · Advanced Materials · doi:10.1002/1521-4095(200012)12:23
Flagged first, then by citations
Cited by
Sorted by citations
Recyclable and (Bio)degradable Polyesters in a Circular Plastics Economy
Shi, C., Quinn, E. C., Diment, W. T., & Chen, E. Y. ‐. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00848 · Cited by 418 · see citing works
Dinuclear catalysts for the ring opening polymerization of lactide
Kremer, A. B., & Mehrkhodavandi, P. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.09.008 · Cited by 152 · see citing works
Advances in heterometallic ring-opening (co)polymerisation catalysis
Gruszka, W., & Garden, J. A. (2021) · Nature Communications · doi:10.1038/s41467-021-23192-y · Cited by 115 · see citing works
Wu, L.-J., Lee, W., Kumar Ganta, P., Chang, Y.-L., Chang, Y.-C., & Chen, H.-Y. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214847 · Cited by 96 · see citing works
Groups 1, 2 and Zn(II) Heterodinuclear Catalysts for Epoxide/CO2 Ring-Opening Copolymerization
Deacy, A. C., Durr, C. B., Garden, J. A., White, A. J. P., & Williams, C. K. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b02923 · Cited by 70 · see citing works
Yolsal, U., Shaw, P. J., Lowy, P. A., Chambenahalli, R., & Garden, J. A. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c05103 · Cited by 64 · see citing works
Monomeric and dimeric magnesium mono-BHT complexes as effective ROP catalysts
Nifant'ev, I. E., Shlyakhtin, A. V., Tavtorkin, A. N., Ivchenko, P. V., Борисов, Р. С., & Churakov, A. V. (2016) · Catalysis Communications · doi:10.1016/j.catcom.2016.09.018 · Cited by 52 · see citing works
Gruszka, W., Lykkeberg, A., Nichol, G. S., Shaver, M. P., Buchard, A., & Garden, J. A. (2020) · Chemical Science · doi:10.1039/d0sc04705h · Cited by 36 · see citing works
Dubey, S. P., Abhyankar, H. A., Marchante, V., Brighton, J., Blackburn, K., Temple, C., Bergmann, B., Trinh, G., & David, C. (2016) · Polymers · doi:10.3390/polym8040164 · Cited by 32 · see citing works
Gruszka, W., Sha, H., Buchard, A., & Garden, J. A. (2022) · Catalysis Science & Technology · doi:10.1039/d1cy01914g · Cited by 24 · see citing works
Multicatalysis from renewable resources: a direct route to furan-based polyesters
Guillaume, L., Marshall, A., Niessen, N., Ni, P., Gauvin, R. M., & Thomas, C. M. (2021) · Green Chemistry · doi:10.1039/d1gc01889b · Cited by 23 · see citing works
Self-citationSingle-site cobalt and zinc catalysts for the ring-opening polymerization of lactide
Marin, P., Tschan, M. J. ‐., Haquette, P., Roisnel, T., Rosal, I. D., Maron, L., & Thomas, C. M. (2019) · European Polymer Journal · doi:10.1016/j.eurpolymj.2019.08.035 · Cited by 19 · see citing works
Self-citationBekmirzaev, J., Simon, M., D’Aniello, S., Mazzeo, M., Cohen‐Janes, S. J., Mathers, R. T., Gauvin, R. M., & Thomas, C. M. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202319414 · Cited by 18 · see citing works
Self-citationDubey, S. P., Abhyankar, H. A., Marchante, V., Brighton, J., Bergmann, B., Trinh, G., & David, C. (2017) · RSC Advances · doi:10.1039/c6ra26514f · Cited by 17 · see citing works
Ivchenko, P. V., Shlyakhtin, A. V., & Nifant'ev, I. E. (2017) · Mendeleev Communications · doi:10.1016/j.mencom.2017.05.020 · Cited by 16 · see citing works
Petrus, R., Lis, T., & Kowaliński, A. (2022) · Dalton Transactions · doi:10.1039/d2dt00731b · Cited by 11 · see citing works
Microstructurally controlled polymers of rac-lactide by lithium complexes
Char, J., Кулык, О. Г., Brûlé, E., Montigny, F. D., Guérineau, V., Roisnel, T., Tschan, M. J. ‐., & Thomas, C. M. (2015) · Comptes Rendus Chimie · doi:10.1016/j.crci.2015.05.018 · Cited by 9 · see citing works
Self-citationBaker, C. A., Romain, C., & Long, N. J. (2021) · Chemical Communications · doi:10.1039/d1cc05083d · Cited by 8 · see citing works
Ambient Temperature Polymerization of Methyl Methacrylate Mediated by Ate Complexes
Fouilloux, H., & Thomas, C. M. (2021) · ChemCatChem · doi:10.1002/cctc.202101673 · Cited by 6 · see citing works
Self-citationSynthesis of High Molecular Weight Stereo-Di-Block Copolymers Driven by a Co-Initiator Free Catalyst
Moya‐López, C., Bravo, I., Castro‐Osma, J. A., Chapron, D., Bourson, P., Vagner, C., Cochez, M., Leoné, N., Lara‐Sánchez, A., Alonso‐Moreno, C., et al. (2022) · Polymers · doi:10.3390/polym14020232 · Cited by 5 · see citing works
Exploiting multimetallic catalysts to access polymer materials from CO2
Garden, J. A. (2017) · Green Materials · doi:10.1680/jgrma.16.00022 · Cited by 5 · see citing works
Efficient Copolymerization of Methyl Methacrylate and Lactide Using Metalate Catalysts
Upitak, K., & Thomas, C. M. (2025) · Macromolecular Rapid Communications · doi:10.1002/marc.202400895 · Cited by 4 · see citing works
Self-citationNiedźwiedź, M., Ignaczak, W., Sobolewski, P., Demirci, G., & Fray, M. E. (2022) · ChemRxiv · doi:10.26434/chemrxiv-2022-jn0mj · Cited by 4 · see citing works
Navarro, M., González-Lizana, D., Sánchez‐Barba, L. F., Garcés, A., Fernández, I., Lara‐Sánchez, A., & Rodrı́guez, A. M. (2023) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c02410 · Cited by 3 · see citing works
Bekmirzaev, J., Simon, M., D’Aniello, S., Mazzeo, M., Cohen‐Janes, S. J., Mathers, R. T., Gauvin, R. M., & Thomas, C. M. (2024) · Angewandte Chemie · doi:10.1002/ange.202319414 · Cited by 2 · see citing works
Self-citationNiedźwiedź, M., Ignaczak, W., Sobolewski, P., Goszczyńska, A., Demirci, G., & Fray, M. E. (2023) · RSC Advances · doi:10.1039/d3ra02157b · Cited by 2 · see citing works
Mechanisms in Heterobimetallic Reactivity
Singer, F. N., & Buchard, A. (2022) · Wiley eBooks · doi:10.1002/9781119448877.ch4
Piyawongsiri, T., Gaston, A. J., Rahman, M. A., Hughes, J. W. J., Rudman, G. E., Lowy, P. A., Nichol, G. S., Morrison, C. A., Phomphrai, K., & Garden, J. A. (2025) · Catalysis Science & Technology · doi:10.1039/d5cy00872g
Advances and technical challenges in mono-material plastics design for sustainability
Quinn, E. C., Gace, M. T., Hamernik, L. J., Shi, C., Knauer, K. M., Beckham, G. T., & Chen, E. Y. ‐. (2026) · Nature Reviews Materials · doi:10.1038/s41578-026-00961-z
- Authors
- Char, J., Brulé, E., Gros, P. C., Rager, M.-N., Guérineau, V., & Thomas, C. M.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Thomas, Christophe M.
- Venue
- Journal of Organometallic Chemistry
- Publisher
- Elsevier BV
- Published
- 2015-11
- Volume
- 796
- Pages
- 47-52
- ISSN
- 0022-328X (ISSN-L)
- OpenAlex
- W2073346163
- Cited by
- 30
- References
- 27
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 4 · 2023: 2 · 2022: 6 · 2021: 5 · 2020: 1 · 2019: 1 · 2018: 2 · 2017: 3 · 2016: 2 · 2015: 1
- FWCI
- 0.97
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Organometallic Chemistry (publishedVersion)
- HAL (submittedVersion)
- Funders
- CNRS
- ENSCP
- Fondation Pierre-Gilles de Gennes
- French Ministry of Research and Higher Education
- Institut Universitaire de France (IUF)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- polylactic acid, stereoselective catalysis, heterobimetallic complexes, magnesium complexes, zinc complexes, biodegradable polymers, biomass-derived monomers
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review